Structure–activity relationships of voltaglue organic blends
Voltage‐activated, one‐pot adhesives are an emerging platform with many potential advantages, but require multicomponent grafting of electrochemical donors and acceptors for operation in organic environments. This formulation strategy reduces throughput efficiency, organic solubility, and requires a...
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
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2020
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/144889 |
| _version_ | 1811687243287363584 |
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| author | Tan, Nigel Chew Shun Ghosh, Animesh Steele, Terry W. J. |
| author2 | School of Materials Science and Engineering |
| author_facet | School of Materials Science and Engineering Tan, Nigel Chew Shun Ghosh, Animesh Steele, Terry W. J. |
| author_sort | Tan, Nigel Chew Shun |
| collection | NTU |
| description | Voltage‐activated, one‐pot adhesives are an emerging platform with many potential advantages, but require multicomponent grafting of electrochemical donors and acceptors for operation in organic environments. This formulation strategy reduces throughput efficiency, organic solubility, and requires additional purification of the grafted dendrimers. A more advanced strategy is proposed for setting up the donor–acceptor conductive network by exploiting a flexible blending design, providing faster throughput of structure–activity analyses with less synthetic investment. The blend method investigates the ampere‐dependent storage modulus and gelation time as a function of both donor and acceptor concentration. This blend strategy allows a rapid evaluation of donor–acceptor parameters involved in voltage‐activated adhesive formulations. |
| first_indexed | 2024-10-01T05:13:13Z |
| format | Journal Article |
| id | ntu-10356/144889 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T05:13:13Z |
| publishDate | 2020 |
| record_format | dspace |
| spelling | ntu-10356/1448892023-07-14T15:55:49Z Structure–activity relationships of voltaglue organic blends Tan, Nigel Chew Shun Ghosh, Animesh Steele, Terry W. J. School of Materials Science and Engineering Engineering::Materials Adhesives Electrocuring Voltage‐activated, one‐pot adhesives are an emerging platform with many potential advantages, but require multicomponent grafting of electrochemical donors and acceptors for operation in organic environments. This formulation strategy reduces throughput efficiency, organic solubility, and requires additional purification of the grafted dendrimers. A more advanced strategy is proposed for setting up the donor–acceptor conductive network by exploiting a flexible blending design, providing faster throughput of structure–activity analyses with less synthetic investment. The blend method investigates the ampere‐dependent storage modulus and gelation time as a function of both donor and acceptor concentration. This blend strategy allows a rapid evaluation of donor–acceptor parameters involved in voltage‐activated adhesive formulations. Accepted version 2020-12-02T06:36:44Z 2020-12-02T06:36:44Z 2020 Journal Article Tan, N. C. S., Ghosh, A., & Steele, T. W. J. (2020). Structure–activity relationships of voltaglue organic blends. Macromolecular Rapid Communications, 41(21), 2000188-. doi:10.1002/marc.202000188 1022-1336 https://hdl.handle.net/10356/144889 10.1002/marc.202000188 21 41 2000188 en Macromolecular Rapid Communications This is the accepted version of the following article: Tan, N. C. S., Ghosh, A., & Steele, T. W. J. (2020). Structure–activity relationships of voltaglue organic blends. Macromolecular Rapid Communications, 41(21), 2000188-. doi:10.1002/marc.202000188, which has been published in final form at http://dx.doi.org/10.1002/marc.202000188. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [https://authorservices.wiley.com/authorresources/Journal-Authors/licensing/self-archiving.html]. application/pdf |
| spellingShingle | Engineering::Materials Adhesives Electrocuring Tan, Nigel Chew Shun Ghosh, Animesh Steele, Terry W. J. Structure–activity relationships of voltaglue organic blends |
| title | Structure–activity relationships of voltaglue organic blends |
| title_full | Structure–activity relationships of voltaglue organic blends |
| title_fullStr | Structure–activity relationships of voltaglue organic blends |
| title_full_unstemmed | Structure–activity relationships of voltaglue organic blends |
| title_short | Structure–activity relationships of voltaglue organic blends |
| title_sort | structure activity relationships of voltaglue organic blends |
| topic | Engineering::Materials Adhesives Electrocuring |
| url | https://hdl.handle.net/10356/144889 |
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