Research progress on negative electrodes for practical li-ion batteries : beyond carbonaceous anodes
Research activities related to the development of negative electrodes for construction of high-performance Li-ion batteries (LIBs) with conventional cathodes such as LiCoO2, LiFePO4, and LiMn2O4 are described. The anode materials are classified in to three main categories, insertion, conversion, and...
| Main Authors: | , , |
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| Format: | Journal Article |
| Language: | English |
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2015
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| Online Access: | https://hdl.handle.net/10356/107342 http://hdl.handle.net/10220/25481 |
| _version_ | 1826112778217193472 |
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| author | Aravindan, Vanchiappan Lee, Yun-Sung Madhavi, Srinivasan |
| author2 | School of Materials Science and Engineering |
| author_facet | School of Materials Science and Engineering Aravindan, Vanchiappan Lee, Yun-Sung Madhavi, Srinivasan |
| author_sort | Aravindan, Vanchiappan |
| collection | NTU |
| description | Research activities related to the development of negative electrodes for construction of high-performance Li-ion batteries (LIBs) with conventional cathodes such as LiCoO2, LiFePO4, and LiMn2O4 are described. The anode materials are classified in to three main categories, insertion, conversion, and alloying type, based on their reactivity with Li. Although numerous materials have been proposed (i.e., for half-cell assembly), few of them have reached commercial applications, apart from graphite, Li4Ti5O12, Si, and Sn-Co-C. This clearly demonstrates that full-cell studies are desperately needed rather than just characterizing materials in half-cell assemblies. Additionally, the performance of such anodes in practical Li-ion configurations (full-cell) is much more important than merely proposing materials for LIBs. Irreversible capacity loss, huge volume variation, unstable solid electrolyte interface layer formation, and poor cycleability are the main issues for conversion and alloy type anodes. This review addresses how best to circumvent the mentioned issues during the construction of Li-ion cells and the future prospects of such anodes are described in detail. |
| first_indexed | 2024-10-01T03:12:22Z |
| format | Journal Article |
| id | ntu-10356/107342 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:12:22Z |
| publishDate | 2015 |
| record_format | dspace |
| spelling | ntu-10356/1073422021-01-14T07:24:32Z Research progress on negative electrodes for practical li-ion batteries : beyond carbonaceous anodes Aravindan, Vanchiappan Lee, Yun-Sung Madhavi, Srinivasan School of Materials Science and Engineering Energy Research Institute @ NTU (ERI@N) DRNTU::Engineering::Materials::Energy materials Research activities related to the development of negative electrodes for construction of high-performance Li-ion batteries (LIBs) with conventional cathodes such as LiCoO2, LiFePO4, and LiMn2O4 are described. The anode materials are classified in to three main categories, insertion, conversion, and alloying type, based on their reactivity with Li. Although numerous materials have been proposed (i.e., for half-cell assembly), few of them have reached commercial applications, apart from graphite, Li4Ti5O12, Si, and Sn-Co-C. This clearly demonstrates that full-cell studies are desperately needed rather than just characterizing materials in half-cell assemblies. Additionally, the performance of such anodes in practical Li-ion configurations (full-cell) is much more important than merely proposing materials for LIBs. Irreversible capacity loss, huge volume variation, unstable solid electrolyte interface layer formation, and poor cycleability are the main issues for conversion and alloy type anodes. This review addresses how best to circumvent the mentioned issues during the construction of Li-ion cells and the future prospects of such anodes are described in detail. 2015-05-08T08:01:37Z 2019-12-06T22:29:07Z 2015-05-08T08:01:37Z 2019-12-06T22:29:07Z 2015 2015 Journal Article Aravindan, V., Lee, Y.-S., & Madhavi, S. (2015). Research progress on negative electrodes for practical li-ion batteries : beyond carbonaceous anodes. Advanced energy materials, 5(13), 1402225-. 1614-6832 https://hdl.handle.net/10356/107342 http://hdl.handle.net/10220/25481 10.1002/aenm.201402225 en Advanced energy materials © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| spellingShingle | DRNTU::Engineering::Materials::Energy materials Aravindan, Vanchiappan Lee, Yun-Sung Madhavi, Srinivasan Research progress on negative electrodes for practical li-ion batteries : beyond carbonaceous anodes |
| title | Research progress on negative electrodes for practical li-ion batteries : beyond carbonaceous anodes |
| title_full | Research progress on negative electrodes for practical li-ion batteries : beyond carbonaceous anodes |
| title_fullStr | Research progress on negative electrodes for practical li-ion batteries : beyond carbonaceous anodes |
| title_full_unstemmed | Research progress on negative electrodes for practical li-ion batteries : beyond carbonaceous anodes |
| title_short | Research progress on negative electrodes for practical li-ion batteries : beyond carbonaceous anodes |
| title_sort | research progress on negative electrodes for practical li ion batteries beyond carbonaceous anodes |
| topic | DRNTU::Engineering::Materials::Energy materials |
| url | https://hdl.handle.net/10356/107342 http://hdl.handle.net/10220/25481 |
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