Titanium-based metal–organic frameworks for photocatalytic applications
Titanium-based metal–organic frameworks (Ti-MOFs) are considered one of the most appealing subclasses of the MOFs family owing to their promising optoelectronic and photocatalytic properties, high thermal and chemical stability, and unique structural features. Restricted by their challenging synthes...
Main Authors: | , , , , |
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Format: | Journal Article |
Language: | English |
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2020
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Online Access: | https://hdl.handle.net/10356/137599 |
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author | Zhu, Jianjun Li, Pei-Zhou Guo, Wenhan Zhao, Yanli Zou, Ruqiang |
author2 | School of Physical and Mathematical Sciences |
author_facet | School of Physical and Mathematical Sciences Zhu, Jianjun Li, Pei-Zhou Guo, Wenhan Zhao, Yanli Zou, Ruqiang |
author_sort | Zhu, Jianjun |
collection | NTU |
description | Titanium-based metal–organic frameworks (Ti-MOFs) are considered one of the most appealing subclasses of the MOFs family owing to their promising optoelectronic and photocatalytic properties, high thermal and chemical stability, and unique structural features. Restricted by their challenging synthesis, however, only limited Ti-MOFs have been reported and utilized so far. In this review, we comprehensively summarize the synthesis, structures and photocatalytic applications of Ti-MOFs reported to date, particularly focusing on the synthetic strategy to develop new Ti-MOF structures and composites as photocatalysts with high sunlight harvesting efficiency and photocatalytic activity. Photocatalytic applications including photocatalytic redox reactions, water splitting, organic pollutant degradation, polymerization, deoximation reaction and sensors are highlighted. For wider interests, other applications of Ti-MOFs are also briefly introduced. This review aims to provide up-to-date developments of Ti-MOFs beneficial to researchers who currently work or are interested in this field. |
first_indexed | 2024-10-01T05:47:03Z |
format | Journal Article |
id | ntu-10356/137599 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T05:47:03Z |
publishDate | 2020 |
record_format | dspace |
spelling | ntu-10356/1375992023-02-28T19:27:56Z Titanium-based metal–organic frameworks for photocatalytic applications Zhu, Jianjun Li, Pei-Zhou Guo, Wenhan Zhao, Yanli Zou, Ruqiang School of Physical and Mathematical Sciences Science::Chemistry Metal-organic Frameworks Photocatalysis Titanium-based metal–organic frameworks (Ti-MOFs) are considered one of the most appealing subclasses of the MOFs family owing to their promising optoelectronic and photocatalytic properties, high thermal and chemical stability, and unique structural features. Restricted by their challenging synthesis, however, only limited Ti-MOFs have been reported and utilized so far. In this review, we comprehensively summarize the synthesis, structures and photocatalytic applications of Ti-MOFs reported to date, particularly focusing on the synthetic strategy to develop new Ti-MOF structures and composites as photocatalysts with high sunlight harvesting efficiency and photocatalytic activity. Photocatalytic applications including photocatalytic redox reactions, water splitting, organic pollutant degradation, polymerization, deoximation reaction and sensors are highlighted. For wider interests, other applications of Ti-MOFs are also briefly introduced. This review aims to provide up-to-date developments of Ti-MOFs beneficial to researchers who currently work or are interested in this field. Accepted version 2020-04-06T02:59:31Z 2020-04-06T02:59:31Z 2018 Journal Article Zhu, J., Li, P.-Z., Guo, W., Zhao, Y., & Zou, R. (2018). Titanium-based metal–organic frameworks for photocatalytic applications. Coordination Chemistry Reviews, 359, 80-101. doi:10.1016/j.ccr.2017.12.013 0010-8545 https://hdl.handle.net/10356/137599 10.1016/j.ccr.2017.12.013 359 80 101 en Coordination Chemistry Reviews © 2018 Elsevier. All rights reserved. This paper was published in Coordination Chemistry Reviews and is made available with permission of Elsevier. application/pdf |
spellingShingle | Science::Chemistry Metal-organic Frameworks Photocatalysis Zhu, Jianjun Li, Pei-Zhou Guo, Wenhan Zhao, Yanli Zou, Ruqiang Titanium-based metal–organic frameworks for photocatalytic applications |
title | Titanium-based metal–organic frameworks for photocatalytic applications |
title_full | Titanium-based metal–organic frameworks for photocatalytic applications |
title_fullStr | Titanium-based metal–organic frameworks for photocatalytic applications |
title_full_unstemmed | Titanium-based metal–organic frameworks for photocatalytic applications |
title_short | Titanium-based metal–organic frameworks for photocatalytic applications |
title_sort | titanium based metal organic frameworks for photocatalytic applications |
topic | Science::Chemistry Metal-organic Frameworks Photocatalysis |
url | https://hdl.handle.net/10356/137599 |
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