Trapping of the putative 1,2-dinitrosoarene intermediate of benzofuroxan tautomerization by coordination at ruthenium and exploration of its redox non-innocence
The reaction of a benzofuroxan with [Ru([9]aneS3)(dmso)Cl2] ([9]aneS3 = 1,4,7-trithiacyclononane) and [Ru(bpy)2(CH3CN)2]2+ yields the ruthenium complexes [Ru([9]aneS3)(ON^NO)(Cl)]+ (1a–c) and [Ru(bpy)2(ON^NO)]n+ (n = 2: 2a and 2b; n = 1: 2a− and 2b−), respectively, containing neutral or monoanionic...
Những tác giả chính: | Chan, Siu-Chung, England, Jason, Wieghardt, Karl, Wong, Chun-Yuen |
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Tác giả khác: | School of Physical and Mathematical Sciences |
Định dạng: | Journal Article |
Ngôn ngữ: | English |
Được phát hành: |
2015
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Những chủ đề: | |
Truy cập trực tuyến: | https://hdl.handle.net/10356/107442 http://hdl.handle.net/10220/25485 |
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