Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries

The coupling of proteins with self-assembly properties and proteins that are capable of recognizing and mineralizing specific inorganic species is a promising strategy for the synthesis of nanoscale materials with controllable morphology and functionality. Herein, GPG-AG3 protein fibers with both of...

Full description

Bibliographic Details
Main Authors: Guo, Guilue, Truong, Thi Hong Anh, Tan, Huiteng, Ang, Huixiang, Zhang, Wenyu, Xu, Chen, Rui, Xianghong, Hu, Zhaolong, Fong, Eileen, Yan, Qingyu
Other Authors: School of Materials Science & Engineering
Format: Journal Article
Language:English
Published: 2014
Subjects:
Online Access:https://hdl.handle.net/10356/105302
http://hdl.handle.net/10220/20683
_version_ 1826128121910263808
author Guo, Guilue
Truong, Thi Hong Anh
Tan, Huiteng
Ang, Huixiang
Zhang, Wenyu
Xu, Chen
Rui, Xianghong
Hu, Zhaolong
Fong, Eileen
Yan, Qingyu
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Guo, Guilue
Truong, Thi Hong Anh
Tan, Huiteng
Ang, Huixiang
Zhang, Wenyu
Xu, Chen
Rui, Xianghong
Hu, Zhaolong
Fong, Eileen
Yan, Qingyu
author_sort Guo, Guilue
collection NTU
description The coupling of proteins with self-assembly properties and proteins that are capable of recognizing and mineralizing specific inorganic species is a promising strategy for the synthesis of nanoscale materials with controllable morphology and functionality. Herein, GPG-AG3 protein fibers with both of these properties were constructed and served as templates for the synthesis of Pt and Pd nanotubes. The protein fibers of assembled GPG-AG3 were more than 10 μm long and had diameters of 20–50 nm. The as-synthesized Pt and Pd nanotubes were composed of dense layers of ∼3–5 nm Pt and Pd nanoparticles. When tested as cathodes in lithium-O2 batteries, the porous Pt nanotubes showed low charge potentials of 3.8 V, with round-trip efficiencies of about 65 % at a current density of 100 mA g−1.
first_indexed 2024-10-01T07:19:45Z
format Journal Article
id ntu-10356/105302
institution Nanyang Technological University
language English
last_indexed 2024-10-01T07:19:45Z
publishDate 2014
record_format dspace
spelling ntu-10356/1053022020-06-01T10:21:17Z Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries Guo, Guilue Truong, Thi Hong Anh Tan, Huiteng Ang, Huixiang Zhang, Wenyu Xu, Chen Rui, Xianghong Hu, Zhaolong Fong, Eileen Yan, Qingyu School of Materials Science & Engineering DRNTU::Science::Chemistry The coupling of proteins with self-assembly properties and proteins that are capable of recognizing and mineralizing specific inorganic species is a promising strategy for the synthesis of nanoscale materials with controllable morphology and functionality. Herein, GPG-AG3 protein fibers with both of these properties were constructed and served as templates for the synthesis of Pt and Pd nanotubes. The protein fibers of assembled GPG-AG3 were more than 10 μm long and had diameters of 20–50 nm. The as-synthesized Pt and Pd nanotubes were composed of dense layers of ∼3–5 nm Pt and Pd nanoparticles. When tested as cathodes in lithium-O2 batteries, the porous Pt nanotubes showed low charge potentials of 3.8 V, with round-trip efficiencies of about 65 % at a current density of 100 mA g−1. 2014-09-15T02:56:50Z 2019-12-06T21:48:57Z 2014-09-15T02:56:50Z 2019-12-06T21:48:57Z 2014 2014 Journal Article Guo, G., Truong, T. H. A., Tan, H., Ang, H., Zhang, W., Xu, C., et al. Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries. Chemistry - an Asian journal, 9(9), 2555-2559. 1861-4728 https://hdl.handle.net/10356/105302 http://hdl.handle.net/10220/20683 10.1002/asia.201402191 en Chemistry - an Asian journal © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
spellingShingle DRNTU::Science::Chemistry
Guo, Guilue
Truong, Thi Hong Anh
Tan, Huiteng
Ang, Huixiang
Zhang, Wenyu
Xu, Chen
Rui, Xianghong
Hu, Zhaolong
Fong, Eileen
Yan, Qingyu
Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries
title Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries
title_full Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries
title_fullStr Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries
title_full_unstemmed Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries
title_short Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries
title_sort platinum and palladium nanotubes based on genetically engineered elastin mimetic fusion protein fiber templates synthesis and application in lithium o2 batteries
topic DRNTU::Science::Chemistry
url https://hdl.handle.net/10356/105302
http://hdl.handle.net/10220/20683
work_keys_str_mv AT guoguilue platinumandpalladiumnanotubesbasedongeneticallyengineeredelastinmimeticfusionproteinfibertemplatessynthesisandapplicationinlithiumo2batteries
AT truongthihonganh platinumandpalladiumnanotubesbasedongeneticallyengineeredelastinmimeticfusionproteinfibertemplatessynthesisandapplicationinlithiumo2batteries
AT tanhuiteng platinumandpalladiumnanotubesbasedongeneticallyengineeredelastinmimeticfusionproteinfibertemplatessynthesisandapplicationinlithiumo2batteries
AT anghuixiang platinumandpalladiumnanotubesbasedongeneticallyengineeredelastinmimeticfusionproteinfibertemplatessynthesisandapplicationinlithiumo2batteries
AT zhangwenyu platinumandpalladiumnanotubesbasedongeneticallyengineeredelastinmimeticfusionproteinfibertemplatessynthesisandapplicationinlithiumo2batteries
AT xuchen platinumandpalladiumnanotubesbasedongeneticallyengineeredelastinmimeticfusionproteinfibertemplatessynthesisandapplicationinlithiumo2batteries
AT ruixianghong platinumandpalladiumnanotubesbasedongeneticallyengineeredelastinmimeticfusionproteinfibertemplatessynthesisandapplicationinlithiumo2batteries
AT huzhaolong platinumandpalladiumnanotubesbasedongeneticallyengineeredelastinmimeticfusionproteinfibertemplatessynthesisandapplicationinlithiumo2batteries
AT fongeileen platinumandpalladiumnanotubesbasedongeneticallyengineeredelastinmimeticfusionproteinfibertemplatessynthesisandapplicationinlithiumo2batteries
AT yanqingyu platinumandpalladiumnanotubesbasedongeneticallyengineeredelastinmimeticfusionproteinfibertemplatessynthesisandapplicationinlithiumo2batteries