Palladium catalyzed asymmetric hydrophosphination of α,β- and α,β,γ,δ-unsaturated malonate esters : efficient control of reactivity, stereo- and regio-selectivity

Palladium catalyzed asymmetric hydrophosphination of α,β- and α,β,γ,δ-unsaturated malonate esters : efficient control of reactivity, stereo- and regio-selectivity

Both PC-cyclometalated and PCP-pincer type palladium catalysts have recently been found to be robust and efficacious catalysts for the asymmetric P–H addition reaction involving activated olefins. Our studies on the asymmetric P–H addition of diphenylphosphine to malonate ester and α,β,γ,δ-alkyliden...

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Bibliographic Details
Main Authors: Leung, Pak-Hing, Yang, Xiang-Yuan, Gan, Jun Hao, Li, Yongxin, Pullarkat, Sumod A.
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2015
Subjects:
DRNTU::Science::Chemistry::Inorganic chemistry::Metals
Online Access:https://hdl.handle.net/10356/106744
http://hdl.handle.net/10220/25069

Internet

https://hdl.handle.net/10356/106744
http://hdl.handle.net/10220/25069

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