Integrated charge transfer in colloidal Cu-MnO heterostructures for high-performance lithium-ion batteries
Nanodimensional monodispersed Cu–MnO heterostructures were synthesized via a facile solution-based method. Cu–MnO heterostructures with narrow size distribution were successfully achieved in the presence of organic surfactants to prevent agglomeration during the growth process. Furthermore, the uniq...
| Main Authors: | , , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2014
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/106518 http://hdl.handle.net/10220/24432 |
| _version_ | 1826121063869710336 |
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| author | Tan, Hui Teng Rui, Xianhong Lu, Ziyang Xu, Chen Liu, Weiling Hng, Huey Hoon Yan, Qingyu |
| author2 | School of Materials Science and Engineering |
| author_facet | School of Materials Science and Engineering Tan, Hui Teng Rui, Xianhong Lu, Ziyang Xu, Chen Liu, Weiling Hng, Huey Hoon Yan, Qingyu |
| author_sort | Tan, Hui Teng |
| collection | NTU |
| description | Nanodimensional monodispersed Cu–MnO heterostructures were synthesized via a facile solution-based method. Cu–MnO heterostructures with narrow size distribution were successfully achieved in the presence of organic surfactants to prevent agglomeration during the growth process. Furthermore, the unique architecture of carbon-coated Cu–MnO (Cu–MnO@C) core–shell heterostructures obtained after a thermal annealing process preserved the electrical integrity of the electrode via the conductive copper “nanobridge” to provide an efficient electron transfer pathway between the active materials and the current collector. On the other hand, the amorphous carbonaceous shell evidently gives a protective layer to attain structural integrity throughout the electrochemical measurements. Enhancement in the electrochemical performance can be reflected by the excellent cycling stability and high rate capability of the Cu–MnO@C heterostructures as compared to the MnO@C nanoparticles. |
| first_indexed | 2024-10-01T05:26:37Z |
| format | Journal Article |
| id | ntu-10356/106518 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T05:26:37Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | ntu-10356/1065182021-01-14T08:27:40Z Integrated charge transfer in colloidal Cu-MnO heterostructures for high-performance lithium-ion batteries Tan, Hui Teng Rui, Xianhong Lu, Ziyang Xu, Chen Liu, Weiling Hng, Huey Hoon Yan, Qingyu School of Materials Science and Engineering Energy Research Institute @ NTU (ERI@N) DRNTU::Engineering::Materials::Energy materials Nanodimensional monodispersed Cu–MnO heterostructures were synthesized via a facile solution-based method. Cu–MnO heterostructures with narrow size distribution were successfully achieved in the presence of organic surfactants to prevent agglomeration during the growth process. Furthermore, the unique architecture of carbon-coated Cu–MnO (Cu–MnO@C) core–shell heterostructures obtained after a thermal annealing process preserved the electrical integrity of the electrode via the conductive copper “nanobridge” to provide an efficient electron transfer pathway between the active materials and the current collector. On the other hand, the amorphous carbonaceous shell evidently gives a protective layer to attain structural integrity throughout the electrochemical measurements. Enhancement in the electrochemical performance can be reflected by the excellent cycling stability and high rate capability of the Cu–MnO@C heterostructures as compared to the MnO@C nanoparticles. 2014-12-11T03:08:37Z 2019-12-06T22:13:22Z 2014-12-11T03:08:37Z 2019-12-06T22:13:22Z 2014 2014 Journal Article Tan, H. T., Rui, X., Lu, Z., Xu, C., Liu, W., Hng, H. H., et al. (2014). Integrated charge transfer in colloidal Cu-MnO heterostructures for high-performance lithium-ion batteries. The journal of physical chemistry C, 118(31), 17452-17460. 1932-7447 https://hdl.handle.net/10356/106518 http://hdl.handle.net/10220/24432 10.1021/jp505026f en The journal of physical chemistry C © 2014 American Chemical Society. |
| spellingShingle | DRNTU::Engineering::Materials::Energy materials Tan, Hui Teng Rui, Xianhong Lu, Ziyang Xu, Chen Liu, Weiling Hng, Huey Hoon Yan, Qingyu Integrated charge transfer in colloidal Cu-MnO heterostructures for high-performance lithium-ion batteries |
| title | Integrated charge transfer in colloidal Cu-MnO heterostructures for high-performance lithium-ion batteries |
| title_full | Integrated charge transfer in colloidal Cu-MnO heterostructures for high-performance lithium-ion batteries |
| title_fullStr | Integrated charge transfer in colloidal Cu-MnO heterostructures for high-performance lithium-ion batteries |
| title_full_unstemmed | Integrated charge transfer in colloidal Cu-MnO heterostructures for high-performance lithium-ion batteries |
| title_short | Integrated charge transfer in colloidal Cu-MnO heterostructures for high-performance lithium-ion batteries |
| title_sort | integrated charge transfer in colloidal cu mno heterostructures for high performance lithium ion batteries |
| topic | DRNTU::Engineering::Materials::Energy materials |
| url | https://hdl.handle.net/10356/106518 http://hdl.handle.net/10220/24432 |
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