Photooxidation of a twisted isoquinolinone
Understanding the oxidation mechanism and positions of twistacenes and twistheteroacenes under ambient conditions is very important because such knowledge can guide us to design and synthesize novel, larger stable analogues. Herein, we demonstrated for the first time that a twisted isoquinolinone ca...
| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2020
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/141815 |
| _version_ | 1826116713834348544 |
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| author | Li, Gang Zhao, Jianfeng Yang, Shufan Li, Yongxin Rakesh, Ganguly Zhang, Qichun |
| author2 | School of Materials Science and Engineering |
| author_facet | School of Materials Science and Engineering Li, Gang Zhao, Jianfeng Yang, Shufan Li, Yongxin Rakesh, Ganguly Zhang, Qichun |
| author_sort | Li, Gang |
| collection | NTU |
| description | Understanding the oxidation mechanism and positions of twistacenes and twistheteroacenes under ambient conditions is very important because such knowledge can guide us to design and synthesize novel, larger stable analogues. Herein, we demonstrated for the first time that a twisted isoquinolinone can decompose under oxygen and light at room temperature. The as‐decomposed product 1 was fully characterized through conventional methods as well as single‐crystal structure analysis. Moreover, the physical properties of the as‐obtained product were carefully investigated and the possible formation mechanism was proposed. |
| first_indexed | 2024-10-01T04:15:54Z |
| format | Journal Article |
| id | ntu-10356/141815 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T04:15:54Z |
| publishDate | 2020 |
| record_format | dspace |
| spelling | ntu-10356/1418152020-06-11T01:49:04Z Photooxidation of a twisted isoquinolinone Li, Gang Zhao, Jianfeng Yang, Shufan Li, Yongxin Rakesh, Ganguly Zhang, Qichun School of Materials Science and Engineering School of Physical and Mathematical Sciences Engineering::Materials Acenes Characterization Understanding the oxidation mechanism and positions of twistacenes and twistheteroacenes under ambient conditions is very important because such knowledge can guide us to design and synthesize novel, larger stable analogues. Herein, we demonstrated for the first time that a twisted isoquinolinone can decompose under oxygen and light at room temperature. The as‐decomposed product 1 was fully characterized through conventional methods as well as single‐crystal structure analysis. Moreover, the physical properties of the as‐obtained product were carefully investigated and the possible formation mechanism was proposed. MOE (Min. of Education, S’pore) 2020-06-11T01:49:04Z 2020-06-11T01:49:04Z 2017 Journal Article Li, G., Zhao, J., Yang, S., Li, Y., Rakesh, G., & Zhang, Q. (2018). Photooxidation of a twisted isoquinolinone. Chemistry - An Asian Journal, 13(3), 250-254. doi:10.1002/asia.201701674 1861-4728 https://hdl.handle.net/10356/141815 10.1002/asia.201701674 29276814 2-s2.0-85040567818 3 13 250 254 en Chemistry - An Asian journal © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. |
| spellingShingle | Engineering::Materials Acenes Characterization Li, Gang Zhao, Jianfeng Yang, Shufan Li, Yongxin Rakesh, Ganguly Zhang, Qichun Photooxidation of a twisted isoquinolinone |
| title | Photooxidation of a twisted isoquinolinone |
| title_full | Photooxidation of a twisted isoquinolinone |
| title_fullStr | Photooxidation of a twisted isoquinolinone |
| title_full_unstemmed | Photooxidation of a twisted isoquinolinone |
| title_short | Photooxidation of a twisted isoquinolinone |
| title_sort | photooxidation of a twisted isoquinolinone |
| topic | Engineering::Materials Acenes Characterization |
| url | https://hdl.handle.net/10356/141815 |
| work_keys_str_mv | AT ligang photooxidationofatwistedisoquinolinone AT zhaojianfeng photooxidationofatwistedisoquinolinone AT yangshufan photooxidationofatwistedisoquinolinone AT liyongxin photooxidationofatwistedisoquinolinone AT rakeshganguly photooxidationofatwistedisoquinolinone AT zhangqichun photooxidationofatwistedisoquinolinone |