The design and synthesis of hollow micro-/nanostructures : present and future trends

Hollow micro-/nanostructures have attracted tremendous interest owing to their intriguing structure-induced physicochemical properties and great potential for widespread applications. With the development of modern synthetic methodology and analytical instruments, a rapid structural/compositional ev...

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Main Authors: Yu, Le, Yu, Xin Yao, Lou, David Xiong Wen
Other Authors: School of Chemical and Biomedical Engineering
Format: Journal Article
Language:English
Published: 2020
Subjects:
Online Access:https://hdl.handle.net/10356/138974
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author Yu, Le
Yu, Xin Yao
Lou, David Xiong Wen
author2 School of Chemical and Biomedical Engineering
author_facet School of Chemical and Biomedical Engineering
Yu, Le
Yu, Xin Yao
Lou, David Xiong Wen
author_sort Yu, Le
collection NTU
description Hollow micro-/nanostructures have attracted tremendous interest owing to their intriguing structure-induced physicochemical properties and great potential for widespread applications. With the development of modern synthetic methodology and analytical instruments, a rapid structural/compositional evolution of hollow structures from simple to complex has occurred in recent decades. Here, an updated overview of research progress made in the synthesis of hollow structures is provided. After an introduction of definition and classification, achievements in synthetic approaches for these delicate hollow architectures are presented in detail. According to formation mechanisms, these strategies can be categorized into four different types, including hard-templating, soft-templating, self-templated, and template-free methods. In particular, the rationales and emerging innovations in conventional templating syntheses are in focus. The development of burgeoning self-templating strategies based on controlled etching, outward diffusion, and heterogeneous contraction is also summarized. In addition, a brief overview of template-free methods and recent advances on combined mechanisms is provided. Notably, the strengths and weaknesses of each category are discussed in detail. In conclusion, a perspective on future trends in the research of hollow micro-/nanostructures is given.
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spelling ntu-10356/1389742020-05-14T07:32:31Z The design and synthesis of hollow micro-/nanostructures : present and future trends Yu, Le Yu, Xin Yao Lou, David Xiong Wen School of Chemical and Biomedical Engineering Engineering::Chemical engineering Hard-templating Hollow Hollow micro-/nanostructures have attracted tremendous interest owing to their intriguing structure-induced physicochemical properties and great potential for widespread applications. With the development of modern synthetic methodology and analytical instruments, a rapid structural/compositional evolution of hollow structures from simple to complex has occurred in recent decades. Here, an updated overview of research progress made in the synthesis of hollow structures is provided. After an introduction of definition and classification, achievements in synthetic approaches for these delicate hollow architectures are presented in detail. According to formation mechanisms, these strategies can be categorized into four different types, including hard-templating, soft-templating, self-templated, and template-free methods. In particular, the rationales and emerging innovations in conventional templating syntheses are in focus. The development of burgeoning self-templating strategies based on controlled etching, outward diffusion, and heterogeneous contraction is also summarized. In addition, a brief overview of template-free methods and recent advances on combined mechanisms is provided. Notably, the strengths and weaknesses of each category are discussed in detail. In conclusion, a perspective on future trends in the research of hollow micro-/nanostructures is given. 2020-05-14T07:32:31Z 2020-05-14T07:32:31Z 2018 Journal Article Yu, L., Yu, X. Y., & Lou, D. X. W. (2018). The design and synthesis of hollow micro-/nanostructures : present and future trends. Advanced Materials, 30(38), 1800939-. doi:10.1002/adma.201800939 0935-9648 https://hdl.handle.net/10356/138974 10.1002/adma.201800939 30009431 2-s2.0-85050828122 38 30 en Advanced Materials © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. This paper was published in Advanced Materials and is made available with permission of WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
spellingShingle Engineering::Chemical engineering
Hard-templating
Hollow
Yu, Le
Yu, Xin Yao
Lou, David Xiong Wen
The design and synthesis of hollow micro-/nanostructures : present and future trends
title The design and synthesis of hollow micro-/nanostructures : present and future trends
title_full The design and synthesis of hollow micro-/nanostructures : present and future trends
title_fullStr The design and synthesis of hollow micro-/nanostructures : present and future trends
title_full_unstemmed The design and synthesis of hollow micro-/nanostructures : present and future trends
title_short The design and synthesis of hollow micro-/nanostructures : present and future trends
title_sort design and synthesis of hollow micro nanostructures present and future trends
topic Engineering::Chemical engineering
Hard-templating
Hollow
url https://hdl.handle.net/10356/138974
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