Aqueous zinc removal by calcium fluoride sludge

Zinc (Zn) contamination is of environmental concern due to its effect on human health. The purpose of this study was to investigate the use of Calcium Fluoride (CaF2) sludge has been used to investigate its feasibility of using to remove Zn from aqueous solution. The CaF2 sludge produced by AFPD Pte...

Full description

Bibliographic Details
Main Author: Chua, Viny Xiao Wei.
Other Authors: Chui, Peng Cheong
Format: Final Year Project (FYP)
Language:English
Published: 2008
Subjects:
Online Access:http://hdl.handle.net/10356/14140
_version_ 1811682681265586176
author Chua, Viny Xiao Wei.
author2 Chui, Peng Cheong
author_facet Chui, Peng Cheong
Chua, Viny Xiao Wei.
author_sort Chua, Viny Xiao Wei.
collection NTU
description Zinc (Zn) contamination is of environmental concern due to its effect on human health. The purpose of this study was to investigate the use of Calcium Fluoride (CaF2) sludge has been used to investigate its feasibility of using to remove Zn from aqueous solution. The CaF2 sludge produced by AFPD Pte Ltd, one of the world’s largest TFT LCD manufacturing plants (based in Singapore), contains apatite, which have high selectivity for certain toxic metals. The major parameters controlling aqueous Zn removal, viz. initial metal ion concentration, solution pH, ionic strength and metal kinetics were evaluated using batch experiments. Result demonstrated that the capacity of aqueous Zn immobilization by CaF2 was high at low initial Zn aqueous solution. Zn removal efficiency by CaF2 generally increased with decreasing ionic strength. In the pH-controlled study, it was found that removal of Zn is dependent on the cation exchange capacity (CEC) of CaF2. It was also found that the desorption level of Zn from CaF2 sludge is high especially in the acidic condition (pH < 2.88). This implies that Zn laden will have to be stabilized before being disposed into landfill since the maximum allowable limit for zinc in discharged water is 5 mg/L.
first_indexed 2024-10-01T04:00:42Z
format Final Year Project (FYP)
id ntu-10356/14140
institution Nanyang Technological University
language English
last_indexed 2024-10-01T04:00:42Z
publishDate 2008
record_format dspace
spelling ntu-10356/141402023-03-03T17:03:27Z Aqueous zinc removal by calcium fluoride sludge Chua, Viny Xiao Wei. Chui, Peng Cheong School of Civil and Environmental Engineering DRNTU::Engineering::Environmental engineering::Waste management Zinc (Zn) contamination is of environmental concern due to its effect on human health. The purpose of this study was to investigate the use of Calcium Fluoride (CaF2) sludge has been used to investigate its feasibility of using to remove Zn from aqueous solution. The CaF2 sludge produced by AFPD Pte Ltd, one of the world’s largest TFT LCD manufacturing plants (based in Singapore), contains apatite, which have high selectivity for certain toxic metals. The major parameters controlling aqueous Zn removal, viz. initial metal ion concentration, solution pH, ionic strength and metal kinetics were evaluated using batch experiments. Result demonstrated that the capacity of aqueous Zn immobilization by CaF2 was high at low initial Zn aqueous solution. Zn removal efficiency by CaF2 generally increased with decreasing ionic strength. In the pH-controlled study, it was found that removal of Zn is dependent on the cation exchange capacity (CEC) of CaF2. It was also found that the desorption level of Zn from CaF2 sludge is high especially in the acidic condition (pH < 2.88). This implies that Zn laden will have to be stabilized before being disposed into landfill since the maximum allowable limit for zinc in discharged water is 5 mg/L. Bachelor of Engineering 2008-10-29T08:18:06Z 2008-10-29T08:18:06Z 2007 2007 Final Year Project (FYP) http://hdl.handle.net/10356/14140 en 57 p. application/pdf
spellingShingle DRNTU::Engineering::Environmental engineering::Waste management
Chua, Viny Xiao Wei.
Aqueous zinc removal by calcium fluoride sludge
title Aqueous zinc removal by calcium fluoride sludge
title_full Aqueous zinc removal by calcium fluoride sludge
title_fullStr Aqueous zinc removal by calcium fluoride sludge
title_full_unstemmed Aqueous zinc removal by calcium fluoride sludge
title_short Aqueous zinc removal by calcium fluoride sludge
title_sort aqueous zinc removal by calcium fluoride sludge
topic DRNTU::Engineering::Environmental engineering::Waste management
url http://hdl.handle.net/10356/14140
work_keys_str_mv AT chuavinyxiaowei aqueouszincremovalbycalciumfluoridesludge