Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries
The coupling of proteins with self-assembly properties and proteins that are capable of recognizing and mineralizing specific inorganic species is a promising strategy for the synthesis of nanoscale materials with controllable morphology and functionality. Herein, GPG-AG3 protein fibers with both of...
Main Authors: | , , , , , , , , , |
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Format: | Journal Article |
Language: | English |
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2014
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Online Access: | https://hdl.handle.net/10356/105302 http://hdl.handle.net/10220/20683 |
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author | Guo, Guilue Truong, Thi Hong Anh Tan, Huiteng Ang, Huixiang Zhang, Wenyu Xu, Chen Rui, Xianghong Hu, Zhaolong Fong, Eileen Yan, Qingyu |
author2 | School of Materials Science & Engineering |
author_facet | School of Materials Science & Engineering Guo, Guilue Truong, Thi Hong Anh Tan, Huiteng Ang, Huixiang Zhang, Wenyu Xu, Chen Rui, Xianghong Hu, Zhaolong Fong, Eileen Yan, Qingyu |
author_sort | Guo, Guilue |
collection | NTU |
description | The coupling of proteins with self-assembly properties and proteins that are capable of recognizing and mineralizing specific inorganic species is a promising strategy for the synthesis of nanoscale materials with controllable morphology and functionality. Herein, GPG-AG3 protein fibers with both of these properties were constructed and served as templates for the synthesis of Pt and Pd nanotubes. The protein fibers of assembled GPG-AG3 were more than 10 μm long and had diameters of 20–50 nm. The as-synthesized Pt and Pd nanotubes were composed of dense layers of ∼3–5 nm Pt and Pd nanoparticles. When tested as cathodes in lithium-O2 batteries, the porous Pt nanotubes showed low charge potentials of 3.8 V, with round-trip efficiencies of about 65 % at a current density of 100 mA g−1. |
first_indexed | 2024-10-01T07:19:45Z |
format | Journal Article |
id | ntu-10356/105302 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T07:19:45Z |
publishDate | 2014 |
record_format | dspace |
spelling | ntu-10356/1053022020-06-01T10:21:17Z Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries Guo, Guilue Truong, Thi Hong Anh Tan, Huiteng Ang, Huixiang Zhang, Wenyu Xu, Chen Rui, Xianghong Hu, Zhaolong Fong, Eileen Yan, Qingyu School of Materials Science & Engineering DRNTU::Science::Chemistry The coupling of proteins with self-assembly properties and proteins that are capable of recognizing and mineralizing specific inorganic species is a promising strategy for the synthesis of nanoscale materials with controllable morphology and functionality. Herein, GPG-AG3 protein fibers with both of these properties were constructed and served as templates for the synthesis of Pt and Pd nanotubes. The protein fibers of assembled GPG-AG3 were more than 10 μm long and had diameters of 20–50 nm. The as-synthesized Pt and Pd nanotubes were composed of dense layers of ∼3–5 nm Pt and Pd nanoparticles. When tested as cathodes in lithium-O2 batteries, the porous Pt nanotubes showed low charge potentials of 3.8 V, with round-trip efficiencies of about 65 % at a current density of 100 mA g−1. 2014-09-15T02:56:50Z 2019-12-06T21:48:57Z 2014-09-15T02:56:50Z 2019-12-06T21:48:57Z 2014 2014 Journal Article Guo, G., Truong, T. H. A., Tan, H., Ang, H., Zhang, W., Xu, C., et al. Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries. Chemistry - an Asian journal, 9(9), 2555-2559. 1861-4728 https://hdl.handle.net/10356/105302 http://hdl.handle.net/10220/20683 10.1002/asia.201402191 en Chemistry - an Asian journal © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
spellingShingle | DRNTU::Science::Chemistry Guo, Guilue Truong, Thi Hong Anh Tan, Huiteng Ang, Huixiang Zhang, Wenyu Xu, Chen Rui, Xianghong Hu, Zhaolong Fong, Eileen Yan, Qingyu Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries |
title | Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries |
title_full | Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries |
title_fullStr | Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries |
title_full_unstemmed | Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries |
title_short | Platinum and palladium nanotubes based on genetically engineered elastin-mimetic fusion protein-fiber templates : synthesis and application in lithium-O2 batteries |
title_sort | platinum and palladium nanotubes based on genetically engineered elastin mimetic fusion protein fiber templates synthesis and application in lithium o2 batteries |
topic | DRNTU::Science::Chemistry |
url | https://hdl.handle.net/10356/105302 http://hdl.handle.net/10220/20683 |
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