Metathesis in metal – organic gels (MOGs) : a facile strategy to construct robust fluorescent Ln‐MOG sensors for antibiotics and explosives
It is essential to develop new effective sensor materials for the detection of antibiotics and organic explosives, due to their negative impacts on ecosystems and human health. In this work, guided by an in situ metal‐node metathesis approach, a fluorescent metal–organic gel [MOG(Eu) gel] has been s...
| Main Authors: | , , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2020
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/137757 |
| _version_ | 1811689654580150272 |
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| author | Qin, Zheng-Sheng Dong, Wen-Wen Zhao, Jun Wu, Ya-Pan Tian, Zheng-Fang Zhang, Qichun Li, Dong-Sheng |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Qin, Zheng-Sheng Dong, Wen-Wen Zhao, Jun Wu, Ya-Pan Tian, Zheng-Fang Zhang, Qichun Li, Dong-Sheng |
| author_sort | Qin, Zheng-Sheng |
| collection | NTU |
| description | It is essential to develop new effective sensor materials for the detection of antibiotics and organic explosives, due to their negative impacts on ecosystems and human health. In this work, guided by an in situ metal‐node metathesis approach, a fluorescent metal–organic gel [MOG(Eu) gel] has been synthesized for the first time by metal‐ion exchange between Eu3+ and Al3+ in the nonfluorescent MOG(Al) gel. More importantly, the postsynthetic MOG(Eu) xerogel shows remarkable selective detection ability towards ronidazole (RDZ), ornidazole (ODZ), metronidazole (MDZ), and dimetridazole (DTZ) antibiotics, as well as 4‐nitrophenol (4‐NP), with low detection limits of 1.205, 0.542, 0.999, 0.377, and 1.582 ppm, respectively. The high quenching efficiencies can be attributed to the decrease of effective energy transfer in the host–guest systems. The strategy of metathesis opens up new opportunities for synthetic methods and functional applications in MOGs materials. |
| first_indexed | 2024-10-01T05:51:32Z |
| format | Journal Article |
| id | ntu-10356/137757 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T05:51:32Z |
| publishDate | 2020 |
| record_format | dspace |
| spelling | ntu-10356/1377572020-06-01T10:13:56Z Metathesis in metal – organic gels (MOGs) : a facile strategy to construct robust fluorescent Ln‐MOG sensors for antibiotics and explosives Qin, Zheng-Sheng Dong, Wen-Wen Zhao, Jun Wu, Ya-Pan Tian, Zheng-Fang Zhang, Qichun Li, Dong-Sheng School of Materials Science & Engineering Engineering::Materials Metal–organic Gels Metathesis It is essential to develop new effective sensor materials for the detection of antibiotics and organic explosives, due to their negative impacts on ecosystems and human health. In this work, guided by an in situ metal‐node metathesis approach, a fluorescent metal–organic gel [MOG(Eu) gel] has been synthesized for the first time by metal‐ion exchange between Eu3+ and Al3+ in the nonfluorescent MOG(Al) gel. More importantly, the postsynthetic MOG(Eu) xerogel shows remarkable selective detection ability towards ronidazole (RDZ), ornidazole (ODZ), metronidazole (MDZ), and dimetridazole (DTZ) antibiotics, as well as 4‐nitrophenol (4‐NP), with low detection limits of 1.205, 0.542, 0.999, 0.377, and 1.582 ppm, respectively. The high quenching efficiencies can be attributed to the decrease of effective energy transfer in the host–guest systems. The strategy of metathesis opens up new opportunities for synthetic methods and functional applications in MOGs materials. MOE (Min. of Education, S’pore) 2020-04-14T00:56:39Z 2020-04-14T00:56:39Z 2017 Journal Article Qin, Z.-S., Dong, W.-W., Zhao, J., Wu, Y.-P., Tian, Z.-F., Zhang, Q., & Li, D.-S. (2018). Metathesis in metal – organic gels (MOGs) : a facile strategy to construct robust fluorescent Ln‐MOG sensors for antibiotics and explosives. European Journal of Inorganic Chemistry, 2018(2), 186-193. doi:10.1002/ejic.201701339 1434-1948 https://hdl.handle.net/10356/137757 10.1002/ejic.201701339 2-s2.0-85040836364 2 2018 186 193 en European Journal of Inorganic Chemistry © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. |
| spellingShingle | Engineering::Materials Metal–organic Gels Metathesis Qin, Zheng-Sheng Dong, Wen-Wen Zhao, Jun Wu, Ya-Pan Tian, Zheng-Fang Zhang, Qichun Li, Dong-Sheng Metathesis in metal – organic gels (MOGs) : a facile strategy to construct robust fluorescent Ln‐MOG sensors for antibiotics and explosives |
| title | Metathesis in metal – organic gels (MOGs) : a facile strategy to construct robust fluorescent Ln‐MOG sensors for antibiotics and explosives |
| title_full | Metathesis in metal – organic gels (MOGs) : a facile strategy to construct robust fluorescent Ln‐MOG sensors for antibiotics and explosives |
| title_fullStr | Metathesis in metal – organic gels (MOGs) : a facile strategy to construct robust fluorescent Ln‐MOG sensors for antibiotics and explosives |
| title_full_unstemmed | Metathesis in metal – organic gels (MOGs) : a facile strategy to construct robust fluorescent Ln‐MOG sensors for antibiotics and explosives |
| title_short | Metathesis in metal – organic gels (MOGs) : a facile strategy to construct robust fluorescent Ln‐MOG sensors for antibiotics and explosives |
| title_sort | metathesis in metal organic gels mogs a facile strategy to construct robust fluorescent ln mog sensors for antibiotics and explosives |
| topic | Engineering::Materials Metal–organic Gels Metathesis |
| url | https://hdl.handle.net/10356/137757 |
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