High-performance asymmetric supercapacitors based on multilayer MnO2 graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability

In this work, MnO2/GO (graphene oxide) composites with novel multilayer nanoflake structure, and a carbon material derived from Artemia cyst shell with genetic 3D hierarchical porous structure (HPC), are prepared. An asymmetric supercapacitor has been fabricated using MnO2/GO as positive electrode a...

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Main Authors: Zhao, Yufeng, Ran, Wei, He, Jing, Huang, Yizhong, Liu, Zhifeng, Liu, Wei, Tang, Yongfu, Zhang, Long, Gao, Dawei, Gao, Faming
Other Authors: School of Materials Science & Engineering
Format: Journal Article
Language:English
Published: 2015
Subjects:
Online Access:https://hdl.handle.net/10356/107133
http://hdl.handle.net/10220/25360
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author Zhao, Yufeng
Ran, Wei
He, Jing
Huang, Yizhong
Liu, Zhifeng
Liu, Wei
Tang, Yongfu
Zhang, Long
Gao, Dawei
Gao, Faming
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Zhao, Yufeng
Ran, Wei
He, Jing
Huang, Yizhong
Liu, Zhifeng
Liu, Wei
Tang, Yongfu
Zhang, Long
Gao, Dawei
Gao, Faming
author_sort Zhao, Yufeng
collection NTU
description In this work, MnO2/GO (graphene oxide) composites with novel multilayer nanoflake structure, and a carbon material derived from Artemia cyst shell with genetic 3D hierarchical porous structure (HPC), are prepared. An asymmetric supercapacitor has been fabricated using MnO2/GO as positive electrode and HPC as negative electrode material. Because of their unique structures, both MnO2/GO composites and HPC exhibit excellent electrochemical performances. The optimized asymmetric supercapacitor could be cycled reversibly in the high voltage range of 0–2 V in aqueous electrolyte, which exhibits maximum energy density of 46.7 Wh kg−1 at a power density of 100 W kg−1 and remains 18.9 Wh kg−1 at 2000 W kg−1. Additionally, such device also shows superior long cycle life along with ∼100% capacitance retention after 1000 cycles and ∼93% after 4000 cycles.
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spelling ntu-10356/1071332020-06-01T10:13:41Z High-performance asymmetric supercapacitors based on multilayer MnO2 graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability Zhao, Yufeng Ran, Wei He, Jing Huang, Yizhong Liu, Zhifeng Liu, Wei Tang, Yongfu Zhang, Long Gao, Dawei Gao, Faming School of Materials Science & Engineering DRNTU::Science::Chemistry::Physical chemistry::Electrochemistry In this work, MnO2/GO (graphene oxide) composites with novel multilayer nanoflake structure, and a carbon material derived from Artemia cyst shell with genetic 3D hierarchical porous structure (HPC), are prepared. An asymmetric supercapacitor has been fabricated using MnO2/GO as positive electrode and HPC as negative electrode material. Because of their unique structures, both MnO2/GO composites and HPC exhibit excellent electrochemical performances. The optimized asymmetric supercapacitor could be cycled reversibly in the high voltage range of 0–2 V in aqueous electrolyte, which exhibits maximum energy density of 46.7 Wh kg−1 at a power density of 100 W kg−1 and remains 18.9 Wh kg−1 at 2000 W kg−1. Additionally, such device also shows superior long cycle life along with ∼100% capacitance retention after 1000 cycles and ∼93% after 4000 cycles. 2015-04-10T06:37:33Z 2019-12-06T22:25:26Z 2015-04-10T06:37:33Z 2019-12-06T22:25:26Z 2014 2014 Journal Article Zhao, Y., Ran, W., He, J., Huang, Y., Liu, Z., Liu, W., et al. (2015). High-performance asymmetric supercapacitors based on multilayer MnO2 graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability. Small, 11(11), 1310-1319. 1613-6810 https://hdl.handle.net/10356/107133 http://hdl.handle.net/10220/25360 10.1002/smll.201401922 en Small © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
spellingShingle DRNTU::Science::Chemistry::Physical chemistry::Electrochemistry
Zhao, Yufeng
Ran, Wei
He, Jing
Huang, Yizhong
Liu, Zhifeng
Liu, Wei
Tang, Yongfu
Zhang, Long
Gao, Dawei
Gao, Faming
High-performance asymmetric supercapacitors based on multilayer MnO2 graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability
title High-performance asymmetric supercapacitors based on multilayer MnO2 graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability
title_full High-performance asymmetric supercapacitors based on multilayer MnO2 graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability
title_fullStr High-performance asymmetric supercapacitors based on multilayer MnO2 graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability
title_full_unstemmed High-performance asymmetric supercapacitors based on multilayer MnO2 graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability
title_short High-performance asymmetric supercapacitors based on multilayer MnO2 graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability
title_sort high performance asymmetric supercapacitors based on multilayer mno2 graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability
topic DRNTU::Science::Chemistry::Physical chemistry::Electrochemistry
url https://hdl.handle.net/10356/107133
http://hdl.handle.net/10220/25360
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