Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications
Microporous materials with higher uptake – offtake difference per adsorption – desorption cycle have great potential to design adsorption assisted chillers, heat pumps and thermal batteries. In this context, we report a green reaction method for synthesizing aluminium fumarate (AlFum) metal-organic...
Main Authors: | , , |
---|---|
Other Authors: | |
Format: | Journal Article |
Language: | English |
Published: |
2020
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/142749 |
_version_ | 1826112410295992320 |
---|---|
author | Kayal, Sibnath Chakraborty, Anutosh Teo, Benjamin How Wei |
author2 | School of Mechanical and Aerospace Engineering |
author_facet | School of Mechanical and Aerospace Engineering Kayal, Sibnath Chakraborty, Anutosh Teo, Benjamin How Wei |
author_sort | Kayal, Sibnath |
collection | NTU |
description | Microporous materials with higher uptake – offtake difference per adsorption – desorption cycle have great potential to design adsorption assisted chillers, heat pumps and thermal batteries. In this context, we report a green reaction method for synthesizing aluminium fumarate (AlFum) metal-organic framework (MOF). The water uptake on AlFum shows S-shape isotherm curve with sharp increase in uptake – offtake difference in a narrow pressure range. The proposed green synthesized AlFum exhibits higher deliverable energy capacity as compared to that of conventional (dimethylformamide based synthesis) AlFum for adsorptive cooling applications. |
first_indexed | 2024-10-01T03:06:33Z |
format | Journal Article |
id | ntu-10356/142749 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T03:06:33Z |
publishDate | 2020 |
record_format | dspace |
spelling | ntu-10356/1427492020-06-30T00:41:55Z Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications Kayal, Sibnath Chakraborty, Anutosh Teo, Benjamin How Wei School of Mechanical and Aerospace Engineering Singapore Institute of Manufacturing Technology Engineering::Mechanical engineering Aluminium Fumarate MOF Green Synthesis Microporous materials with higher uptake – offtake difference per adsorption – desorption cycle have great potential to design adsorption assisted chillers, heat pumps and thermal batteries. In this context, we report a green reaction method for synthesizing aluminium fumarate (AlFum) metal-organic framework (MOF). The water uptake on AlFum shows S-shape isotherm curve with sharp increase in uptake – offtake difference in a narrow pressure range. The proposed green synthesized AlFum exhibits higher deliverable energy capacity as compared to that of conventional (dimethylformamide based synthesis) AlFum for adsorptive cooling applications. 2020-06-30T00:41:54Z 2020-06-30T00:41:54Z 2018 Journal Article Kayal, S., Chakraborty, A., & Teo, B. H. W. (2018). Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications. Materials Letters, 221, 165-167. doi:10.1016/j.matlet.2018.03.099 0167-577X https://hdl.handle.net/10356/142749 10.1016/j.matlet.2018.03.099 2-s2.0-85044120259 221 165 167 en Materials Letters © 2018 Elsevier B.V. All rights reserved. |
spellingShingle | Engineering::Mechanical engineering Aluminium Fumarate MOF Green Synthesis Kayal, Sibnath Chakraborty, Anutosh Teo, Benjamin How Wei Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications |
title | Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications |
title_full | Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications |
title_fullStr | Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications |
title_full_unstemmed | Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications |
title_short | Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications |
title_sort | green synthesis and characterization of aluminium fumarate metal organic framework for heat transformation applications |
topic | Engineering::Mechanical engineering Aluminium Fumarate MOF Green Synthesis |
url | https://hdl.handle.net/10356/142749 |
work_keys_str_mv | AT kayalsibnath greensynthesisandcharacterizationofaluminiumfumaratemetalorganicframeworkforheattransformationapplications AT chakrabortyanutosh greensynthesisandcharacterizationofaluminiumfumaratemetalorganicframeworkforheattransformationapplications AT teobenjaminhowwei greensynthesisandcharacterizationofaluminiumfumaratemetalorganicframeworkforheattransformationapplications |