Synthesis of a base-stabilized silicon(I)-iron(II) complex for hydroboration of carbonyl compounds
The reaction of the amidinatosilicon(I) dimer [LSi:]2 (1; L = PhC(N tBu)2) with FeBr2 in tetrahydrofuran (THF) at ambient temperature afforded the silicon(I)-iron(II) dimer [LSi(FeBr2·THF)]2 (2) after 40 h. Compound 2 can catalyze hydroboration of aliphatic and aromatic ketone compounds with HBpin i...
| Main Authors: | , , , |
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| 其他作者: | |
| 格式: | Journal Article |
| 语言: | English |
| 出版: |
2020
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| 主题: | |
| 在线阅读: | https://hdl.handle.net/10356/136861 |