Electrical and thermal transport in thermoelectric, skutterudites, CoSb3
Thermoelectric energy harvesting has come into the spotlight in recent years to achieve standards amongst other type of green technology in obtaining sustainable energy. In-filled and Te-doped Co4Sb12 skutterudites were produced via solid-state synthesis and their thermoelectric properties were inve...
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Format: | Final Year Project (FYP) |
Language: | English |
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Nanyang Technological University
2021
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Online Access: | https://hdl.handle.net/10356/147667 |
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author | Na, Shi Ching |
author2 | Kedar Hippalgaonkar |
author_facet | Kedar Hippalgaonkar Na, Shi Ching |
author_sort | Na, Shi Ching |
collection | NTU |
description | Thermoelectric energy harvesting has come into the spotlight in recent years to achieve standards amongst other type of green technology in obtaining sustainable energy. In-filled and Te-doped Co4Sb12 skutterudites were produced via solid-state synthesis and their thermoelectric properties were investigated from 300K to 800K. The parent compound Co4Sb12 is p-type, whereas In-filled and Te-doped compounds, InzCo4Sb12-xTex showed n-type conduction resulted from indium and tellurium which are natural electron donors. InzCo4Sb12-xTex compounds show high electrical conductivity due to increase in the carrier concentration and low thermal conductivity due to predominantly increased phonon scattering due to filling of voids of the unit cell. The reduction in thermal conductivity and enhancement in electrical conductivity helped to establish a higher zT= S2σ/κ value for InzCo4Sb12-xTex. |
first_indexed | 2024-10-01T03:58:25Z |
format | Final Year Project (FYP) |
id | ntu-10356/147667 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T03:58:25Z |
publishDate | 2021 |
publisher | Nanyang Technological University |
record_format | dspace |
spelling | ntu-10356/1476672023-03-04T15:43:39Z Electrical and thermal transport in thermoelectric, skutterudites, CoSb3 Na, Shi Ching Kedar Hippalgaonkar School of Materials Science and Engineering A star, Institute of Materials Research and Engineering REPAKA Durga Venkata Maheswar kedar@ntu.edu.sg Engineering::Materials Thermoelectric energy harvesting has come into the spotlight in recent years to achieve standards amongst other type of green technology in obtaining sustainable energy. In-filled and Te-doped Co4Sb12 skutterudites were produced via solid-state synthesis and their thermoelectric properties were investigated from 300K to 800K. The parent compound Co4Sb12 is p-type, whereas In-filled and Te-doped compounds, InzCo4Sb12-xTex showed n-type conduction resulted from indium and tellurium which are natural electron donors. InzCo4Sb12-xTex compounds show high electrical conductivity due to increase in the carrier concentration and low thermal conductivity due to predominantly increased phonon scattering due to filling of voids of the unit cell. The reduction in thermal conductivity and enhancement in electrical conductivity helped to establish a higher zT= S2σ/κ value for InzCo4Sb12-xTex. Bachelor of Engineering (Materials Engineering) 2021-04-29T01:05:45Z 2021-04-29T01:05:45Z 2021 Final Year Project (FYP) Na, S. C. (2021). Electrical and thermal transport in thermoelectric, skutterudites, CoSb3. Final Year Project (FYP), Nanyang Technological University, Singapore. https://hdl.handle.net/10356/147667 https://hdl.handle.net/10356/147667 en application/pdf Nanyang Technological University |
spellingShingle | Engineering::Materials Na, Shi Ching Electrical and thermal transport in thermoelectric, skutterudites, CoSb3 |
title | Electrical and thermal transport in thermoelectric, skutterudites, CoSb3 |
title_full | Electrical and thermal transport in thermoelectric, skutterudites, CoSb3 |
title_fullStr | Electrical and thermal transport in thermoelectric, skutterudites, CoSb3 |
title_full_unstemmed | Electrical and thermal transport in thermoelectric, skutterudites, CoSb3 |
title_short | Electrical and thermal transport in thermoelectric, skutterudites, CoSb3 |
title_sort | electrical and thermal transport in thermoelectric skutterudites cosb3 |
topic | Engineering::Materials |
url | https://hdl.handle.net/10356/147667 |
work_keys_str_mv | AT nashiching electricalandthermaltransportinthermoelectricskutteruditescosb3 |