Self-assembly of conjugated units using metal-terpyridine coordination
Due to their inherently dynamic natures and fascinating photoluminescent/photoelectronic properties, coordination compounds of metal ions and conjugated terpyridine ligands have attracted considerable attention as functional materials for a variety of potential applications. In this feature article,...
| Main Authors: | , , |
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| Format: | Journal Article |
| Language: | English |
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2014
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| Online Access: | https://hdl.handle.net/10356/103156 http://hdl.handle.net/10220/24445 |
| _version_ | 1826109830349193216 |
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| author | Gao, Yang Rajwar, Deepa Grimsdale, Andrew C. |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Gao, Yang Rajwar, Deepa Grimsdale, Andrew C. |
| author_sort | Gao, Yang |
| collection | NTU |
| description | Due to their inherently dynamic natures and fascinating photoluminescent/photoelectronic properties, coordination compounds of metal ions and conjugated terpyridine ligands have attracted considerable attention as functional materials for a variety of potential applications. In this feature article, a summary of recent work toward the development of one- (1D), two- (2D), and three-dimensional (3D) supramolecular polymers, networks, and metallomacrocycles based on zinc metal ion coordination of conjugated units bearing terpyridine ligands is presented, and it is shown how it fits within the overall framework of work in this field. Here, a sequential study from terpyridines as basic building blocks to their zinc-coordinated supramolecular 1D polymers, 2D macrocycles, and 2D and 3D networks is developed. These networks are compared with respect to their thermal stabilities, molecular organization, and linear and nonlinear optical properties. This work opens new prospects for the development of supramolecular chemistry of terpyridines and other transition metal ions, and also their application in future optoelectronic devices. |
| first_indexed | 2024-10-01T02:24:48Z |
| format | Journal Article |
| id | ntu-10356/103156 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T02:24:48Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | ntu-10356/1031562020-06-01T10:21:28Z Self-assembly of conjugated units using metal-terpyridine coordination Gao, Yang Rajwar, Deepa Grimsdale, Andrew C. School of Materials Science & Engineering DRNTU::Engineering::Materials::Energy materials Due to their inherently dynamic natures and fascinating photoluminescent/photoelectronic properties, coordination compounds of metal ions and conjugated terpyridine ligands have attracted considerable attention as functional materials for a variety of potential applications. In this feature article, a summary of recent work toward the development of one- (1D), two- (2D), and three-dimensional (3D) supramolecular polymers, networks, and metallomacrocycles based on zinc metal ion coordination of conjugated units bearing terpyridine ligands is presented, and it is shown how it fits within the overall framework of work in this field. Here, a sequential study from terpyridines as basic building blocks to their zinc-coordinated supramolecular 1D polymers, 2D macrocycles, and 2D and 3D networks is developed. These networks are compared with respect to their thermal stabilities, molecular organization, and linear and nonlinear optical properties. This work opens new prospects for the development of supramolecular chemistry of terpyridines and other transition metal ions, and also their application in future optoelectronic devices. 2014-12-11T09:02:49Z 2019-12-06T21:06:34Z 2014-12-11T09:02:49Z 2019-12-06T21:06:34Z 2014 2014 Journal Article Gao, Y., Rajwar, D., & Grimsdale, A. C. (2014). Self-assembly of conjugated units using metal-terpyridine coordination. Macromolecular rapid communications, 35(20), 1727-1740. 1022-1336 https://hdl.handle.net/10356/103156 http://hdl.handle.net/10220/24445 10.1002/marc.201400225 en Macromolecular rapid communications © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| spellingShingle | DRNTU::Engineering::Materials::Energy materials Gao, Yang Rajwar, Deepa Grimsdale, Andrew C. Self-assembly of conjugated units using metal-terpyridine coordination |
| title | Self-assembly of conjugated units using metal-terpyridine coordination |
| title_full | Self-assembly of conjugated units using metal-terpyridine coordination |
| title_fullStr | Self-assembly of conjugated units using metal-terpyridine coordination |
| title_full_unstemmed | Self-assembly of conjugated units using metal-terpyridine coordination |
| title_short | Self-assembly of conjugated units using metal-terpyridine coordination |
| title_sort | self assembly of conjugated units using metal terpyridine coordination |
| topic | DRNTU::Engineering::Materials::Energy materials |
| url | https://hdl.handle.net/10356/103156 http://hdl.handle.net/10220/24445 |
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