Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries

Metal organic polymers (MOPs), including metal coordination polymers (CPs, one-dimensional), metal–organic frameworks (MOFs, two-/three-dimensional), Prussian blue (PB) and Prussian blue analogues (PBAs), have recently emerged as promising electrochemically active materials for energy storage and co...

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Main Authors: Wu, Zhenzhen, Xie, Jian, Xu, Zhichuan Jason, Zhang, Shanqing, Zhang, Qichun
Other Authors: School of Materials Science and Engineering
Format: Journal Article
Language:English
Published: 2020
Subjects:
Online Access:https://hdl.handle.net/10356/144104
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author Wu, Zhenzhen
Xie, Jian
Xu, Zhichuan Jason
Zhang, Shanqing
Zhang, Qichun
author2 School of Materials Science and Engineering
author_facet School of Materials Science and Engineering
Wu, Zhenzhen
Xie, Jian
Xu, Zhichuan Jason
Zhang, Shanqing
Zhang, Qichun
author_sort Wu, Zhenzhen
collection NTU
description Metal organic polymers (MOPs), including metal coordination polymers (CPs, one-dimensional), metal–organic frameworks (MOFs, two-/three-dimensional), Prussian blue (PB) and Prussian blue analogues (PBAs), have recently emerged as promising electrochemically active materials for energy storage and conversion systems. Due to the tunability of their composition and the structural versatility, diverse electrochemical behaviors for multi-electron reactions, fast-ion diffusion, and small volume change of electrodes could be achieved upon charging and discharging. Because of these superiorities, MOPs are considered as effective substitutes for future advanced energy storage systems. Here, we summarize the recent progress in pristine MOPs as electrode candidates for rechargeable lithium and sodium ion batteries. The working mechanisms and strategies for enhancing the electrochemical performance in related advanced electrochemical energy storage (EES) applications are also highlighted in this review.
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spelling ntu-10356/1441042023-07-14T15:53:22Z Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries Wu, Zhenzhen Xie, Jian Xu, Zhichuan Jason Zhang, Shanqing Zhang, Qichun School of Materials Science and Engineering Centre for Clean Environment and Energy, School of Environment and Science, Gold Coast Campus, Griffith University Engineering::Materials Metal–organic Polymers Electrodes Metal organic polymers (MOPs), including metal coordination polymers (CPs, one-dimensional), metal–organic frameworks (MOFs, two-/three-dimensional), Prussian blue (PB) and Prussian blue analogues (PBAs), have recently emerged as promising electrochemically active materials for energy storage and conversion systems. Due to the tunability of their composition and the structural versatility, diverse electrochemical behaviors for multi-electron reactions, fast-ion diffusion, and small volume change of electrodes could be achieved upon charging and discharging. Because of these superiorities, MOPs are considered as effective substitutes for future advanced energy storage systems. Here, we summarize the recent progress in pristine MOPs as electrode candidates for rechargeable lithium and sodium ion batteries. The working mechanisms and strategies for enhancing the electrochemical performance in related advanced electrochemical energy storage (EES) applications are also highlighted in this review. Ministry of Education (MOE) Accepted version Q.Z. acknowledges financial support from AcRF Tier 1 (RG 111/17, RG 2/17, RG 114/16, RG 8/16) and Tier 2 (MOE 2017- T2-1-021 and MOE 2018-T2-1-070), Singapore. S.Z. acknowledges financial support from Australia Research Council Discovery projects (DP170103721 and DP180102003). 2020-10-13T07:21:23Z 2020-10-13T07:21:23Z 2019 Journal Article Wu, Z., Xie, J., Xu, Z. J., Zhang, S., & Zhang, Q. (2019). Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries. Journal of Materials Chemistry A, 7(9), 4259-4290. doi:10.1039/C8TA11994E 2050-7488 https://hdl.handle.net/10356/144104 10.1039/C8TA11994E 9 7 4259 4290 en AcRF Tier 1 RG 111/17 AcRF Tier 1 RG 2/17 AcRF Tier 1 RG 114/16 AcRF Tier 1 RG 8/16 MOE 2017-T2-1-021 MOE 2018-T2-1-070 Australia Research Council Discovery projects (DP170103721 and DP180102003) Journal of Materials Chemistry A © 2019 Royal Society of Chemistry. All rights reserved. This paper was published in Journal of Materials Chemistry A and is made available with permission of Royal Society of Chemistry. application/pdf
spellingShingle Engineering::Materials
Metal–organic Polymers
Electrodes
Wu, Zhenzhen
Xie, Jian
Xu, Zhichuan Jason
Zhang, Shanqing
Zhang, Qichun
Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries
title Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries
title_full Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries
title_fullStr Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries
title_full_unstemmed Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries
title_short Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries
title_sort recent progress in metal organic polymers as promising electrodes for lithium sodium rechargeable batteries
topic Engineering::Materials
Metal–organic Polymers
Electrodes
url https://hdl.handle.net/10356/144104
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