Activation of dihydrogen by 1,4,2,5-diazadiborinine
Activation of dihydrogen (H2) by 1,4,2,5-diazadiborinine is reported. Under the heating condition, treatment of 1,4,2,5-diazadiborinine with H2 results in the cleavage of H–H bond, to afford product 2, which was fully characterized by NMR and IR spectroscopy as well as X-ray diffraction and HRMS ana...
| Main Authors: | , |
|---|---|
| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2020
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/138555 |
| _version_ | 1826128024281546752 |
|---|---|
| author | Wang, Baolin Kinjo, Rei |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Wang, Baolin Kinjo, Rei |
| author_sort | Wang, Baolin |
| collection | NTU |
| description | Activation of dihydrogen (H2) by 1,4,2,5-diazadiborinine is reported. Under the heating condition, treatment of 1,4,2,5-diazadiborinine with H2 results in the cleavage of H–H bond, to afford product 2, which was fully characterized by NMR and IR spectroscopy as well as X-ray diffraction and HRMS analysis. In the presence of borane dimethylsulfide complex (BH3·SMe2), 2 readily isomerizes to 3 under the mild reaction condition. |
| first_indexed | 2024-10-01T07:18:07Z |
| format | Journal Article |
| id | ntu-10356/138555 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T07:18:07Z |
| publishDate | 2020 |
| record_format | dspace |
| spelling | ntu-10356/1385552020-05-08T04:29:03Z Activation of dihydrogen by 1,4,2,5-diazadiborinine Wang, Baolin Kinjo, Rei School of Physical and Mathematical Sciences Science::Chemistry 1,4,2,5-Diazadiborinine Dihydrogen Activation Activation of dihydrogen (H2) by 1,4,2,5-diazadiborinine is reported. Under the heating condition, treatment of 1,4,2,5-diazadiborinine with H2 results in the cleavage of H–H bond, to afford product 2, which was fully characterized by NMR and IR spectroscopy as well as X-ray diffraction and HRMS analysis. In the presence of borane dimethylsulfide complex (BH3·SMe2), 2 readily isomerizes to 3 under the mild reaction condition. MOE (Min. of Education, S’pore) 2020-05-08T04:29:03Z 2020-05-08T04:29:03Z 2018 Journal Article Wang, B., & Kinjo, R. (2018). Activation of dihydrogen by 1,4,2,5-diazadiborinine. Tetrahedron, 74(51), 7273-7276. doi:10.1016/j.tet.2018.10.067 0040-4020 https://hdl.handle.net/10356/138555 10.1016/j.tet.2018.10.067 2-s2.0-85055907392 51 74 7273 7276 en Tetrahedron © 2018 Elsevier Ltd . All rights reserved. |
| spellingShingle | Science::Chemistry 1,4,2,5-Diazadiborinine Dihydrogen Activation Wang, Baolin Kinjo, Rei Activation of dihydrogen by 1,4,2,5-diazadiborinine |
| title | Activation of dihydrogen by 1,4,2,5-diazadiborinine |
| title_full | Activation of dihydrogen by 1,4,2,5-diazadiborinine |
| title_fullStr | Activation of dihydrogen by 1,4,2,5-diazadiborinine |
| title_full_unstemmed | Activation of dihydrogen by 1,4,2,5-diazadiborinine |
| title_short | Activation of dihydrogen by 1,4,2,5-diazadiborinine |
| title_sort | activation of dihydrogen by 1 4 2 5 diazadiborinine |
| topic | Science::Chemistry 1,4,2,5-Diazadiborinine Dihydrogen Activation |
| url | https://hdl.handle.net/10356/138555 |
| work_keys_str_mv | AT wangbaolin activationofdihydrogenby1425diazadiborinine AT kinjorei activationofdihydrogenby1425diazadiborinine |