Hole-transporting small molecules based on thiophene cores for high efficiency perovskite solar cells
Two new electron-rich molecules, 2,3,4,5-tetra[4,4′-bis(methoxyphenyl)aminophen-4“-yl]-thiophene (H111) and 4,4′,5,5′-tetra[4,4′-bis(methoxyphenyl)aminophen-4”-yl]-2,2′-bithiophene (H112), which contain thiophene cores with arylamine side groups, are reported. When used as the hole-transporting mate...
| Main Authors: | , , , , , , , |
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| Format: | Journal Article |
| Language: | English |
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2014
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| Online Access: | https://hdl.handle.net/10356/106665 http://hdl.handle.net/10220/24517 |
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| author | Mhaisalkar, Subodh Gautam Li, Hairong Fu, Kunwu Boix, Pablo P. Wong, Lydia H. Hagfeldt, Anders Grätzel, Michael Grimsdale, Andrew C. |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Mhaisalkar, Subodh Gautam Li, Hairong Fu, Kunwu Boix, Pablo P. Wong, Lydia H. Hagfeldt, Anders Grätzel, Michael Grimsdale, Andrew C. |
| author_sort | Mhaisalkar, Subodh Gautam |
| collection | NTU |
| description | Two new electron-rich molecules, 2,3,4,5-tetra[4,4′-bis(methoxyphenyl)aminophen-4“-yl]-thiophene (H111) and 4,4′,5,5′-tetra[4,4′-bis(methoxyphenyl)aminophen-4”-yl]-2,2′-bithiophene (H112), which contain thiophene cores with arylamine side groups, are reported. When used as the hole-transporting material (HTM) in perovskite-based solar cell devices, power conversion efficiencies of up to 15.4 % under AM 1.5G solar simulation were obtained. This is the highest efficiency achieved with HTMs not composed of 2,2′,7,7′-tetrakis(N,N′-di-p-methoxyphenylamine)-9,9′-spirobifluorene (spiro-OMeTAD) and its isomers. Both HTMs, especially H111, have great potential to replace expensive spiro-OMeTAD given their much simpler and less expensive syntheses. |
| first_indexed | 2025-02-19T04:03:04Z |
| format | Journal Article |
| id | ntu-10356/106665 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2025-02-19T04:03:04Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | ntu-10356/1066652021-01-08T07:59:52Z Hole-transporting small molecules based on thiophene cores for high efficiency perovskite solar cells Mhaisalkar, Subodh Gautam Li, Hairong Fu, Kunwu Boix, Pablo P. Wong, Lydia H. Hagfeldt, Anders Grätzel, Michael Grimsdale, Andrew C. School of Materials Science & Engineering Energy Research Institute @ NTU (ERI@N) DRNTU::Science::Chemistry::Physical chemistry::Electrochemistry Two new electron-rich molecules, 2,3,4,5-tetra[4,4′-bis(methoxyphenyl)aminophen-4“-yl]-thiophene (H111) and 4,4′,5,5′-tetra[4,4′-bis(methoxyphenyl)aminophen-4”-yl]-2,2′-bithiophene (H112), which contain thiophene cores with arylamine side groups, are reported. When used as the hole-transporting material (HTM) in perovskite-based solar cell devices, power conversion efficiencies of up to 15.4 % under AM 1.5G solar simulation were obtained. This is the highest efficiency achieved with HTMs not composed of 2,2′,7,7′-tetrakis(N,N′-di-p-methoxyphenylamine)-9,9′-spirobifluorene (spiro-OMeTAD) and its isomers. Both HTMs, especially H111, have great potential to replace expensive spiro-OMeTAD given their much simpler and less expensive syntheses. 2014-12-22T06:27:56Z 2019-12-06T22:15:52Z 2014-12-22T06:27:56Z 2019-12-06T22:15:52Z 2014 2014 Journal Article Li, H., Fu, K., Boix, P. P., Wong, L. H., Hagfeldt, A., Grätzel, M., et al. (2014). Hole-transporting small molecules based on thiophene cores for high efficiency perovskite solar cells. ChemSusChem, 7(12), 3420-3425. 1864-5631 https://hdl.handle.net/10356/106665 http://hdl.handle.net/10220/24517 10.1002/cssc.201402587 en ChemSusChem © 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| spellingShingle | DRNTU::Science::Chemistry::Physical chemistry::Electrochemistry Mhaisalkar, Subodh Gautam Li, Hairong Fu, Kunwu Boix, Pablo P. Wong, Lydia H. Hagfeldt, Anders Grätzel, Michael Grimsdale, Andrew C. Hole-transporting small molecules based on thiophene cores for high efficiency perovskite solar cells |
| title | Hole-transporting small molecules based on thiophene cores for high efficiency perovskite solar cells |
| title_full | Hole-transporting small molecules based on thiophene cores for high efficiency perovskite solar cells |
| title_fullStr | Hole-transporting small molecules based on thiophene cores for high efficiency perovskite solar cells |
| title_full_unstemmed | Hole-transporting small molecules based on thiophene cores for high efficiency perovskite solar cells |
| title_short | Hole-transporting small molecules based on thiophene cores for high efficiency perovskite solar cells |
| title_sort | hole transporting small molecules based on thiophene cores for high efficiency perovskite solar cells |
| topic | DRNTU::Science::Chemistry::Physical chemistry::Electrochemistry |
| url | https://hdl.handle.net/10356/106665 http://hdl.handle.net/10220/24517 |
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