[Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines
Cp*IrCl2]2 catalyzes the cyclization of 2-ethynylanilines to 2,2′-biindoles via intramolecular hydroamination. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.
| Main Authors: | , , |
|---|---|
| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2014
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/103801 http://hdl.handle.net/10220/24539 |
| _version_ | 1811678212631035904 |
|---|---|
| author | Kumaran, Elumalai Fan, Wai Yip Leong, Weng Kee |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Kumaran, Elumalai Fan, Wai Yip Leong, Weng Kee |
| author_sort | Kumaran, Elumalai |
| collection | NTU |
| description | Cp*IrCl2]2 catalyzes the cyclization of 2-ethynylanilines to 2,2′-biindoles via intramolecular hydroamination. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies. |
| first_indexed | 2024-10-01T02:49:40Z |
| format | Journal Article |
| id | ntu-10356/103801 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T02:49:40Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | ntu-10356/1038012023-02-28T19:37:58Z [Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines Kumaran, Elumalai Fan, Wai Yip Leong, Weng Kee School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds Cp*IrCl2]2 catalyzes the cyclization of 2-ethynylanilines to 2,2′-biindoles via intramolecular hydroamination. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies. MOE (Min. of Education, S’pore) Accepted version 2014-12-26T04:34:28Z 2019-12-06T21:20:35Z 2014-12-26T04:34:28Z 2019-12-06T21:20:35Z 2014 2014 Journal Article Kumaran, E., Fan, W. Y., & Leong, W. K. (2014). [Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines. Organic letters, 16(5), 1342-1345. https://hdl.handle.net/10356/103801 http://hdl.handle.net/10220/24539 10.1021/ol5000692 en Organic letters © 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organic Letters, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/ol5000692]. 5 p. application/pdf |
| spellingShingle | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds Kumaran, Elumalai Fan, Wai Yip Leong, Weng Kee [Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines |
| title | [Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines |
| title_full | [Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines |
| title_fullStr | [Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines |
| title_full_unstemmed | [Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines |
| title_short | [Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines |
| title_sort | cp ircl2 2 catalyzed formation of 2 2 biindoles from 2 ethynylanilines |
| topic | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds |
| url | https://hdl.handle.net/10356/103801 http://hdl.handle.net/10220/24539 |
| work_keys_str_mv | AT kumaranelumalai cpircl22catalyzedformationof22biindolesfrom2ethynylanilines AT fanwaiyip cpircl22catalyzedformationof22biindolesfrom2ethynylanilines AT leongwengkee cpircl22catalyzedformationof22biindolesfrom2ethynylanilines |