Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications

Microporous materials with higher uptake – offtake difference per adsorption – desorption cycle have great potential to design adsorption assisted chillers, heat pumps and thermal batteries. In this context, we report a green reaction method for synthesizing aluminium fumarate (AlFum) metal-organic...

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Main Authors: Kayal, Sibnath, Chakraborty, Anutosh, Teo, Benjamin How Wei
Other Authors: School of Mechanical and Aerospace Engineering
Format: Journal Article
Language:English
Published: 2020
Subjects:
Online Access:https://hdl.handle.net/10356/142749
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author Kayal, Sibnath
Chakraborty, Anutosh
Teo, Benjamin How Wei
author2 School of Mechanical and Aerospace Engineering
author_facet School of Mechanical and Aerospace Engineering
Kayal, Sibnath
Chakraborty, Anutosh
Teo, Benjamin How Wei
author_sort Kayal, Sibnath
collection NTU
description Microporous materials with higher uptake – offtake difference per adsorption – desorption cycle have great potential to design adsorption assisted chillers, heat pumps and thermal batteries. In this context, we report a green reaction method for synthesizing aluminium fumarate (AlFum) metal-organic framework (MOF). The water uptake on AlFum shows S-shape isotherm curve with sharp increase in uptake – offtake difference in a narrow pressure range. The proposed green synthesized AlFum exhibits higher deliverable energy capacity as compared to that of conventional (dimethylformamide based synthesis) AlFum for adsorptive cooling applications.
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spelling ntu-10356/1427492020-06-30T00:41:55Z Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications Kayal, Sibnath Chakraborty, Anutosh Teo, Benjamin How Wei School of Mechanical and Aerospace Engineering Singapore Institute of Manufacturing Technology Engineering::Mechanical engineering Aluminium Fumarate MOF Green Synthesis Microporous materials with higher uptake – offtake difference per adsorption – desorption cycle have great potential to design adsorption assisted chillers, heat pumps and thermal batteries. In this context, we report a green reaction method for synthesizing aluminium fumarate (AlFum) metal-organic framework (MOF). The water uptake on AlFum shows S-shape isotherm curve with sharp increase in uptake – offtake difference in a narrow pressure range. The proposed green synthesized AlFum exhibits higher deliverable energy capacity as compared to that of conventional (dimethylformamide based synthesis) AlFum for adsorptive cooling applications. 2020-06-30T00:41:54Z 2020-06-30T00:41:54Z 2018 Journal Article Kayal, S., Chakraborty, A., & Teo, B. H. W. (2018). Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications. Materials Letters, 221, 165-167. doi:10.1016/j.matlet.2018.03.099 0167-577X https://hdl.handle.net/10356/142749 10.1016/j.matlet.2018.03.099 2-s2.0-85044120259 221 165 167 en Materials Letters © 2018 Elsevier B.V. All rights reserved.
spellingShingle Engineering::Mechanical engineering
Aluminium Fumarate MOF
Green Synthesis
Kayal, Sibnath
Chakraborty, Anutosh
Teo, Benjamin How Wei
Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications
title Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications
title_full Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications
title_fullStr Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications
title_full_unstemmed Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications
title_short Green synthesis and characterization of aluminium fumarate metal-organic framework for heat transformation applications
title_sort green synthesis and characterization of aluminium fumarate metal organic framework for heat transformation applications
topic Engineering::Mechanical engineering
Aluminium Fumarate MOF
Green Synthesis
url https://hdl.handle.net/10356/142749
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AT teobenjaminhowwei greensynthesisandcharacterizationofaluminiumfumaratemetalorganicframeworkforheattransformationapplications