Li3V2(PO4)3 cathode materials for lithium-ion batteries : a review
The principal challenges facing the development of lithium ion batteries (LIBs) for hybrid electric/plug-in-hybrid (HEV/PHEV) vehicles and for off-peak energy storage are cost, safety, cell energy density (voltage × capacity), rate of charge/discharge, and service life. There are exciting developm...
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
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2014
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| Online Access: | https://hdl.handle.net/10356/104510 http://hdl.handle.net/10220/20235 |
| _version_ | 1826125456141713408 |
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| author | Rui, Xianhong Yan, Qingyu Skyllas-Kazacos, Maria Lim, Tuti Mariana |
| author2 | School of Civil and Environmental Engineering |
| author_facet | School of Civil and Environmental Engineering Rui, Xianhong Yan, Qingyu Skyllas-Kazacos, Maria Lim, Tuti Mariana |
| author_sort | Rui, Xianhong |
| collection | NTU |
| description | The principal challenges facing the development of lithium ion batteries (LIBs) for hybrid
electric/plug-in-hybrid (HEV/PHEV) vehicles and for off-peak energy storage are cost, safety, cell energy density
(voltage × capacity), rate of charge/discharge, and service life. There are exciting developments in new positive
electrode (cathode) materials to replace the LiCoO2 for use in the LIBs over the past decade. Monoclinic Li3V2(PO4)3
(LVP) with promising electrochemical properties including excellent cycling stability, high theoretical capacity (197
mAh g-1), low synthetic cost, improved safety characteristic, and low environmental impact emerges as highly suitable
candidate. In this review, we focus on research work related to the LVP and discuss its host structure, mechanism of
lithium insertion/extraction, transport properties (i.e., electronic conductivity, and lithium diffusion), synthesis and
electrochemical properties. We highlight some recent development of LVP, which shows superior cycling stability and
high rate capability and give some vision for the future research of LVP based electrode. |
| first_indexed | 2024-10-01T06:36:36Z |
| format | Journal Article |
| id | ntu-10356/104510 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:36:36Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | ntu-10356/1045102021-01-08T08:19:11Z Li3V2(PO4)3 cathode materials for lithium-ion batteries : a review Rui, Xianhong Yan, Qingyu Skyllas-Kazacos, Maria Lim, Tuti Mariana School of Civil and Environmental Engineering School of Materials Science & Engineering TUM CREATE Centre for Electromobility Energy Research Institute @ NTU (ERI@N) DRNTU::Engineering::Materials::Energy materials The principal challenges facing the development of lithium ion batteries (LIBs) for hybrid electric/plug-in-hybrid (HEV/PHEV) vehicles and for off-peak energy storage are cost, safety, cell energy density (voltage × capacity), rate of charge/discharge, and service life. There are exciting developments in new positive electrode (cathode) materials to replace the LiCoO2 for use in the LIBs over the past decade. Monoclinic Li3V2(PO4)3 (LVP) with promising electrochemical properties including excellent cycling stability, high theoretical capacity (197 mAh g-1), low synthetic cost, improved safety characteristic, and low environmental impact emerges as highly suitable candidate. In this review, we focus on research work related to the LVP and discuss its host structure, mechanism of lithium insertion/extraction, transport properties (i.e., electronic conductivity, and lithium diffusion), synthesis and electrochemical properties. We highlight some recent development of LVP, which shows superior cycling stability and high rate capability and give some vision for the future research of LVP based electrode. Accepted version 2014-07-21T07:36:00Z 2019-12-06T21:34:15Z 2014-07-21T07:36:00Z 2019-12-06T21:34:15Z 2014 2014 Journal Article Rui, X., Yan, Q., Skyllas-Kazacos, M., & Lim, T. M. (2014). Li3V2(PO4)3 cathode materials for lithium-ion batteries: A review. Journal of Power Sources, 258, 19-38. 0378-7753 https://hdl.handle.net/10356/104510 http://hdl.handle.net/10220/20235 10.1016/j.jpowsour.2014.01.126 en Journal of power sources © 2014 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Power Sources, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: http://dx.doi.org/10.1016/j.jpowsour.2014.01.126. 20 p. application/pdf |
| spellingShingle | DRNTU::Engineering::Materials::Energy materials Rui, Xianhong Yan, Qingyu Skyllas-Kazacos, Maria Lim, Tuti Mariana Li3V2(PO4)3 cathode materials for lithium-ion batteries : a review |
| title | Li3V2(PO4)3 cathode materials for lithium-ion batteries : a review |
| title_full | Li3V2(PO4)3 cathode materials for lithium-ion batteries : a review |
| title_fullStr | Li3V2(PO4)3 cathode materials for lithium-ion batteries : a review |
| title_full_unstemmed | Li3V2(PO4)3 cathode materials for lithium-ion batteries : a review |
| title_short | Li3V2(PO4)3 cathode materials for lithium-ion batteries : a review |
| title_sort | li3v2 po4 3 cathode materials for lithium ion batteries a review |
| topic | DRNTU::Engineering::Materials::Energy materials |
| url | https://hdl.handle.net/10356/104510 http://hdl.handle.net/10220/20235 |
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