A well-defined aluminum-based lewis acid as an effective catalyst for Diels-Alder transformations
A catalytically active aluminum-based system for Diels–Alder transformations is reported. The system was generated by mixing a β-diketiminate-stabilized aluminum bistriflate compound with Na[BArCl4] (ArCl=3,5-Cl2C6H3). Solid-state analysis of the catalytic system reveals a unique structure incorpora...
| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2015
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| Online Access: | https://hdl.handle.net/10356/106139 http://hdl.handle.net/10220/26340 http://dx.doi.org/10.1002/chem.201502205 |
| _version_ | 1826113547021582336 |
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| author | Liu, Zhizhou Lee, Jazreen Hui Qi Ganguly, Rakesh Vidović, Dragoslav |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Liu, Zhizhou Lee, Jazreen Hui Qi Ganguly, Rakesh Vidović, Dragoslav |
| author_sort | Liu, Zhizhou |
| collection | NTU |
| description | A catalytically active aluminum-based system for Diels–Alder transformations is reported. The system was generated by mixing a β-diketiminate-stabilized aluminum bistriflate compound with Na[BArCl4] (ArCl=3,5-Cl2C6H3). Solid-state analysis of the catalytic system reveals a unique structure incorporating a two-dimensional coordination polymer. According to the experimental results obtained from several Diels–Alder transformations, the aluminum-based system appears to be a more practical and more robust alternative to the recently reported compounds based on carbon and silicon cations. |
| first_indexed | 2024-10-01T03:25:00Z |
| format | Journal Article |
| id | ntu-10356/106139 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:25:00Z |
| publishDate | 2015 |
| record_format | dspace |
| spelling | ntu-10356/1061392019-12-06T22:05:21Z A well-defined aluminum-based lewis acid as an effective catalyst for Diels-Alder transformations Liu, Zhizhou Lee, Jazreen Hui Qi Ganguly, Rakesh Vidović, Dragoslav School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Physical chemistry::Catalysis A catalytically active aluminum-based system for Diels–Alder transformations is reported. The system was generated by mixing a β-diketiminate-stabilized aluminum bistriflate compound with Na[BArCl4] (ArCl=3,5-Cl2C6H3). Solid-state analysis of the catalytic system reveals a unique structure incorporating a two-dimensional coordination polymer. According to the experimental results obtained from several Diels–Alder transformations, the aluminum-based system appears to be a more practical and more robust alternative to the recently reported compounds based on carbon and silicon cations. 2015-07-07T09:16:04Z 2019-12-06T22:05:21Z 2015-07-07T09:16:04Z 2019-12-06T22:05:21Z 2015 2015 Journal Article Liu, Z., Lee, J. H. Q., Ganguly, R., & Vidović, D. (2015). A well-defined aluminum-based lewis acid as an effective catalyst for Diels-Alder transformations. Chemistry - A European Journal, 21(32), 11344-11348. 0947-6539 https://hdl.handle.net/10356/106139 http://hdl.handle.net/10220/26340 http://dx.doi.org/10.1002/chem.201502205 en Chemistry - A European Journal © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| spellingShingle | DRNTU::Science::Chemistry::Physical chemistry::Catalysis Liu, Zhizhou Lee, Jazreen Hui Qi Ganguly, Rakesh Vidović, Dragoslav A well-defined aluminum-based lewis acid as an effective catalyst for Diels-Alder transformations |
| title | A well-defined aluminum-based lewis acid as an effective catalyst for Diels-Alder transformations |
| title_full | A well-defined aluminum-based lewis acid as an effective catalyst for Diels-Alder transformations |
| title_fullStr | A well-defined aluminum-based lewis acid as an effective catalyst for Diels-Alder transformations |
| title_full_unstemmed | A well-defined aluminum-based lewis acid as an effective catalyst for Diels-Alder transformations |
| title_short | A well-defined aluminum-based lewis acid as an effective catalyst for Diels-Alder transformations |
| title_sort | well defined aluminum based lewis acid as an effective catalyst for diels alder transformations |
| topic | DRNTU::Science::Chemistry::Physical chemistry::Catalysis |
| url | https://hdl.handle.net/10356/106139 http://hdl.handle.net/10220/26340 http://dx.doi.org/10.1002/chem.201502205 |
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