A new three-dimensional (3D) multilayer organic material : synthesis, swelling, exfoliation, and application
A novel fully rigid, rod-shaped oligo(p-benzamide) (OPBA-6) molecule was designed and synthesized, which can be recrystallized into a three-dimensional (3D) multilayer material via an antiparallel molecular packing model. Intermolecular hydrogen bonding and π–π interaction are brought to ensure a st...
| Main Authors: | , , , , , , , , , |
|---|---|
| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/106182 http://hdl.handle.net/10220/17074 http://dx.doi.org/10.1021/la400206s |
| _version_ | 1826124858167132160 |
|---|---|
| author | Xu, Lu Huang, Youju Li, Junjun Wang, Daoliang Li, Liangbin Chen, Mingming Tao, Jiaojiao Cui, Kunpeng Pan, Guoqiang Huang, Ningdong |
| author2 | School of Chemical and Biomedical Engineering |
| author_facet | School of Chemical and Biomedical Engineering Xu, Lu Huang, Youju Li, Junjun Wang, Daoliang Li, Liangbin Chen, Mingming Tao, Jiaojiao Cui, Kunpeng Pan, Guoqiang Huang, Ningdong |
| author_sort | Xu, Lu |
| collection | NTU |
| description | A novel fully rigid, rod-shaped oligo(p-benzamide) (OPBA-6) molecule was designed and synthesized, which can be recrystallized into a three-dimensional (3D) multilayer material via an antiparallel molecular packing model. Intermolecular hydrogen bonding and π–π interaction are brought to ensure a strong intralayer interaction, while decoration of layer surface with sulfonic groups promotes water to enter interlayer space and facilitates the swelling and exfoliation of sample. With a simple dispersion in water, the obtained multilayer material can be easily swollen by water without destruction of in-plane morphology and subsequently delaminated into 2D nanosheets with thickness of about 5.38 nm. This achievement may be the first attempt to exfoliate layered organic materials and thus provide a new strategy to prepare 2D organic nanosheets without using any substrates or templates as required by conventional and widely used self-assembly routes. Based on exfoliated nanosheets, poly(vinyl alcohol) nanocomposites were prepared using a simple water solution processing method. A 64% increase in tensile stress and a 63% improvement in Young’s modulus were achieved by addition of 7 wt % OPBA-6 loading. |
| first_indexed | 2024-10-01T06:27:13Z |
| format | Journal Article |
| id | ntu-10356/106182 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:27:13Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/1061822019-12-06T22:05:54Z A new three-dimensional (3D) multilayer organic material : synthesis, swelling, exfoliation, and application Xu, Lu Huang, Youju Li, Junjun Wang, Daoliang Li, Liangbin Chen, Mingming Tao, Jiaojiao Cui, Kunpeng Pan, Guoqiang Huang, Ningdong School of Chemical and Biomedical Engineering DRNTU::Science::Chemistry::Organic chemistry A novel fully rigid, rod-shaped oligo(p-benzamide) (OPBA-6) molecule was designed and synthesized, which can be recrystallized into a three-dimensional (3D) multilayer material via an antiparallel molecular packing model. Intermolecular hydrogen bonding and π–π interaction are brought to ensure a strong intralayer interaction, while decoration of layer surface with sulfonic groups promotes water to enter interlayer space and facilitates the swelling and exfoliation of sample. With a simple dispersion in water, the obtained multilayer material can be easily swollen by water without destruction of in-plane morphology and subsequently delaminated into 2D nanosheets with thickness of about 5.38 nm. This achievement may be the first attempt to exfoliate layered organic materials and thus provide a new strategy to prepare 2D organic nanosheets without using any substrates or templates as required by conventional and widely used self-assembly routes. Based on exfoliated nanosheets, poly(vinyl alcohol) nanocomposites were prepared using a simple water solution processing method. A 64% increase in tensile stress and a 63% improvement in Young’s modulus were achieved by addition of 7 wt % OPBA-6 loading. 2013-10-30T06:13:10Z 2019-12-06T22:05:54Z 2013-10-30T06:13:10Z 2019-12-06T22:05:54Z 2013 2013 Journal Article Xu, L., Huang, Y., Li, J., Wang, D., Chen, M., Tao, J., et al. (2013). A new three-dimensional (3D) multilayer organic material: synthesis, swelling, exfoliation, and application. Langmuir, 29(11), 3813-3820. https://hdl.handle.net/10356/106182 http://hdl.handle.net/10220/17074 http://dx.doi.org/10.1021/la400206s en Langmuir © 2013 American Chemical Society |
| spellingShingle | DRNTU::Science::Chemistry::Organic chemistry Xu, Lu Huang, Youju Li, Junjun Wang, Daoliang Li, Liangbin Chen, Mingming Tao, Jiaojiao Cui, Kunpeng Pan, Guoqiang Huang, Ningdong A new three-dimensional (3D) multilayer organic material : synthesis, swelling, exfoliation, and application |
| title | A new three-dimensional (3D) multilayer organic material : synthesis, swelling, exfoliation, and application |
| title_full | A new three-dimensional (3D) multilayer organic material : synthesis, swelling, exfoliation, and application |
| title_fullStr | A new three-dimensional (3D) multilayer organic material : synthesis, swelling, exfoliation, and application |
| title_full_unstemmed | A new three-dimensional (3D) multilayer organic material : synthesis, swelling, exfoliation, and application |
| title_short | A new three-dimensional (3D) multilayer organic material : synthesis, swelling, exfoliation, and application |
| title_sort | new three dimensional 3d multilayer organic material synthesis swelling exfoliation and application |
| topic | DRNTU::Science::Chemistry::Organic chemistry |
| url | https://hdl.handle.net/10356/106182 http://hdl.handle.net/10220/17074 http://dx.doi.org/10.1021/la400206s |
| work_keys_str_mv | AT xulu anewthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT huangyouju anewthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT lijunjun anewthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT wangdaoliang anewthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT liliangbin anewthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT chenmingming anewthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT taojiaojiao anewthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT cuikunpeng anewthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT panguoqiang anewthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT huangningdong anewthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT xulu newthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT huangyouju newthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT lijunjun newthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT wangdaoliang newthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT liliangbin newthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT chenmingming newthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT taojiaojiao newthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT cuikunpeng newthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT panguoqiang newthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication AT huangningdong newthreedimensional3dmultilayerorganicmaterialsynthesisswellingexfoliationandapplication |