A simple process to prepare nitrogen-modified few-layer graphene for a supercapacitor electrode

We report a simple approach to prepare the nitrogen-modified few-layer graphene (FLG) directly from graphite flakes. With the aid of melamine, graphite flakes can be directly ultrasonicated into FLG in acetone. The subsequent annealing process further transforms the melamine absorbed on the surface...

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Bibliographic Details
Main Authors: Xiao, Ni, Lau, Damien, Shi, Wenhui, Zhu, Jixin, Dong, Xiaochen, Hng, Huey Hoon, Yan, Qingyu
Other Authors: School of Materials Science and Engineering
Format: Journal Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/107203
http://hdl.handle.net/10220/17717
Description
Summary:We report a simple approach to prepare the nitrogen-modified few-layer graphene (FLG) directly from graphite flakes. With the aid of melamine, graphite flakes can be directly ultrasonicated into FLG in acetone. The subsequent annealing process further transforms the melamine absorbed on the surface of graphene into melon (C6N9H3)x, which is one type of condensation product of melamine, and simultaneously dopes the graphene with nitrogen. When tested as a supercapacitor electrode, the nitrogen-modified FLG shows a much higher specific capacitance (e.g., 227 F/g at 1A/g) than that of reduced graphene oxide (rGO) (e.g., 133 F/g at 1A/g).