Thermal-responsive polymers for enhancing safety of electrochemical storage devices

Thermal runway constitutes the most pressing safety issue in lithium-ion batteries and supercapacitors of large-scale and high-power density due to risks of fire or explosion. However, traditional strategies for averting thermal runaway do not enable the charging-discharging rate to change according...

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Main Authors: Yang, Hui, Leow, Wan Ru, Chen, Xiaodong
Other Authors: School of Materials Science & Engineering
Format: Journal Article
Language:English
Published: 2020
Subjects:
Online Access:https://hdl.handle.net/10356/138699
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author Yang, Hui
Leow, Wan Ru
Chen, Xiaodong
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Yang, Hui
Leow, Wan Ru
Chen, Xiaodong
author_sort Yang, Hui
collection NTU
description Thermal runway constitutes the most pressing safety issue in lithium-ion batteries and supercapacitors of large-scale and high-power density due to risks of fire or explosion. However, traditional strategies for averting thermal runaway do not enable the charging-discharging rate to change according to temperature or the original performance to resume when the device is cooled to room temperature. To efficiently control thermal runaway, thermal-responsive polymers provide a feasible and reversible strategy due to their ability to sense and subsequently act according to a predetermined sequence when triggered by heat. Herein, recent research progress on the use of thermal-responsive polymers to enhance the thermal safety of electrochemical storage devices is reviewed. First, a brief discussion is provided on the methods of preventing thermal runaway in electrochemical storage devices. Subsequently, a short review is provided on the different types of thermal-responsive polymers that can efficiently avoid thermal runaway, such as phase change polymers, polymers with sol-gel transitions, and polymers with positive temperature coefficients. The results represent the important development of thermal-responsive polymers toward the prevention of thermal runaway in next-generation smart electrochemical storage devices.
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spelling ntu-10356/1386992023-07-14T16:00:54Z Thermal-responsive polymers for enhancing safety of electrochemical storage devices Yang, Hui Leow, Wan Ru Chen, Xiaodong School of Materials Science & Engineering Innovative Centre for Flexible Devices Engineering::Materials Electrochemical Storage Devices Thermal-responsive Polymers Thermal runway constitutes the most pressing safety issue in lithium-ion batteries and supercapacitors of large-scale and high-power density due to risks of fire or explosion. However, traditional strategies for averting thermal runaway do not enable the charging-discharging rate to change according to temperature or the original performance to resume when the device is cooled to room temperature. To efficiently control thermal runaway, thermal-responsive polymers provide a feasible and reversible strategy due to their ability to sense and subsequently act according to a predetermined sequence when triggered by heat. Herein, recent research progress on the use of thermal-responsive polymers to enhance the thermal safety of electrochemical storage devices is reviewed. First, a brief discussion is provided on the methods of preventing thermal runaway in electrochemical storage devices. Subsequently, a short review is provided on the different types of thermal-responsive polymers that can efficiently avoid thermal runaway, such as phase change polymers, polymers with sol-gel transitions, and polymers with positive temperature coefficients. The results represent the important development of thermal-responsive polymers toward the prevention of thermal runaway in next-generation smart electrochemical storage devices. NRF (Natl Research Foundation, S’pore) MOE (Min. of Education, S’pore) Accepted version 2020-05-12T02:34:23Z 2020-05-12T02:34:23Z 2018 Journal Article Yang, H., Leow, W. R., & Chen, X. (2018). Thermal-responsive polymers for enhancing safety of electrochemical storage devices. Advanced Materials, 30(13), 1704347-. doi:10.1002/adma.201704347 0935-9648 https://hdl.handle.net/10356/138699 10.1002/adma.201704347 29363208 2-s2.0-85040962119 13 30 1704347 (1 of 8) 1704347 (8 of 8) en Advanced Materials © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. This paper was published in Advanced Materials and is made available with permission of WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. application/pdf
spellingShingle Engineering::Materials
Electrochemical Storage Devices
Thermal-responsive Polymers
Yang, Hui
Leow, Wan Ru
Chen, Xiaodong
Thermal-responsive polymers for enhancing safety of electrochemical storage devices
title Thermal-responsive polymers for enhancing safety of electrochemical storage devices
title_full Thermal-responsive polymers for enhancing safety of electrochemical storage devices
title_fullStr Thermal-responsive polymers for enhancing safety of electrochemical storage devices
title_full_unstemmed Thermal-responsive polymers for enhancing safety of electrochemical storage devices
title_short Thermal-responsive polymers for enhancing safety of electrochemical storage devices
title_sort thermal responsive polymers for enhancing safety of electrochemical storage devices
topic Engineering::Materials
Electrochemical Storage Devices
Thermal-responsive Polymers
url https://hdl.handle.net/10356/138699
work_keys_str_mv AT yanghui thermalresponsivepolymersforenhancingsafetyofelectrochemicalstoragedevices
AT leowwanru thermalresponsivepolymersforenhancingsafetyofelectrochemicalstoragedevices
AT chenxiaodong thermalresponsivepolymersforenhancingsafetyofelectrochemicalstoragedevices