A new insight into electrochemical detection of eugenol by hierarchical sheaf-like mesoporous NiCo2O4

In this work, NiCo2O4 nanosheet with sheaf-like nanostructure morphologies was synthesized by a facile one-step hydrothermal reaction followed by annealing treatment. Impressively, the NiCo2O4 exhibit rapid detection of eugenol. The linear range of detection is from 1-500 µM, and the limit of detect...

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Main Authors: Anu Prathap, Mylamparambil Udayan, Wei, Chao, Sun, Shengnan, Xu, Zhichuan J.
Other Authors: School of Materials Science & Engineering
Format: Journal Article
Language:English
Published: 2015
Subjects:
Online Access:https://hdl.handle.net/10356/103862
http://hdl.handle.net/10220/25830
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author Anu Prathap, Mylamparambil Udayan
Wei, Chao
Sun, Shengnan
Xu, Zhichuan J.
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Anu Prathap, Mylamparambil Udayan
Wei, Chao
Sun, Shengnan
Xu, Zhichuan J.
author_sort Anu Prathap, Mylamparambil Udayan
collection NTU
description In this work, NiCo2O4 nanosheet with sheaf-like nanostructure morphologies was synthesized by a facile one-step hydrothermal reaction followed by annealing treatment. Impressively, the NiCo2O4 exhibit rapid detection of eugenol. The linear range of detection is from 1-500 µM, and the limit of detection is 5.4 pM. NiCo2O4 modified electrode demonstrated high sensitivity, good repeatability and reproducibility, and long-term stability (7 % decrease in response over 30 days). Based on this work, an electrochemical reaction mechanism for eugenol oxidation was proposed, and in addition, the NiCo2O4 modified electrode was successfully employed for the analysis of eugenol in medicative balm samples. The recoveries study for eugenol in medicative balm samples gave values in the range of 98.7– 05.5%.
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spelling ntu-10356/1038622023-07-14T15:54:25Z A new insight into electrochemical detection of eugenol by hierarchical sheaf-like mesoporous NiCo2O4 Anu Prathap, Mylamparambil Udayan Wei, Chao Sun, Shengnan Xu, Zhichuan J. School of Materials Science & Engineering DRNTU::Engineering::Materials::Nanostructured materials In this work, NiCo2O4 nanosheet with sheaf-like nanostructure morphologies was synthesized by a facile one-step hydrothermal reaction followed by annealing treatment. Impressively, the NiCo2O4 exhibit rapid detection of eugenol. The linear range of detection is from 1-500 µM, and the limit of detection is 5.4 pM. NiCo2O4 modified electrode demonstrated high sensitivity, good repeatability and reproducibility, and long-term stability (7 % decrease in response over 30 days). Based on this work, an electrochemical reaction mechanism for eugenol oxidation was proposed, and in addition, the NiCo2O4 modified electrode was successfully employed for the analysis of eugenol in medicative balm samples. The recoveries study for eugenol in medicative balm samples gave values in the range of 98.7– 05.5%. Accepted version 2015-06-08T06:30:59Z 2019-12-06T21:21:47Z 2015-06-08T06:30:59Z 2019-12-06T21:21:47Z 2015 2015 Journal Article Anu Prathap, M. U., Wei, C., Sun, S., & Xu, Z. J. (2015). A new insight into electrochemical detection of eugenol by hierarchical sheaf-like mesoporous NiCo2O4. Nano research, 8(8), 2636-2645. https://hdl.handle.net/10356/103862 http://hdl.handle.net/10220/25830 10.1007/s12274-015-0769-z 194233 en Nano research © 2015 Tsinghua University Press and Springer. This is the author created version of a work that has been peer reviewed and accepted for publication by Nano Research, Tsinghua University Press and Springer. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1007/s12274-015-0769-z]. application/pdf
spellingShingle DRNTU::Engineering::Materials::Nanostructured materials
Anu Prathap, Mylamparambil Udayan
Wei, Chao
Sun, Shengnan
Xu, Zhichuan J.
A new insight into electrochemical detection of eugenol by hierarchical sheaf-like mesoporous NiCo2O4
title A new insight into electrochemical detection of eugenol by hierarchical sheaf-like mesoporous NiCo2O4
title_full A new insight into electrochemical detection of eugenol by hierarchical sheaf-like mesoporous NiCo2O4
title_fullStr A new insight into electrochemical detection of eugenol by hierarchical sheaf-like mesoporous NiCo2O4
title_full_unstemmed A new insight into electrochemical detection of eugenol by hierarchical sheaf-like mesoporous NiCo2O4
title_short A new insight into electrochemical detection of eugenol by hierarchical sheaf-like mesoporous NiCo2O4
title_sort new insight into electrochemical detection of eugenol by hierarchical sheaf like mesoporous nico2o4
topic DRNTU::Engineering::Materials::Nanostructured materials
url https://hdl.handle.net/10356/103862
http://hdl.handle.net/10220/25830
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