Diastereoselective intramolecular hydride transfer
This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to undergo reduction of transient carbocation, which is generated upon electrophilic activation of alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via the 6-member...
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| Format: | Thesis-Doctor of Philosophy |
| Language: | English |
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Nanyang Technological University
2021
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| Online Access: | https://hdl.handle.net/10356/146238 |
| _version_ | 1811690392678039552 |
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| author | Gandamana, Dhika Aditya |
| author2 | Chiba Shunsuke |
| author_facet | Chiba Shunsuke Gandamana, Dhika Aditya |
| author_sort | Gandamana, Dhika Aditya |
| collection | NTU |
| description | This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to
undergo reduction of transient carbocation, which is generated upon electrophilic activation of
alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via
the 6-membered chair-like transition state. |
| first_indexed | 2024-10-01T06:03:16Z |
| format | Thesis-Doctor of Philosophy |
| id | ntu-10356/146238 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:03:16Z |
| publishDate | 2021 |
| publisher | Nanyang Technological University |
| record_format | dspace |
| spelling | ntu-10356/1462382023-02-28T23:48:06Z Diastereoselective intramolecular hydride transfer Gandamana, Dhika Aditya Chiba Shunsuke School of Physical and Mathematical Sciences Shunsuke@ntu.edu.sg Science::Chemistry::Organic chemistry::Organic synthesis This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to undergo reduction of transient carbocation, which is generated upon electrophilic activation of alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via the 6-membered chair-like transition state. Doctor of Philosophy 2021-02-03T05:49:25Z 2021-02-03T05:49:25Z 2020 Thesis-Doctor of Philosophy Gandamana, D. A. (2020). Diastereoselective intramolecular hydride transfer. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/146238 10.32657/10356/146238 en This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0). application/pdf Nanyang Technological University |
| spellingShingle | Science::Chemistry::Organic chemistry::Organic synthesis Gandamana, Dhika Aditya Diastereoselective intramolecular hydride transfer |
| title | Diastereoselective intramolecular hydride transfer |
| title_full | Diastereoselective intramolecular hydride transfer |
| title_fullStr | Diastereoselective intramolecular hydride transfer |
| title_full_unstemmed | Diastereoselective intramolecular hydride transfer |
| title_short | Diastereoselective intramolecular hydride transfer |
| title_sort | diastereoselective intramolecular hydride transfer |
| topic | Science::Chemistry::Organic chemistry::Organic synthesis |
| url | https://hdl.handle.net/10356/146238 |
| work_keys_str_mv | AT gandamanadhikaaditya diastereoselectiveintramolecularhydridetransfer |