Platinum-osmium heterometallic clusters containing N-heterocyclic carbene ligands and an electron-deficient tetraosmium by-product
The room temperature reaction of [Os 3 (CO) 12 ] (1) with three molar equivalents of [PtCl(allyl)(NHC)] (2) in the presence of KOtBu afforded the heterometallic clusters [PtOs 3 (CO) 12 (NHC)] (3), [Pt 2 Os 3 (CO) 12 (NHC) 2 ] (4), and [Pt 3 Os 3 (CO) 12 (NHC) 3 ] (5), together with a trace amount o...
| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2020
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/142976 |