Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization
ABC-type miktoarm star copolymers are synthesized using a single living radical polymerization (organocatalyzed living radical polymerization) via a "combinatorial" approach. The arm A is poly(butyl acrylate), the arm B is poly(methyl methacrylate), and the arm C encompasses hydrophobic an...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2020
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/137971 |
| _version_ | 1811689613412007936 |
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| author | Ge, Yicen Chen, Chen Sim, Xuan Ming Zheng, Jie Goto, Atsushi |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Ge, Yicen Chen, Chen Sim, Xuan Ming Zheng, Jie Goto, Atsushi |
| author_sort | Ge, Yicen |
| collection | NTU |
| description | ABC-type miktoarm star copolymers are synthesized using a single living radical polymerization (organocatalyzed living radical polymerization) via a "combinatorial" approach. The arm A is poly(butyl acrylate), the arm B is poly(methyl methacrylate), and the arm C encompasses hydrophobic and hydrophilic polyacrylates. A poly(butyl acrylate) with a vinyl chain end (macromonomer) is synthesized. A poly(methyl methacrylate) is subsequently connected to the reactive vinyl group to generate diblock copolymer. From the junction of the diblock copolymer, polymer C grew to yield star copolymers. An amphiphilic star copolymer is also synthesized, and its self-assembly structure is studied in an aqueous solution. |
| first_indexed | 2024-10-01T05:50:53Z |
| format | Journal Article |
| id | ntu-10356/137971 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T05:50:53Z |
| publishDate | 2020 |
| record_format | dspace |
| spelling | ntu-10356/1379712023-02-28T19:49:42Z Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization Ge, Yicen Chen, Chen Sim, Xuan Ming Zheng, Jie Goto, Atsushi School of Physical and Mathematical Sciences Science::Chemistry Miktoarm Star Copolymers Living Radical Polymerization ABC-type miktoarm star copolymers are synthesized using a single living radical polymerization (organocatalyzed living radical polymerization) via a "combinatorial" approach. The arm A is poly(butyl acrylate), the arm B is poly(methyl methacrylate), and the arm C encompasses hydrophobic and hydrophilic polyacrylates. A poly(butyl acrylate) with a vinyl chain end (macromonomer) is synthesized. A poly(methyl methacrylate) is subsequently connected to the reactive vinyl group to generate diblock copolymer. From the junction of the diblock copolymer, polymer C grew to yield star copolymers. An amphiphilic star copolymer is also synthesized, and its self-assembly structure is studied in an aqueous solution. NRF (Natl Research Foundation, S’pore) ASTAR (Agency for Sci., Tech. and Research, S’pore) Accepted version 2020-04-20T12:29:31Z 2020-04-20T12:29:31Z 2020 Journal Article Ge, Y., Chen, C., Sim, X. M., Zheng, J., & Goto, A. (2020). Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization. Macromolecular Rapid Communications, 41(5), e1900623-. doi:10.1002/marc.201900623 1521-3927 https://hdl.handle.net/10356/137971 10.1002/marc.201900623 32003518 2-s2.0-85078858806 5 41 e1900623 en Macromolecular Rapid Communications This is the peer reviewed version of the following article: Ge, Y., Chen, C., Sim, X. M., Zheng, J., & Goto, A. (2020). Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization. Macromolecular Rapid Communications, 41(5), e1900623-. doi:10.1002/marc.201900623, which has been published in final form at 10.1002/marc.201900623. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. application/pdf |
| spellingShingle | Science::Chemistry Miktoarm Star Copolymers Living Radical Polymerization Ge, Yicen Chen, Chen Sim, Xuan Ming Zheng, Jie Goto, Atsushi Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization |
| title | Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization |
| title_full | Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization |
| title_fullStr | Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization |
| title_full_unstemmed | Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization |
| title_short | Synthesis of ABC miktoarm star copolymers via organocatalyzed living radical polymerization |
| title_sort | synthesis of abc miktoarm star copolymers via organocatalyzed living radical polymerization |
| topic | Science::Chemistry Miktoarm Star Copolymers Living Radical Polymerization |
| url | https://hdl.handle.net/10356/137971 |
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