Responsive amorphous photonic structures of spherical/polyhedral colloidal metal-organic frameworks
Amorphous photonic structures (APSs) with isotropic structural colors are of great promise for creating reflective full-color displays or responsive colorimetric devices. However, there is a lack of guiding principles in developing stimuli-responsive functional APSs, and the building blocks of APSs...
| Main Authors: | , , , , , , , , , |
|---|---|
| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2020
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/142904 |
| _version_ | 1826110733672251392 |
|---|---|
| author | Bai, Ling He, Yuheng Zhou, Jiajing Lim, Yun Mai, Van Cuong Chen, Yonghao Hou, Shuai Zhao, Yue Zhang, Jun Duan, Hongwei |
| author2 | School of Chemical and Biomedical Engineering |
| author_facet | School of Chemical and Biomedical Engineering Bai, Ling He, Yuheng Zhou, Jiajing Lim, Yun Mai, Van Cuong Chen, Yonghao Hou, Shuai Zhao, Yue Zhang, Jun Duan, Hongwei |
| author_sort | Bai, Ling |
| collection | NTU |
| description | Amorphous photonic structures (APSs) with isotropic structural colors are of great promise for creating reflective full-color displays or responsive colorimetric devices. However, there is a lack of guiding principles in developing stimuli-responsive functional APSs, and the building blocks of APSs are still limited to spherical particles despite the increasing emergence of anisotropic functional particles. Moreover, current production of APSs, in particular high-resolution APS patterns, is not fundamentally compatible with industrial manufacturing technologies, forming a major barrier toward their applications. Presented here is a proof-of-concept study on scalable fabrication of responsive APSs by colloidal assembly of spherical/polyhedral metal-organic framework (MOF) particles on liquid-permeable substrates. It is shown that infiltration assisted Mayer rod coating allows for rapid production of customized multicolored structural color patterns of MOF APSs by controlling liquid wetting/infiltration on the substrate with printed wax coatings. Small-angle X-ray scattering and optical measurements reveal the structural parameters of MOF APSs such as average nearest interscattering spacing and particle packing density, theoretically relating the optical properties and responsive color shifts of MOF APSs to factors affecting their scattering profile, which provides the guideline for the development of smart APS photonic devices via a wide spectrum of colloidal particles for diverse applications. |
| first_indexed | 2024-10-01T02:39:21Z |
| format | Journal Article |
| id | ntu-10356/142904 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T02:39:21Z |
| publishDate | 2020 |
| record_format | dspace |
| spelling | ntu-10356/1429042023-12-29T06:45:32Z Responsive amorphous photonic structures of spherical/polyhedral colloidal metal-organic frameworks Bai, Ling He, Yuheng Zhou, Jiajing Lim, Yun Mai, Van Cuong Chen, Yonghao Hou, Shuai Zhao, Yue Zhang, Jun Duan, Hongwei School of Chemical and Biomedical Engineering Engineering::Materials Amorphous Photonic Structures Anisotropic Particles Amorphous photonic structures (APSs) with isotropic structural colors are of great promise for creating reflective full-color displays or responsive colorimetric devices. However, there is a lack of guiding principles in developing stimuli-responsive functional APSs, and the building blocks of APSs are still limited to spherical particles despite the increasing emergence of anisotropic functional particles. Moreover, current production of APSs, in particular high-resolution APS patterns, is not fundamentally compatible with industrial manufacturing technologies, forming a major barrier toward their applications. Presented here is a proof-of-concept study on scalable fabrication of responsive APSs by colloidal assembly of spherical/polyhedral metal-organic framework (MOF) particles on liquid-permeable substrates. It is shown that infiltration assisted Mayer rod coating allows for rapid production of customized multicolored structural color patterns of MOF APSs by controlling liquid wetting/infiltration on the substrate with printed wax coatings. Small-angle X-ray scattering and optical measurements reveal the structural parameters of MOF APSs such as average nearest interscattering spacing and particle packing density, theoretically relating the optical properties and responsive color shifts of MOF APSs to factors affecting their scattering profile, which provides the guideline for the development of smart APS photonic devices via a wide spectrum of colloidal particles for diverse applications. MOE (Min. of Education, S’pore) Accepted version 2020-07-08T02:16:54Z 2020-07-08T02:16:54Z 2019 Journal Article Bai, L., He, Y., Zhou, J., Lim, Y., Mai, V. C., Chen, Y., . . . Duan, H. (2019). Responsive amorphous photonic structures of spherical/polyhedral colloidal metal-organic frameworks. Advanced Optical Materials, 7(13), 1900522-. doi:10.1002/adom.201900522 2195-1071 https://hdl.handle.net/10356/142904 10.1002/adom.201900522 2-s2.0-85065204397 13 7 en Advanced Optical Materials This is the accepted version of the following article: Bai, L., He, Y., Zhou, J., Lim, Y., Mai, V. C., Chen, Y., . . . Duan, H. (2019). Responsive amorphous photonic structures of spherical/polyhedral colloidal metal-organic frameworks. Advanced Optical Materials, 7(13), 1900522-, which has been published in final form at http://dx.doi.org/10.1002/adom.201900522. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [https://authorservices.wiley.com/authorresources/Journal-Authors/licensing/self-archiving.html]. application/pdf |
| spellingShingle | Engineering::Materials Amorphous Photonic Structures Anisotropic Particles Bai, Ling He, Yuheng Zhou, Jiajing Lim, Yun Mai, Van Cuong Chen, Yonghao Hou, Shuai Zhao, Yue Zhang, Jun Duan, Hongwei Responsive amorphous photonic structures of spherical/polyhedral colloidal metal-organic frameworks |
| title | Responsive amorphous photonic structures of spherical/polyhedral colloidal metal-organic frameworks |
| title_full | Responsive amorphous photonic structures of spherical/polyhedral colloidal metal-organic frameworks |
| title_fullStr | Responsive amorphous photonic structures of spherical/polyhedral colloidal metal-organic frameworks |
| title_full_unstemmed | Responsive amorphous photonic structures of spherical/polyhedral colloidal metal-organic frameworks |
| title_short | Responsive amorphous photonic structures of spherical/polyhedral colloidal metal-organic frameworks |
| title_sort | responsive amorphous photonic structures of spherical polyhedral colloidal metal organic frameworks |
| topic | Engineering::Materials Amorphous Photonic Structures Anisotropic Particles |
| url | https://hdl.handle.net/10356/142904 |
| work_keys_str_mv | AT bailing responsiveamorphousphotonicstructuresofsphericalpolyhedralcolloidalmetalorganicframeworks AT heyuheng responsiveamorphousphotonicstructuresofsphericalpolyhedralcolloidalmetalorganicframeworks AT zhoujiajing responsiveamorphousphotonicstructuresofsphericalpolyhedralcolloidalmetalorganicframeworks AT limyun responsiveamorphousphotonicstructuresofsphericalpolyhedralcolloidalmetalorganicframeworks AT maivancuong responsiveamorphousphotonicstructuresofsphericalpolyhedralcolloidalmetalorganicframeworks AT chenyonghao responsiveamorphousphotonicstructuresofsphericalpolyhedralcolloidalmetalorganicframeworks AT houshuai responsiveamorphousphotonicstructuresofsphericalpolyhedralcolloidalmetalorganicframeworks AT zhaoyue responsiveamorphousphotonicstructuresofsphericalpolyhedralcolloidalmetalorganicframeworks AT zhangjun responsiveamorphousphotonicstructuresofsphericalpolyhedralcolloidalmetalorganicframeworks AT duanhongwei responsiveamorphousphotonicstructuresofsphericalpolyhedralcolloidalmetalorganicframeworks |