Preparation of metal-semiconductor hybrid nanostructure

Metal nanostructures have a unique property from their bulk form due to their quantum confinement effect. One of the properties that spark the interest of scientist is their optical properties in which these metal nanostructures will induce local surface plasmon resonance when they interact with lig...

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Main Author: Gihm, Wen De
Other Authors: Xue Can
Format: Final Year Project (FYP)
Language:English
Published: Nanyang Technological University 2021
Subjects:
Online Access:https://hdl.handle.net/10356/147654
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author Gihm, Wen De
author2 Xue Can
author_facet Xue Can
Gihm, Wen De
author_sort Gihm, Wen De
collection NTU
description Metal nanostructures have a unique property from their bulk form due to their quantum confinement effect. One of the properties that spark the interest of scientist is their optical properties in which these metal nanostructures will induce local surface plasmon resonance when they interact with light. Thus, they can be used in catalytic reactions such as water splitting and hydrogenation that involve applications to improve the quality of the environment. However, when these nanoparticles are coated with a different material, there will be an enhancement in its local surface plasmon resonance. This is mainly due to factor such as the size, shape and dielectric constant of the surrounding medium which will affect its effectiveness during its catalytic reaction. This study will mainly demonstrate the photocatalytic reaction to degrade methylene blue dye using Au as a catalyst. Au will be synthesized by seed mediated method and coated with SiO2 and Pt before exposing methylene blue dye under visible light with the catalyst. The results indicate that Au with a thinner coating of SiO2 is the most effective in degrading the methylene blue dye. Furthermore, the addition of Pt on the SiO2 would enhance the rate of degradation further. However, factors like agglomeration can also affect the effectiveness of the degradation.
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spelling ntu-10356/1476542023-03-04T15:43:31Z Preparation of metal-semiconductor hybrid nanostructure Gihm, Wen De Xue Can School of Materials Science and Engineering CXUE@ntu.edu.sg Engineering::Materials Metal nanostructures have a unique property from their bulk form due to their quantum confinement effect. One of the properties that spark the interest of scientist is their optical properties in which these metal nanostructures will induce local surface plasmon resonance when they interact with light. Thus, they can be used in catalytic reactions such as water splitting and hydrogenation that involve applications to improve the quality of the environment. However, when these nanoparticles are coated with a different material, there will be an enhancement in its local surface plasmon resonance. This is mainly due to factor such as the size, shape and dielectric constant of the surrounding medium which will affect its effectiveness during its catalytic reaction. This study will mainly demonstrate the photocatalytic reaction to degrade methylene blue dye using Au as a catalyst. Au will be synthesized by seed mediated method and coated with SiO2 and Pt before exposing methylene blue dye under visible light with the catalyst. The results indicate that Au with a thinner coating of SiO2 is the most effective in degrading the methylene blue dye. Furthermore, the addition of Pt on the SiO2 would enhance the rate of degradation further. However, factors like agglomeration can also affect the effectiveness of the degradation. Bachelor of Engineering (Materials Engineering) 2021-04-08T13:47:58Z 2021-04-08T13:47:58Z 2021 Final Year Project (FYP) Gihm, W. D. (2021). Preparation of metal-semiconductor hybrid nanostructure. Final Year Project (FYP), Nanyang Technological University, Singapore. https://hdl.handle.net/10356/147654 https://hdl.handle.net/10356/147654 en application/pdf Nanyang Technological University
spellingShingle Engineering::Materials
Gihm, Wen De
Preparation of metal-semiconductor hybrid nanostructure
title Preparation of metal-semiconductor hybrid nanostructure
title_full Preparation of metal-semiconductor hybrid nanostructure
title_fullStr Preparation of metal-semiconductor hybrid nanostructure
title_full_unstemmed Preparation of metal-semiconductor hybrid nanostructure
title_short Preparation of metal-semiconductor hybrid nanostructure
title_sort preparation of metal semiconductor hybrid nanostructure
topic Engineering::Materials
url https://hdl.handle.net/10356/147654
work_keys_str_mv AT gihmwende preparationofmetalsemiconductorhybridnanostructure