Palladacycle catalyzed asymmetric P-H addition of diarylphosphines to N-enoyl phthalimides
The first asymmetric phospha-Michael addition of diarylphosphines to N-enoyl phthalimides has been developed in the presence of a chiral palladacycle catalyst. A library of free chiral tertiary phosphine adducts were directly obtained with excellent yields and enantioselectivities. Products can be s...
Main Authors: | Chew, Renta Jonathan, Lu, Yunpeng, Jia, Yu-Xiang, Li, Bin-Bin, Wong, Esther Hui Yen, Goh, Rosanne, Li, Yongxin, Huang, Yinhua, Pullarkat, Sumod Appukuttan, Leung, Pak-Hing |
---|---|
Other Authors: | School of Physical and Mathematical Sciences |
Format: | Journal Article |
Language: | English |
Published: |
2014
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/103605 http://hdl.handle.net/10220/24566 |
Similar Items
-
Asymmetric synthesis of enaminophosphines via palladacycle-catalyzed addition of Ph2PH to α,β-unsaturated imines
by: Pullarkat, Sumod A., et al.
Published: (2013) -
Pd-catalyzed enantiodivergent and regiospecific phospha-michael addition of diphenylphosphine to 4-oxo-enamides : efficient access to chiral phosphinocarboxamides and their analogues
by: Chew, Renta Jonathan, et al.
Published: (2015) -
Palladacycle-catalyzed asymmetric hydrophosphination of enones for synthesis of C*- and P*-chiral tertiary phosphines
by: Pullarkat, Sumod A., et al.
Published: (2013) -
Enantioselective addition of diphenylphosphine to 3-methyl-4-nitro-5-alkenylisoxazoles
by: Chew, Renta Jonathan, et al.
Published: (2014) -
Synthesis, optical resolution, and stereochemical properties of a rationally designed chiral C–N palladacycle
by: Li, Yongxin, et al.
Published: (2014)