Cobalt-catalyzed hydroacylative dimerization of allenes leading to skipped dienes

A cobalt-diphosphine catalyst has been found to promote a selective 1:2 coupling reaction between aldehydes and allenes to form β,δ-dialkylidene ketones, featuring skipped diene moieties, with high regioselectivities and stereoselectivities. The reaction is distinct from previously reported, rhodium...

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Bibliographic Details
Main Authors: Ding, Wei, Ho, Terence Yan King, Okuda, Yasuhiro, Wijaya, Christopher Kevin, Tan, Zheng Hao, Yoshikai, Naohiko
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2020
Subjects:
Online Access:https://hdl.handle.net/10356/145049