Nanomaterials for plant growth

Upconversion nanoparticles (UCNP) have been studied only in recent years for ap-plication in various fields such as optoelectronic, bioimaging and bioscience. The effects of varying pH and holding times, on the size, length and phases of UCNP were studied in this work by using either pure lauric aci...

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Main Author: Goh, Shermaine Shi Min
Other Authors: Lam Yeng Ming
Format: Final Year Project (FYP)
Language:English
Published: Nanyang Technological University 2020
Subjects:
Online Access:https://hdl.handle.net/10356/138903
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author Goh, Shermaine Shi Min
author2 Lam Yeng Ming
author_facet Lam Yeng Ming
Goh, Shermaine Shi Min
author_sort Goh, Shermaine Shi Min
collection NTU
description Upconversion nanoparticles (UCNP) have been studied only in recent years for ap-plication in various fields such as optoelectronic, bioimaging and bioscience. The effects of varying pH and holding times, on the size, length and phases of UCNP were studied in this work by using either pure lauric acid (LA), pure citric acid (Cit) or Cit-LA cosurfactant system at molar ratios of 4:1. Then, the produced UCNP with the optimum conditions would be used for further applications in plants, through the roots and leaves. The particles were prepared using hydrothermal autoclave synthe-sis. The surfactant ratio, reaction time and pH were investigated and optimized for desired size, shape and phase of the UCNP, and further characterized by using SEM, XRD and EDX, for this application. This study showed that differences in ligand properties, especially chelating abilities is essential in determining the particle size, shape and phase transformation. SEM images showed that out of all the experimental variations worked on, an optimal hydrothermal reaction conditions to pro-duce a mixture of hexagonal and cubic phases a & b -NaYF4:Yb,Tm with optimal av-erage diameter of 23 nm and average length of 92 nm have been determined: the re-action was done using Cit-LA cosurfactants at 4:1 molar ratio, at pH 7 and for 6 h. XRD showed that in general, for Cit-LA and LA, synthesized UCNP had both a & b phases. On the other hand, using pure Cit surfactant produced significantly larger, predominantly b phase UCNP.
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spelling ntu-10356/1389032023-03-04T15:47:38Z Nanomaterials for plant growth Goh, Shermaine Shi Min Lam Yeng Ming School of Materials Science and Engineering YMLam@ntu.edu.sg Engineering::Materials Upconversion nanoparticles (UCNP) have been studied only in recent years for ap-plication in various fields such as optoelectronic, bioimaging and bioscience. The effects of varying pH and holding times, on the size, length and phases of UCNP were studied in this work by using either pure lauric acid (LA), pure citric acid (Cit) or Cit-LA cosurfactant system at molar ratios of 4:1. Then, the produced UCNP with the optimum conditions would be used for further applications in plants, through the roots and leaves. The particles were prepared using hydrothermal autoclave synthe-sis. The surfactant ratio, reaction time and pH were investigated and optimized for desired size, shape and phase of the UCNP, and further characterized by using SEM, XRD and EDX, for this application. This study showed that differences in ligand properties, especially chelating abilities is essential in determining the particle size, shape and phase transformation. SEM images showed that out of all the experimental variations worked on, an optimal hydrothermal reaction conditions to pro-duce a mixture of hexagonal and cubic phases a & b -NaYF4:Yb,Tm with optimal av-erage diameter of 23 nm and average length of 92 nm have been determined: the re-action was done using Cit-LA cosurfactants at 4:1 molar ratio, at pH 7 and for 6 h. XRD showed that in general, for Cit-LA and LA, synthesized UCNP had both a & b phases. On the other hand, using pure Cit surfactant produced significantly larger, predominantly b phase UCNP. Bachelor of Engineering (Materials Engineering) 2020-05-13T12:32:41Z 2020-05-13T12:32:41Z 2020 Final Year Project (FYP) https://hdl.handle.net/10356/138903 en application/pdf Nanyang Technological University
spellingShingle Engineering::Materials
Goh, Shermaine Shi Min
Nanomaterials for plant growth
title Nanomaterials for plant growth
title_full Nanomaterials for plant growth
title_fullStr Nanomaterials for plant growth
title_full_unstemmed Nanomaterials for plant growth
title_short Nanomaterials for plant growth
title_sort nanomaterials for plant growth
topic Engineering::Materials
url https://hdl.handle.net/10356/138903
work_keys_str_mv AT gohshermaineshimin nanomaterialsforplantgrowth