A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl
A highly curved nitrogen‐containing buckybowl, which can be considered as a corannulene/azacorannulene hybrid, was synthesized and characterized. This molecule has a polycyclic aromatic C40N core, corresponding to a partial azafullerene structure C80−xNx (x=1,2,3…), and exhibits interesting properti...
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2020
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| Online Access: | https://hdl.handle.net/10356/137722 |
| _version_ | 1811680231865450496 |
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| author | Tokimaru, Yuki Ito, Shingo Nozaki, Kyoko |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Tokimaru, Yuki Ito, Shingo Nozaki, Kyoko |
| author_sort | Tokimaru, Yuki |
| collection | NTU |
| description | A highly curved nitrogen‐containing buckybowl, which can be considered as a corannulene/azacorannulene hybrid, was synthesized and characterized. This molecule has a polycyclic aromatic C40N core, corresponding to a partial azafullerene structure C80−xNx (x=1,2,3…), and exhibits interesting properties that arise from its large and highly curved π surface and the embedded nitrogen atom, which include association with C60, a lower LUMO level relative to azapentabenzocorannulene, and the formation of a radical cationic species upon oxidation. |
| first_indexed | 2024-10-01T03:21:46Z |
| format | Journal Article |
| id | ntu-10356/137722 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:21:46Z |
| publishDate | 2020 |
| record_format | dspace |
| spelling | ntu-10356/1377222020-04-13T01:09:06Z A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl Tokimaru, Yuki Ito, Shingo Nozaki, Kyoko School of Physical and Mathematical Sciences Science::Chemistry Azacorannulene Buckybowls A highly curved nitrogen‐containing buckybowl, which can be considered as a corannulene/azacorannulene hybrid, was synthesized and characterized. This molecule has a polycyclic aromatic C40N core, corresponding to a partial azafullerene structure C80−xNx (x=1,2,3…), and exhibits interesting properties that arise from its large and highly curved π surface and the embedded nitrogen atom, which include association with C60, a lower LUMO level relative to azapentabenzocorannulene, and the formation of a radical cationic species upon oxidation. 2020-04-13T01:09:05Z 2020-04-13T01:09:05Z 2018 Journal Article Tokimaru, Y., Ito, S., & Nozaki, K. (2018). A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl. Angewandte Chemie International Edition, 57(31), 9818-9822. doi:10.1002/anie.201805678 1433-7851 https://hdl.handle.net/10356/137722 10.1002/anie.201805678 29878551 2-s2.0-85050452245 31 57 9818 9822 en Angewandte Chemie International Edition © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. |
| spellingShingle | Science::Chemistry Azacorannulene Buckybowls Tokimaru, Yuki Ito, Shingo Nozaki, Kyoko A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl |
| title | A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl |
| title_full | A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl |
| title_fullStr | A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl |
| title_full_unstemmed | A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl |
| title_short | A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl |
| title_sort | hybrid of corannulene and azacorannulene synthesis of a highly curved nitrogen containing buckybowl |
| topic | Science::Chemistry Azacorannulene Buckybowls |
| url | https://hdl.handle.net/10356/137722 |
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