Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis
The ruthenacyclic carbamoyl complexes [RuX{2-NHC(O)C5H3NR}(CO)2(NCMe)] (R = H and Me; X = Br and SC6H3-o,o-Me2) are excellent catalysts for the hydrolysis of organosilanes, particularly towards primary silanes, generating hydrogen under ambient conditions within seconds. These complexes are structur...
| Main Authors: | , , , |
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| Format: | Journal Article |
| Language: | English |
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2020
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| Online Access: | https://hdl.handle.net/10356/136693 |
| _version_ | 1826121916184788992 |
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| author | Barik, Chandan Kr Ganguly, Rakesh Li, Yongxin Leong, Weng Kee |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Barik, Chandan Kr Ganguly, Rakesh Li, Yongxin Leong, Weng Kee |
| author_sort | Barik, Chandan Kr |
| collection | NTU |
| description | The ruthenacyclic carbamoyl complexes [RuX{2-NHC(O)C5H3NR}(CO)2(NCMe)] (R = H and Me; X = Br and SC6H3-o,o-Me2) are excellent catalysts for the hydrolysis of organosilanes, particularly towards primary silanes, generating hydrogen under ambient conditions within seconds. These complexes are structural mimics of the [Fe]-hydrogenase active site and like the natural enzyme, a labile ligand at the sixth coordination site is essential to the catalytic activity. |
| first_indexed | 2024-10-01T05:39:59Z |
| format | Journal Article |
| id | ntu-10356/136693 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T05:39:59Z |
| publishDate | 2020 |
| record_format | dspace |
| spelling | ntu-10356/1366932023-02-28T20:02:06Z Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis Barik, Chandan Kr Ganguly, Rakesh Li, Yongxin Leong, Weng Kee School of Physical and Mathematical Sciences Science::Chemistry Science::Chemistry::Inorganic chemistry Organosilane Hydrolysis Ruthenacyclic Carbamoyl Complex The ruthenacyclic carbamoyl complexes [RuX{2-NHC(O)C5H3NR}(CO)2(NCMe)] (R = H and Me; X = Br and SC6H3-o,o-Me2) are excellent catalysts for the hydrolysis of organosilanes, particularly towards primary silanes, generating hydrogen under ambient conditions within seconds. These complexes are structural mimics of the [Fe]-hydrogenase active site and like the natural enzyme, a labile ligand at the sixth coordination site is essential to the catalytic activity. ASTAR (Agency for Sci., Tech. and Research, S’pore) MOE (Min. of Education, S’pore) Accepted version 2020-01-10T06:37:06Z 2020-01-10T06:37:06Z 2018 Journal Article Barik, C. K., Ganguly, R., Li, Y., & Leong, W. K. (2018). Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis. European Journal of Inorganic Chemistry, 2018(46), 4982-4986. doi:10.1002/ejic.201801012 1434-1948 https://hdl.handle.net/10356/136693 10.1002/ejic.201801012 2-s2.0-85057577457 46 2018 4982 4986 en European Journal of Inorganic Chemistry This is the peer reviewed version of the following article: Barik, C. K., Ganguly, R., Li, Y., & Leong, W. K. (2018). Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis. European Journal of Inorganic Chemistry, 2018(46), 4982-4986. doi:10.1002/ejic.201801012, which has been published in final form at 10.1002/ejic.201801012. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. application/pdf |
| spellingShingle | Science::Chemistry Science::Chemistry::Inorganic chemistry Organosilane Hydrolysis Ruthenacyclic Carbamoyl Complex Barik, Chandan Kr Ganguly, Rakesh Li, Yongxin Leong, Weng Kee Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis |
| title | Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis |
| title_full | Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis |
| title_fullStr | Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis |
| title_full_unstemmed | Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis |
| title_short | Ruthenacyclic carbamoyl complexes : highly efficient catalysts for organosilane hydrolysis |
| title_sort | ruthenacyclic carbamoyl complexes highly efficient catalysts for organosilane hydrolysis |
| topic | Science::Chemistry Science::Chemistry::Inorganic chemistry Organosilane Hydrolysis Ruthenacyclic Carbamoyl Complex |
| url | https://hdl.handle.net/10356/136693 |
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