The stoichiometry of TCNQ-based organic charge-transfer cocrystals
Organic charge-transfer cocrystals (CTCs) have attracted significant research attention due to their wide range of potential applications in organic optoelectronic devices, organic magnetic devices, organic energy devices, pharmaceutical industry, etc. The physical properties of organic charge trans...
| Main Authors: | , , , |
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| Format: | Journal Article |
| Language: | English |
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2021
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| Online Access: | https://hdl.handle.net/10356/146592 |
| _version_ | 1826121741192134656 |
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| author | Gao, Jiaoyang Zhai, Huifei Hu, Peng Jiang, Hui |
| author2 | School of Materials Science and Engineering |
| author_facet | School of Materials Science and Engineering Gao, Jiaoyang Zhai, Huifei Hu, Peng Jiang, Hui |
| author_sort | Gao, Jiaoyang |
| collection | NTU |
| description | Organic charge-transfer cocrystals (CTCs) have attracted significant research attention due to their wide range of potential applications in organic optoelectronic devices, organic magnetic devices, organic energy devices, pharmaceutical industry, etc. The physical properties of organic charge transfer cocrystals can be tuned not only by changing the donor and acceptor molecules, but also by varying the stoichiometry between the donor and the acceptor. However, the importance of the stoichiometry on tuning the properties of CTCs has still been underestimated. In this review, single-crystal growth methods of organic CTCs with different stoichiometries are first introduced, and their physical properties, including the degree of charge transfer, electrical conductivity, and field-effect mobility, are then discussed. Finally, a perspective of this research direction is provided to give the readers a general understanding of the concept. |
| first_indexed | 2024-10-01T05:37:08Z |
| format | Journal Article |
| id | ntu-10356/146592 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T05:37:08Z |
| publishDate | 2021 |
| record_format | dspace |
| spelling | ntu-10356/1465922023-07-14T16:03:18Z The stoichiometry of TCNQ-based organic charge-transfer cocrystals Gao, Jiaoyang Zhai, Huifei Hu, Peng Jiang, Hui School of Materials Science and Engineering Engineering::Materials Single Crystals Organic Semiconductors Organic charge-transfer cocrystals (CTCs) have attracted significant research attention due to their wide range of potential applications in organic optoelectronic devices, organic magnetic devices, organic energy devices, pharmaceutical industry, etc. The physical properties of organic charge transfer cocrystals can be tuned not only by changing the donor and acceptor molecules, but also by varying the stoichiometry between the donor and the acceptor. However, the importance of the stoichiometry on tuning the properties of CTCs has still been underestimated. In this review, single-crystal growth methods of organic CTCs with different stoichiometries are first introduced, and their physical properties, including the degree of charge transfer, electrical conductivity, and field-effect mobility, are then discussed. Finally, a perspective of this research direction is provided to give the readers a general understanding of the concept. National Research Foundation (NRF) Published version This research was funded by the National Natural Science Foundation of China (No. 51803168) and the APC was funded by Nowthwest University. P.H. also acknowledges financial support from the Youth Innovation Team of Shaanxi Universities. H.Z. acknowledges financial support from the National Natural Science Foundation of China (11704311), Natural Science Foundation of Shaanxi Provincial Department of Education (17JK0772) and Natural Science Foundation of Shaanxi Province (2018JQ1069). H.J. acknowledges the grants from the National Research Foundation, Prime Minister’s Office, Singapore under its Campus of Research Excellence and Technological Enterprise (CREATE) programme. 2021-03-02T06:12:43Z 2021-03-02T06:12:43Z 2020 Journal Article Gao, J., Zhai, H., Hu, P., & Jiang, H. (2020). The stoichiometry of TCNQ-based organic charge-transfer cocrystals. Crystals, 10(11), 993-. doi:10.3390/cryst10110993 2073-4352 https://hdl.handle.net/10356/146592 10.3390/cryst10110993 2-s2.0-85095795022 11 10 en Crystals © 2020 The Authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). application/pdf |
| spellingShingle | Engineering::Materials Single Crystals Organic Semiconductors Gao, Jiaoyang Zhai, Huifei Hu, Peng Jiang, Hui The stoichiometry of TCNQ-based organic charge-transfer cocrystals |
| title | The stoichiometry of TCNQ-based organic charge-transfer cocrystals |
| title_full | The stoichiometry of TCNQ-based organic charge-transfer cocrystals |
| title_fullStr | The stoichiometry of TCNQ-based organic charge-transfer cocrystals |
| title_full_unstemmed | The stoichiometry of TCNQ-based organic charge-transfer cocrystals |
| title_short | The stoichiometry of TCNQ-based organic charge-transfer cocrystals |
| title_sort | stoichiometry of tcnq based organic charge transfer cocrystals |
| topic | Engineering::Materials Single Crystals Organic Semiconductors |
| url | https://hdl.handle.net/10356/146592 |
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