Rational design of intertwined carbon nanotubes threaded porous CoP@carbon nanocubes as anode with superior lithium storage
A novel 3D porous CoP@C-CNTs composite with CNTs threaded CoP@C nanocubes is rationally designed and demonstrated as a promising anode for lithium-ion battery. The CoP@C-CNTs composite displays high surface area and abundant pores resulted from the pyrolysis of metal-organic frameworks (MOFs). CoP n...
| Үндсэн зохиолчид: | , , , , , , , , |
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| Формат: | Journal Article |
| Хэл сонгох: | English |
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2020
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| Нөхцлүүд: | |
| Онлайн хандалт: | https://hdl.handle.net/10356/138972 |
| _version_ | 1826124271696478208 |
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| author | Zhu, Peipei Zhang, Ze Zhao, Pengfei Zhang, Bowei Cao, Xun Yu, Ji Cai, Jianxin Huang, Yizhong Yang, Zhenyu |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Zhu, Peipei Zhang, Ze Zhao, Pengfei Zhang, Bowei Cao, Xun Yu, Ji Cai, Jianxin Huang, Yizhong Yang, Zhenyu |
| author_sort | Zhu, Peipei |
| collection | NTU |
| description | A novel 3D porous CoP@C-CNTs composite with CNTs threaded CoP@C nanocubes is rationally designed and demonstrated as a promising anode for lithium-ion battery. The CoP@C-CNTs composite displays high surface area and abundant pores resulted from the pyrolysis of metal-organic frameworks (MOFs). CoP nanoparticles are well encapsulated in MOFs-derived carbon nanocubes, which can effectively accommodate the volume change of active CoP during charge/discharge processes. Besides, the N/P co-doped feature induced in-situ in the synthesis process helps to improve the electrical conductivity. Moreover, the presence of intertwined CNTs network threaded CoP@C nanocubes is the vital part for rapid electron transportation within the whole electrode. As a result, the CoP@C-CNTs electrode exhibits a high initial discharge capacity of 1254 mAh g−1 at a current density of 0.1 A g−1, and an outstanding rate performance (532 mAh g−1 at current densities of 5 A g−1), as well as excellent cycling stability with a capacity fade rate of ∼0.02% per cycle over 500 cycles at the current density of 2 A g−1. |
| first_indexed | 2024-10-01T06:17:56Z |
| format | Journal Article |
| id | ntu-10356/138972 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:17:56Z |
| publishDate | 2020 |
| record_format | dspace |
| spelling | ntu-10356/1389722020-06-01T10:21:23Z Rational design of intertwined carbon nanotubes threaded porous CoP@carbon nanocubes as anode with superior lithium storage Zhu, Peipei Zhang, Ze Zhao, Pengfei Zhang, Bowei Cao, Xun Yu, Ji Cai, Jianxin Huang, Yizhong Yang, Zhenyu School of Materials Science & Engineering Engineering::Materials Lithium Ion Batteries Anode A novel 3D porous CoP@C-CNTs composite with CNTs threaded CoP@C nanocubes is rationally designed and demonstrated as a promising anode for lithium-ion battery. The CoP@C-CNTs composite displays high surface area and abundant pores resulted from the pyrolysis of metal-organic frameworks (MOFs). CoP nanoparticles are well encapsulated in MOFs-derived carbon nanocubes, which can effectively accommodate the volume change of active CoP during charge/discharge processes. Besides, the N/P co-doped feature induced in-situ in the synthesis process helps to improve the electrical conductivity. Moreover, the presence of intertwined CNTs network threaded CoP@C nanocubes is the vital part for rapid electron transportation within the whole electrode. As a result, the CoP@C-CNTs electrode exhibits a high initial discharge capacity of 1254 mAh g−1 at a current density of 0.1 A g−1, and an outstanding rate performance (532 mAh g−1 at current densities of 5 A g−1), as well as excellent cycling stability with a capacity fade rate of ∼0.02% per cycle over 500 cycles at the current density of 2 A g−1. MOE (Min. of Education, S’pore) 2020-05-14T07:19:44Z 2020-05-14T07:19:44Z 2018 Journal Article Zhu, P., Zhang, Z., Zhao, P., Zhang, B., Cao, X., Yu, J., . . . Yang, Z. (2019). Rational design of intertwined carbon nanotubes threaded porous CoP@ carbon nanocubes as anode with superior lithium storage. Carbon, 142, 269-277. doi:10.1016/j.carbon.2018.10.066 0008-6223 https://hdl.handle.net/10356/138972 10.1016/j.carbon.2018.10.066 2-s2.0-85055976538 142 269 277 en Carbon © 2018 Elsevier Ltd. All rights reserved. |
| spellingShingle | Engineering::Materials Lithium Ion Batteries Anode Zhu, Peipei Zhang, Ze Zhao, Pengfei Zhang, Bowei Cao, Xun Yu, Ji Cai, Jianxin Huang, Yizhong Yang, Zhenyu Rational design of intertwined carbon nanotubes threaded porous CoP@carbon nanocubes as anode with superior lithium storage |
| title | Rational design of intertwined carbon nanotubes threaded porous CoP@carbon nanocubes as anode with superior lithium storage |
| title_full | Rational design of intertwined carbon nanotubes threaded porous CoP@carbon nanocubes as anode with superior lithium storage |
| title_fullStr | Rational design of intertwined carbon nanotubes threaded porous CoP@carbon nanocubes as anode with superior lithium storage |
| title_full_unstemmed | Rational design of intertwined carbon nanotubes threaded porous CoP@carbon nanocubes as anode with superior lithium storage |
| title_short | Rational design of intertwined carbon nanotubes threaded porous CoP@carbon nanocubes as anode with superior lithium storage |
| title_sort | rational design of intertwined carbon nanotubes threaded porous cop carbon nanocubes as anode with superior lithium storage |
| topic | Engineering::Materials Lithium Ion Batteries Anode |
| url | https://hdl.handle.net/10356/138972 |
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