A crystalline diazadiborinine radical cation and its boron-centered radical reactivity
One‐electron oxidation of 1,4,2,5‐diazadiborinine 1 has been studied. While the reaction of 1 a bearing phenyl groups on the B atoms with AgAl{OC(CF3)3}4 afforded a complex mixture, the same oxidation reaction with 1 b featuring bulky mesityl substituents on the B atoms rendered the corresponding ca...
Main Authors: | Wang, Baolin, Li, Yongxin, Ganguly, Rakesh, Webster, Richard David, Kinjo, Rei |
---|---|
Other Authors: | School of Physical and Mathematical Sciences |
Format: | Journal Article |
Language: | English |
Published: |
2020
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/137708 |
Similar Items
-
Crystalline boron-linked tetraaminoethylene radical cations
by: Su, Yuanting, et al.
Published: (2018) -
Boron-based stepwise dioxygen activation with 1,4,2,5-diazadiborinine
by: Wang, Baolin, et al.
Published: (2019) -
Engineering the frontier orbitals of a diazadiborinine for facile activation of H2, NH3, and an isonitrile
by: Su, Yuanting, et al.
Published: (2020) -
1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres
by: Wu, Di, et al.
Published: (2015) -
Polyhalides as efficient and mild oxidants for oxidative carbene organocatalysis by radical processes
by: Wu, Xingxing, et al.
Published: (2017)