A conjugated copolymer of N‐Phenyl‐p‐phenylenediamine and pyrene as promising cathode for rechargeable Lithium–ion batteries

A novel conjugated copolymer has been synthesized and employed as an organic cathode material in rechargeable Lithium-ion batteries (LIBs). Due to the synergistic effects from conducting aniline and pyrene units, the resultant batteries based on the as-obtained copolymer can deliver a promising reve...

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Main Authors: Yao, Chang‐Jiang, Xie, Jian, Wu, Zhenzhen, Xu, Zhichuan, Zhang, Shanqing, Zhang, Qichun
Other Authors: School of Materials Science & Engineering
Format: Journal Article
Language:English
Published: 2019
Subjects:
Online Access:https://hdl.handle.net/10356/105033
http://hdl.handle.net/10220/49283
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author Yao, Chang‐Jiang
Xie, Jian
Wu, Zhenzhen
Xu, Zhichuan
Zhang, Shanqing
Zhang, Qichun
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Yao, Chang‐Jiang
Xie, Jian
Wu, Zhenzhen
Xu, Zhichuan
Zhang, Shanqing
Zhang, Qichun
author_sort Yao, Chang‐Jiang
collection NTU
description A novel conjugated copolymer has been synthesized and employed as an organic cathode material in rechargeable Lithium-ion batteries (LIBs). Due to the synergistic effects from conducting aniline and pyrene units, the resultant batteries based on the as-obtained copolymer can deliver a promising reversible specific capacity of 113 mAh g-1 with a high voltage output of 3.2 V and a remarkable 75.2 % capacity retention after 180 cycles. Moreover, an excellent rate performance is also achieved with a fast recovery of the capacity at different current densities.
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spelling ntu-10356/1050332023-07-14T15:56:01Z A conjugated copolymer of N‐Phenyl‐p‐phenylenediamine and pyrene as promising cathode for rechargeable Lithium–ion batteries Yao, Chang‐Jiang Xie, Jian Wu, Zhenzhen Xu, Zhichuan Zhang, Shanqing Zhang, Qichun School of Materials Science & Engineering Pyrene Engineering::Materials Polyaniline A novel conjugated copolymer has been synthesized and employed as an organic cathode material in rechargeable Lithium-ion batteries (LIBs). Due to the synergistic effects from conducting aniline and pyrene units, the resultant batteries based on the as-obtained copolymer can deliver a promising reversible specific capacity of 113 mAh g-1 with a high voltage output of 3.2 V and a remarkable 75.2 % capacity retention after 180 cycles. Moreover, an excellent rate performance is also achieved with a fast recovery of the capacity at different current densities. MOE (Min. of Education, S’pore) Accepted version 2019-07-11T04:48:51Z 2019-12-06T21:44:49Z 2019-07-11T04:48:51Z 2019-12-06T21:44:49Z 2019 2019 Journal Article Yao, C.-J., Xie, J., Wu, Z., Xu, Z., Zhang, S., & Zhang, Q. (2019). A conjugated copolymer of N‐Phenyl‐p‐phenylenediamine and pyrene as promising cathode for rechargeable Lithium–ion batteries. Chemistry - An Asian Journal, 14(13), 2210-2214. doi:10.1002/asia.201900520 1861-4728 https://hdl.handle.net/10356/105033 http://hdl.handle.net/10220/49283 10.1002/asia.201900520 213020 en Chemistry - An Asian Journal This is the peer reviewed version of the following article: Yao, C.-J., Xie, J., Wu, Z., Xu, Z., Zhang, S., & Zhang, Q. (2019). A conjugated copolymer of N‐Phenyl‐p‐phenylenediamine and pyrene as promising cathode for rechargeable Lithium–ion batteries. Chemistry - An Asian Journal, 14(13), 2210-2214. doi:10.1002/asia.201900520, which has been published in final form at https://doi.org/10.1002/asia.201900520. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. 7 p. application/pdf
spellingShingle Pyrene
Engineering::Materials
Polyaniline
Yao, Chang‐Jiang
Xie, Jian
Wu, Zhenzhen
Xu, Zhichuan
Zhang, Shanqing
Zhang, Qichun
A conjugated copolymer of N‐Phenyl‐p‐phenylenediamine and pyrene as promising cathode for rechargeable Lithium–ion batteries
title A conjugated copolymer of N‐Phenyl‐p‐phenylenediamine and pyrene as promising cathode for rechargeable Lithium–ion batteries
title_full A conjugated copolymer of N‐Phenyl‐p‐phenylenediamine and pyrene as promising cathode for rechargeable Lithium–ion batteries
title_fullStr A conjugated copolymer of N‐Phenyl‐p‐phenylenediamine and pyrene as promising cathode for rechargeable Lithium–ion batteries
title_full_unstemmed A conjugated copolymer of N‐Phenyl‐p‐phenylenediamine and pyrene as promising cathode for rechargeable Lithium–ion batteries
title_short A conjugated copolymer of N‐Phenyl‐p‐phenylenediamine and pyrene as promising cathode for rechargeable Lithium–ion batteries
title_sort conjugated copolymer of n phenyl p phenylenediamine and pyrene as promising cathode for rechargeable lithium ion batteries
topic Pyrene
Engineering::Materials
Polyaniline
url https://hdl.handle.net/10356/105033
http://hdl.handle.net/10220/49283
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