Hybridization of MOFs and COFs : a new strategy for construction of MOF@COF core–shell hybrid materials
The exploration of new porous hybrid materials is of great importance because of their unique properties and promising applications in separation of materials, catalysis, etc. Herein, for the first time, by integration of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), a new...
| Main Authors: | , , , , , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2020
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/138715 |
| _version_ | 1826125093323931648 |
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| author | Peng, Yongwu Zhao, Meiting Chen, Bo Zhang, Zhicheng Huang, Ying Dai, Fangna Lai, Zhuangchai Cui, Xiaoya Tan, Chaoliang Zhang, Hua |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Peng, Yongwu Zhao, Meiting Chen, Bo Zhang, Zhicheng Huang, Ying Dai, Fangna Lai, Zhuangchai Cui, Xiaoya Tan, Chaoliang Zhang, Hua |
| author_sort | Peng, Yongwu |
| collection | NTU |
| description | The exploration of new porous hybrid materials is of great importance because of their unique properties and promising applications in separation of materials, catalysis, etc. Herein, for the first time, by integration of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), a new type of MOF@COF core-shell hybrid material, i.e., NH2 -MIL-68@TPA-COF, with high crystallinity and hierarchical pore structure, is synthesized. As a proof-of-concept application, the obtained NH2 -MIL-68@TPA-COF hybrid material is used as an effective visible-light-driven photocatalyst for the degradation of rhodamine B. The synthetic strategy in this study opens up a new avenue for the construction of other MOF-COF hybrid materials, which could have various promising applications. |
| first_indexed | 2024-10-01T06:31:07Z |
| format | Journal Article |
| id | ntu-10356/138715 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:31:07Z |
| publishDate | 2020 |
| record_format | dspace |
| spelling | ntu-10356/1387152020-06-01T10:13:43Z Hybridization of MOFs and COFs : a new strategy for construction of MOF@COF core–shell hybrid materials Peng, Yongwu Zhao, Meiting Chen, Bo Zhang, Zhicheng Huang, Ying Dai, Fangna Lai, Zhuangchai Cui, Xiaoya Tan, Chaoliang Zhang, Hua School of Materials Science & Engineering Center for Programmable Materials Engineering::Materials Core–shell Structure Covalent Organic Frameworks The exploration of new porous hybrid materials is of great importance because of their unique properties and promising applications in separation of materials, catalysis, etc. Herein, for the first time, by integration of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), a new type of MOF@COF core-shell hybrid material, i.e., NH2 -MIL-68@TPA-COF, with high crystallinity and hierarchical pore structure, is synthesized. As a proof-of-concept application, the obtained NH2 -MIL-68@TPA-COF hybrid material is used as an effective visible-light-driven photocatalyst for the degradation of rhodamine B. The synthetic strategy in this study opens up a new avenue for the construction of other MOF-COF hybrid materials, which could have various promising applications. NRF (Natl Research Foundation, S’pore) MOE (Min. of Education, S’pore) 2020-05-12T03:48:17Z 2020-05-12T03:48:17Z 2017 Journal Article Peng, Y., Zhao, M., Chen, B., Zhang, Z., Huang, Y., Dai, F., . . . Zhang, H. (2018). Hybridization of MOFs and COFs : a new strategy for construction of MOF@COF core–shell hybrid materials. Advanced materials, 30(3), 1705454-. doi:10.1002/adma.201705454 0935-9648 https://hdl.handle.net/10356/138715 10.1002/adma.201705454 29134677 2-s2.0-85033684850 3 30 en Advanced materials © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. This paper was published in Advanced materials and is made available with permission of WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| spellingShingle | Engineering::Materials Core–shell Structure Covalent Organic Frameworks Peng, Yongwu Zhao, Meiting Chen, Bo Zhang, Zhicheng Huang, Ying Dai, Fangna Lai, Zhuangchai Cui, Xiaoya Tan, Chaoliang Zhang, Hua Hybridization of MOFs and COFs : a new strategy for construction of MOF@COF core–shell hybrid materials |
| title | Hybridization of MOFs and COFs : a new strategy for construction of MOF@COF core–shell hybrid materials |
| title_full | Hybridization of MOFs and COFs : a new strategy for construction of MOF@COF core–shell hybrid materials |
| title_fullStr | Hybridization of MOFs and COFs : a new strategy for construction of MOF@COF core–shell hybrid materials |
| title_full_unstemmed | Hybridization of MOFs and COFs : a new strategy for construction of MOF@COF core–shell hybrid materials |
| title_short | Hybridization of MOFs and COFs : a new strategy for construction of MOF@COF core–shell hybrid materials |
| title_sort | hybridization of mofs and cofs a new strategy for construction of mof cof core shell hybrid materials |
| topic | Engineering::Materials Core–shell Structure Covalent Organic Frameworks |
| url | https://hdl.handle.net/10356/138715 |
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