Liquid-phase epitaxial growth of two-dimensional semiconductor hetero-nanostructures
Although many two-dimensional (2D) hybrid nanostructures are being prepared, the engineering of epitaxial 2D semiconductor hetero-nanostructures in the liquid phase still remains a challenge. The preparation of 2D semiconductor hetero-nanostructures by epitaxial growth of metal sulfide nanocrystals,...
Main Authors: | , , , , , , , , , , |
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Format: | Journal Article |
Language: | English |
Published: |
2015
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Online Access: | https://hdl.handle.net/10356/103934 http://hdl.handle.net/10220/24662 |
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author | Tan, Chaoliang Zeng, Zhiyuan Huang, Xiao Rui, Xianhong Wu, Xue-Jun Li, Bing Luo, Zhimin Chen, Junze Chen, Bo Yan, Qingyu Zhang, Hua |
author2 | School of Materials Science & Engineering |
author_facet | School of Materials Science & Engineering Tan, Chaoliang Zeng, Zhiyuan Huang, Xiao Rui, Xianhong Wu, Xue-Jun Li, Bing Luo, Zhimin Chen, Junze Chen, Bo Yan, Qingyu Zhang, Hua |
author_sort | Tan, Chaoliang |
collection | NTU |
description | Although many two-dimensional (2D) hybrid nanostructures are being prepared, the engineering of epitaxial 2D semiconductor hetero-nanostructures in the liquid phase still remains a challenge. The preparation of 2D semiconductor hetero-nanostructures by epitaxial growth of metal sulfide nanocrystals, including CuS, ZnS and Ni3S2, is achieved on ultrathin TiS2 nanosheets by a simple electrochemical approach by using the TiS2 crystal and metal foils. Ultrathin CuS nanoplates 50–120 nm in size and with a triangular/hexagonal shape are epitaxially grown on TiS2 nanosheets with perfect epitaxial alignment. ZnS and Ni3S2 nanoplates can be also epitaxially grown on TiS2 nanosheets. As a proof-of-concept application, the obtained 2D CuS–TiS2 composite is used as the anode in a lithium ion battery, which exhibits a high capacity and excellent cycling stability. |
first_indexed | 2024-10-01T05:26:18Z |
format | Journal Article |
id | ntu-10356/103934 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T05:26:18Z |
publishDate | 2015 |
record_format | dspace |
spelling | ntu-10356/1039342020-06-01T10:13:51Z Liquid-phase epitaxial growth of two-dimensional semiconductor hetero-nanostructures Tan, Chaoliang Zeng, Zhiyuan Huang, Xiao Rui, Xianhong Wu, Xue-Jun Li, Bing Luo, Zhimin Chen, Junze Chen, Bo Yan, Qingyu Zhang, Hua School of Materials Science & Engineering DRNTU::Engineering::Materials::Nanostructured materials Although many two-dimensional (2D) hybrid nanostructures are being prepared, the engineering of epitaxial 2D semiconductor hetero-nanostructures in the liquid phase still remains a challenge. The preparation of 2D semiconductor hetero-nanostructures by epitaxial growth of metal sulfide nanocrystals, including CuS, ZnS and Ni3S2, is achieved on ultrathin TiS2 nanosheets by a simple electrochemical approach by using the TiS2 crystal and metal foils. Ultrathin CuS nanoplates 50–120 nm in size and with a triangular/hexagonal shape are epitaxially grown on TiS2 nanosheets with perfect epitaxial alignment. ZnS and Ni3S2 nanoplates can be also epitaxially grown on TiS2 nanosheets. As a proof-of-concept application, the obtained 2D CuS–TiS2 composite is used as the anode in a lithium ion battery, which exhibits a high capacity and excellent cycling stability. 2015-01-16T08:51:30Z 2019-12-06T21:23:20Z 2015-01-16T08:51:30Z 2019-12-06T21:23:20Z 2014 2014 Journal Article Tan, C., Zeng, Z., Huang, X., Rui, X., Wu, X.-J., Li, B., et al. (2014). Liquid-phase epitaxial growth of two-dimensional semiconductor hetero-nanostructures. Angewandte chemie international edition, 54(6), 1841–1845. 1433-7851 https://hdl.handle.net/10356/103934 http://hdl.handle.net/10220/24662 10.1002/anie.201410890 en Angewandte chemie international edition © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
spellingShingle | DRNTU::Engineering::Materials::Nanostructured materials Tan, Chaoliang Zeng, Zhiyuan Huang, Xiao Rui, Xianhong Wu, Xue-Jun Li, Bing Luo, Zhimin Chen, Junze Chen, Bo Yan, Qingyu Zhang, Hua Liquid-phase epitaxial growth of two-dimensional semiconductor hetero-nanostructures |
title | Liquid-phase epitaxial growth of two-dimensional semiconductor hetero-nanostructures |
title_full | Liquid-phase epitaxial growth of two-dimensional semiconductor hetero-nanostructures |
title_fullStr | Liquid-phase epitaxial growth of two-dimensional semiconductor hetero-nanostructures |
title_full_unstemmed | Liquid-phase epitaxial growth of two-dimensional semiconductor hetero-nanostructures |
title_short | Liquid-phase epitaxial growth of two-dimensional semiconductor hetero-nanostructures |
title_sort | liquid phase epitaxial growth of two dimensional semiconductor hetero nanostructures |
topic | DRNTU::Engineering::Materials::Nanostructured materials |
url | https://hdl.handle.net/10356/103934 http://hdl.handle.net/10220/24662 |
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