Nanocarbon‐based electrocatalysts for rechargeable aqueous Li/Zn‐air batteries

Rechargeable aqueous Li/Zn‐air batteries have become the most attractive energy storage devices because of their extremely high theoretical energy density, which enables electric vehicles to drive long range. However, current achievements still suffer from poor cycle life, low practical energy densi...

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Main Authors: Wang, Ronghua, Chen, Zhen, Hu, Ning, Xu, Chaohe, Shen, Zexiang, Liu, Jilei
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2020
Subjects:
Online Access:https://hdl.handle.net/10356/139620
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author Wang, Ronghua
Chen, Zhen
Hu, Ning
Xu, Chaohe
Shen, Zexiang
Liu, Jilei
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Wang, Ronghua
Chen, Zhen
Hu, Ning
Xu, Chaohe
Shen, Zexiang
Liu, Jilei
author_sort Wang, Ronghua
collection NTU
description Rechargeable aqueous Li/Zn‐air batteries have become the most attractive energy storage devices because of their extremely high theoretical energy density, which enables electric vehicles to drive long range. However, current achievements still suffer from poor cycle life, low practical energy density, low round‐trip efficiency, and high manufacturing costs. One of the key challenges is the sluggish kinetics of oxygen electrochemistry during discharge and charge cycles. Thus, significant breakthroughs in design and synthesis of efficient electrocatalysts for the oxygen redox reaction are highly demanded. Nanocarbons, especially heteroatoms doped nanocarbons, are potential oxygen reduction reaction (ORR) catalysts due to the reasonable balance between catalytic activity, durability, and cost. Importantly, by introduction of transition metal nanoparticles, spinel oxides, layered‐double hydroxides, perovskite oxides, and other metal oxides, the constructed nanocarbon‐based materials could deliver promising bifunctional ORR and oxygen evolution reaction (OER) catalytic properties, which could be employed as air‐cathode materials to improve energy storage performances, even to get commercialized. Here, an overview of the recent progress of nanocarbon‐based electrocatalysts as air‐cathode materials for rechargeable aqueous Li/Zn‐air batteries is provided, aiming to highlight the benefits and issues of nanocarbon‐based electrocatalysts as well as to outline the most promising results and applications so far.
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spelling ntu-10356/1396202020-05-20T08:27:50Z Nanocarbon‐based electrocatalysts for rechargeable aqueous Li/Zn‐air batteries Wang, Ronghua Chen, Zhen Hu, Ning Xu, Chaohe Shen, Zexiang Liu, Jilei School of Physical and Mathematical Sciences Science::Physics Lithium-air Batteries Zinc-air Batteries Rechargeable aqueous Li/Zn‐air batteries have become the most attractive energy storage devices because of their extremely high theoretical energy density, which enables electric vehicles to drive long range. However, current achievements still suffer from poor cycle life, low practical energy density, low round‐trip efficiency, and high manufacturing costs. One of the key challenges is the sluggish kinetics of oxygen electrochemistry during discharge and charge cycles. Thus, significant breakthroughs in design and synthesis of efficient electrocatalysts for the oxygen redox reaction are highly demanded. Nanocarbons, especially heteroatoms doped nanocarbons, are potential oxygen reduction reaction (ORR) catalysts due to the reasonable balance between catalytic activity, durability, and cost. Importantly, by introduction of transition metal nanoparticles, spinel oxides, layered‐double hydroxides, perovskite oxides, and other metal oxides, the constructed nanocarbon‐based materials could deliver promising bifunctional ORR and oxygen evolution reaction (OER) catalytic properties, which could be employed as air‐cathode materials to improve energy storage performances, even to get commercialized. Here, an overview of the recent progress of nanocarbon‐based electrocatalysts as air‐cathode materials for rechargeable aqueous Li/Zn‐air batteries is provided, aiming to highlight the benefits and issues of nanocarbon‐based electrocatalysts as well as to outline the most promising results and applications so far. MOE (Min. of Education, S’pore) 2020-05-20T08:27:50Z 2020-05-20T08:27:50Z 2018 Journal Article Wang, R., Chen, Z., Hu, N., Xu, C., Shen, Z., & Liu, J. (2018). Nanocarbon‐based electrocatalysts for rechargeable aqueous Li/Zn‐air batteries. ChemElectroChem, 5(14), 1745-1763. doi:10.1002/celc.201800141 2196-0216 https://hdl.handle.net/10356/139620 10.1002/celc.201800141 2-s2.0-85044435604 14 5 1745 1763 en ChemElectroChem © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved.
spellingShingle Science::Physics
Lithium-air Batteries
Zinc-air Batteries
Wang, Ronghua
Chen, Zhen
Hu, Ning
Xu, Chaohe
Shen, Zexiang
Liu, Jilei
Nanocarbon‐based electrocatalysts for rechargeable aqueous Li/Zn‐air batteries
title Nanocarbon‐based electrocatalysts for rechargeable aqueous Li/Zn‐air batteries
title_full Nanocarbon‐based electrocatalysts for rechargeable aqueous Li/Zn‐air batteries
title_fullStr Nanocarbon‐based electrocatalysts for rechargeable aqueous Li/Zn‐air batteries
title_full_unstemmed Nanocarbon‐based electrocatalysts for rechargeable aqueous Li/Zn‐air batteries
title_short Nanocarbon‐based electrocatalysts for rechargeable aqueous Li/Zn‐air batteries
title_sort nanocarbon based electrocatalysts for rechargeable aqueous li zn air batteries
topic Science::Physics
Lithium-air Batteries
Zinc-air Batteries
url https://hdl.handle.net/10356/139620
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AT huning nanocarbonbasedelectrocatalystsforrechargeableaqueousliznairbatteries
AT xuchaohe nanocarbonbasedelectrocatalystsforrechargeableaqueousliznairbatteries
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