Ultrafiltration with intermittent relaxation using colloidal silica and humic acid as model foulants

Crossflow microfiltration and ultrafiltration are widely used in membrane bioreactors for wastewater treatment and applications in the food, biotechnology and process industries. Membrane fouling is an endemic problem in these operations that can be mitigated by backwashing and intermittent relaxati...

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Main Authors: Taheri, Amir Hooshang, Sim, Lee Nuang, Krantz, William B., Fane, Anthony Gordon
Other Authors: School of Computer Science and Engineering
Format: Journal Article
Language:English
Published: 2021
Subjects:
Online Access:https://hdl.handle.net/10356/147387
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author Taheri, Amir Hooshang
Sim, Lee Nuang
Krantz, William B.
Fane, Anthony Gordon
author2 School of Computer Science and Engineering
author_facet School of Computer Science and Engineering
Taheri, Amir Hooshang
Sim, Lee Nuang
Krantz, William B.
Fane, Anthony Gordon
author_sort Taheri, Amir Hooshang
collection NTU
description Crossflow microfiltration and ultrafiltration are widely used in membrane bioreactors for wastewater treatment and applications in the food, biotechnology and process industries. Membrane fouling is an endemic problem in these operations that can be mitigated by backwashing and intermittent relaxation of the pressure or flux. Intermittent relaxation offers advantages relative to backwashing since it does not alter the membrane morphology or damage susceptible membranes, provides a more uniform removal of the foulant cake layer, and is potentially more energy-efficient. This paper reports a study of intermittent relaxation to mitigate fouling under both constant flux and constant pressure operation using a regenerated cellulose flat sheet ultrafiltration membrane (MWCO 30 kDa) and two model foulants: colloidal silica that is completely rejected and highly compressible and metastable; and, humic acid that is partially rejected and thereby can cause internal pore fouling and is relatively incompressible. Intermittent relaxation more effectively mitigated humic acid fouling owing to the compressibility and metastability of colloidal silica. An optimum relaxation frequency exists owing to the counterbalancing effects between increasing the permeation flux and reducing the time for permeation, which is determined for both constant flux and constant pressure operation. Design heuristics are advanced for the operation of intermittent relaxation.
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spelling ntu-10356/1473872021-03-31T01:55:55Z Ultrafiltration with intermittent relaxation using colloidal silica and humic acid as model foulants Taheri, Amir Hooshang Sim, Lee Nuang Krantz, William B. Fane, Anthony Gordon School of Computer Science and Engineering Nanyang Environment and Water Research Institute Singapore Membrane Technology Centre Engineering::Environmental engineering::Water treatment Membrane Fouling Water Treatment Crossflow microfiltration and ultrafiltration are widely used in membrane bioreactors for wastewater treatment and applications in the food, biotechnology and process industries. Membrane fouling is an endemic problem in these operations that can be mitigated by backwashing and intermittent relaxation of the pressure or flux. Intermittent relaxation offers advantages relative to backwashing since it does not alter the membrane morphology or damage susceptible membranes, provides a more uniform removal of the foulant cake layer, and is potentially more energy-efficient. This paper reports a study of intermittent relaxation to mitigate fouling under both constant flux and constant pressure operation using a regenerated cellulose flat sheet ultrafiltration membrane (MWCO 30 kDa) and two model foulants: colloidal silica that is completely rejected and highly compressible and metastable; and, humic acid that is partially rejected and thereby can cause internal pore fouling and is relatively incompressible. Intermittent relaxation more effectively mitigated humic acid fouling owing to the compressibility and metastability of colloidal silica. An optimum relaxation frequency exists owing to the counterbalancing effects between increasing the permeation flux and reducing the time for permeation, which is determined for both constant flux and constant pressure operation. Design heuristics are advanced for the operation of intermittent relaxation. Economic Development Board (EDB) Funding support from the Singapore Economic Development Board to the Singapore Membrane Technology Center is gratefully acknowledged. 2021-03-31T01:55:55Z 2021-03-31T01:55:55Z 2019 Journal Article Taheri, A. H., Sim, L. N., Krantz, W. B. & Fane, A. G. (2019). Ultrafiltration with intermittent relaxation using colloidal silica and humic acid as model foulants. Separation and Purification Technology, 212, 262-272. https://dx.doi.org/10.1016/j.seppur.2018.11.037 1383-5866 https://hdl.handle.net/10356/147387 10.1016/j.seppur.2018.11.037 2-s2.0-85056594348 212 262 272 en Separation and Purification Technology © 2018 Elsevier B.V. All rights reserved.
spellingShingle Engineering::Environmental engineering::Water treatment
Membrane Fouling
Water Treatment
Taheri, Amir Hooshang
Sim, Lee Nuang
Krantz, William B.
Fane, Anthony Gordon
Ultrafiltration with intermittent relaxation using colloidal silica and humic acid as model foulants
title Ultrafiltration with intermittent relaxation using colloidal silica and humic acid as model foulants
title_full Ultrafiltration with intermittent relaxation using colloidal silica and humic acid as model foulants
title_fullStr Ultrafiltration with intermittent relaxation using colloidal silica and humic acid as model foulants
title_full_unstemmed Ultrafiltration with intermittent relaxation using colloidal silica and humic acid as model foulants
title_short Ultrafiltration with intermittent relaxation using colloidal silica and humic acid as model foulants
title_sort ultrafiltration with intermittent relaxation using colloidal silica and humic acid as model foulants
topic Engineering::Environmental engineering::Water treatment
Membrane Fouling
Water Treatment
url https://hdl.handle.net/10356/147387
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AT krantzwilliamb ultrafiltrationwithintermittentrelaxationusingcolloidalsilicaandhumicacidasmodelfoulants
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