Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines
We report the use of nickel catalysts for the catalytic transfer hydrogenation of hydrazones and other ketimines with formic acid. Strongly donating bisphosphines must be used to support the catalysts. As in enzymatic catalysis, attractive weak interactions may be important for stereochemical contro...
| Main Authors: | , , , , |
|---|---|
| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2015
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/107036 http://hdl.handle.net/10220/25269 http://dx.doi.org/10.1002/anie.201501018 |
| _version_ | 1824455173449187328 |
|---|---|
| author | Xu, Haiyan Yang, Peng Chuanprasit, Pratanphorn Hirao, Hajime Zhou, Steve Jianrong |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Xu, Haiyan Yang, Peng Chuanprasit, Pratanphorn Hirao, Hajime Zhou, Steve Jianrong |
| author_sort | Xu, Haiyan |
| collection | NTU |
| description | We report the use of nickel catalysts for the catalytic transfer hydrogenation of hydrazones and other ketimines with formic acid. Strongly donating bisphosphines must be used to support the catalysts. As in enzymatic catalysis, attractive weak interactions may be important for stereochemical control by the nickel/binapine catalyst. |
| first_indexed | 2025-02-19T03:34:00Z |
| format | Journal Article |
| id | ntu-10356/107036 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2025-02-19T03:34:00Z |
| publishDate | 2015 |
| record_format | dspace |
| spelling | ntu-10356/1070362019-12-06T22:23:36Z Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines Xu, Haiyan Yang, Peng Chuanprasit, Pratanphorn Hirao, Hajime Zhou, Steve Jianrong School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Physical chemistry::Catalysis We report the use of nickel catalysts for the catalytic transfer hydrogenation of hydrazones and other ketimines with formic acid. Strongly donating bisphosphines must be used to support the catalysts. As in enzymatic catalysis, attractive weak interactions may be important for stereochemical control by the nickel/binapine catalyst. 2015-03-24T07:50:44Z 2019-12-06T22:23:36Z 2015-03-24T07:50:44Z 2019-12-06T22:23:36Z 2015 2015 Journal Article Xu, H., Yang, P., Chuanprasit, P., Hirao, H., & Zhou, S. J. (2015). Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines. Angewandte chemie International edition, 54(17), 5112-5116. 1433-7851 https://hdl.handle.net/10356/107036 http://hdl.handle.net/10220/25269 http://dx.doi.org/10.1002/anie.201501018 en Angewandte chemie International edition © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| spellingShingle | DRNTU::Science::Chemistry::Physical chemistry::Catalysis Xu, Haiyan Yang, Peng Chuanprasit, Pratanphorn Hirao, Hajime Zhou, Steve Jianrong Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines |
| title | Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines |
| title_full | Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines |
| title_fullStr | Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines |
| title_full_unstemmed | Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines |
| title_short | Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines |
| title_sort | nickel catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines |
| topic | DRNTU::Science::Chemistry::Physical chemistry::Catalysis |
| url | https://hdl.handle.net/10356/107036 http://hdl.handle.net/10220/25269 http://dx.doi.org/10.1002/anie.201501018 |
| work_keys_str_mv | AT xuhaiyan nickelcatalyzedasymmetrictransferhydrogenationofhydrazonesandotherketimines AT yangpeng nickelcatalyzedasymmetrictransferhydrogenationofhydrazonesandotherketimines AT chuanprasitpratanphorn nickelcatalyzedasymmetrictransferhydrogenationofhydrazonesandotherketimines AT hiraohajime nickelcatalyzedasymmetrictransferhydrogenationofhydrazonesandotherketimines AT zhoustevejianrong nickelcatalyzedasymmetrictransferhydrogenationofhydrazonesandotherketimines |