Necklace-like structures composed of Fe3N@C yolk–shell particles as an advanced anode for sodium-ion batteries
It is of great importance to develop cost-effective electrode materials for large-scale use of Na-ion batteries. Here, a binder-free electrode based on necklace-like structures composed of Fe3 N@C yolk-shell particles as an advanced anode for Na-ion batteries is reported. In this electrode, every Fe...
Main Authors: | , , , |
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Format: | Journal Article |
Language: | English |
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2020
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Online Access: | https://hdl.handle.net/10356/138970 |
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author | Li, Zhen Fang, Yongjin Zhang, Jintao Lou, David Xiong Wen |
author2 | School of Chemical and Biomedical Engineering |
author_facet | School of Chemical and Biomedical Engineering Li, Zhen Fang, Yongjin Zhang, Jintao Lou, David Xiong Wen |
author_sort | Li, Zhen |
collection | NTU |
description | It is of great importance to develop cost-effective electrode materials for large-scale use of Na-ion batteries. Here, a binder-free electrode based on necklace-like structures composed of Fe3 N@C yolk-shell particles as an advanced anode for Na-ion batteries is reported. In this electrode, every Fe3 N@C unit has a novel yolk-shell structure, which can accommodate the volumetric changes of Fe3 N during the (de)sodiation processes for superior structural integrity. Moreover, all reaction units are threaded along the carbon fibers, guaranteeing excellent kinetics for the electrochemical reactions. As a result, when evaluated as an anode material for Na-ion batteries, the Fe3 N@C nano-necklace electrode delivers a prolonged cycle life over 300 cycles, and achieves a high C-rate capacity of 248 mAh g-1 at 2 A g-1 . |
first_indexed | 2024-10-01T07:27:21Z |
format | Journal Article |
id | ntu-10356/138970 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T07:27:21Z |
publishDate | 2020 |
record_format | dspace |
spelling | ntu-10356/1389702020-05-14T06:49:42Z Necklace-like structures composed of Fe3N@C yolk–shell particles as an advanced anode for sodium-ion batteries Li, Zhen Fang, Yongjin Zhang, Jintao Lou, David Xiong Wen School of Chemical and Biomedical Engineering Engineering::Chemical engineering Electrospinning Iron Nitrides It is of great importance to develop cost-effective electrode materials for large-scale use of Na-ion batteries. Here, a binder-free electrode based on necklace-like structures composed of Fe3 N@C yolk-shell particles as an advanced anode for Na-ion batteries is reported. In this electrode, every Fe3 N@C unit has a novel yolk-shell structure, which can accommodate the volumetric changes of Fe3 N during the (de)sodiation processes for superior structural integrity. Moreover, all reaction units are threaded along the carbon fibers, guaranteeing excellent kinetics for the electrochemical reactions. As a result, when evaluated as an anode material for Na-ion batteries, the Fe3 N@C nano-necklace electrode delivers a prolonged cycle life over 300 cycles, and achieves a high C-rate capacity of 248 mAh g-1 at 2 A g-1 . 2020-05-14T06:49:41Z 2020-05-14T06:49:41Z 2018 Journal Article Li, Z., Fang, Y., Zhang, J., & Lou, D. X. W. (2018). Necklace-like structures composed of Fe3N@C yolk-shell particles as an advanced anode for sodium-ion batteries. Advanced Materials, 30(30), 1800525-. doi:10.1002/adma.201800525 0935-9648 https://hdl.handle.net/10356/138970 10.1002/adma.201800525 29920788 2-s2.0-85050388434 30 30 en Advanced Materials © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. This paper was published in Advanced Materials and is made available with permission of WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
spellingShingle | Engineering::Chemical engineering Electrospinning Iron Nitrides Li, Zhen Fang, Yongjin Zhang, Jintao Lou, David Xiong Wen Necklace-like structures composed of Fe3N@C yolk–shell particles as an advanced anode for sodium-ion batteries |
title | Necklace-like structures composed of Fe3N@C yolk–shell particles as an advanced anode for sodium-ion batteries |
title_full | Necklace-like structures composed of Fe3N@C yolk–shell particles as an advanced anode for sodium-ion batteries |
title_fullStr | Necklace-like structures composed of Fe3N@C yolk–shell particles as an advanced anode for sodium-ion batteries |
title_full_unstemmed | Necklace-like structures composed of Fe3N@C yolk–shell particles as an advanced anode for sodium-ion batteries |
title_short | Necklace-like structures composed of Fe3N@C yolk–shell particles as an advanced anode for sodium-ion batteries |
title_sort | necklace like structures composed of fe3n c yolk shell particles as an advanced anode for sodium ion batteries |
topic | Engineering::Chemical engineering Electrospinning Iron Nitrides |
url | https://hdl.handle.net/10356/138970 |
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