Electrical and thermal transport in thermoelectric, skutterudites, CoSb3

Thermoelectric energy harvesting has come into the spotlight in recent years to achieve standards amongst other type of green technology in obtaining sustainable energy. In-filled and Te-doped Co4Sb12 skutterudites were produced via solid-state synthesis and their thermoelectric properties were inve...

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Main Author: Na, Shi Ching
Other Authors: Kedar Hippalgaonkar
Format: Final Year Project (FYP)
Language:English
Published: Nanyang Technological University 2021
Subjects:
Online Access:https://hdl.handle.net/10356/147667
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author Na, Shi Ching
author2 Kedar Hippalgaonkar
author_facet Kedar Hippalgaonkar
Na, Shi Ching
author_sort Na, Shi Ching
collection NTU
description Thermoelectric energy harvesting has come into the spotlight in recent years to achieve standards amongst other type of green technology in obtaining sustainable energy. In-filled and Te-doped Co4Sb12 skutterudites were produced via solid-state synthesis and their thermoelectric properties were investigated from 300K to 800K. The parent compound Co4Sb12 is p-type, whereas In-filled and Te-doped compounds, InzCo4Sb12-xTex showed n-type conduction resulted from indium and tellurium which are natural electron donors. InzCo4Sb12-xTex compounds show high electrical conductivity due to increase in the carrier concentration and low thermal conductivity due to predominantly increased phonon scattering due to filling of voids of the unit cell. The reduction in thermal conductivity and enhancement in electrical conductivity helped to establish a higher zT= S2σ/κ value for InzCo4Sb12-xTex.
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spelling ntu-10356/1476672023-03-04T15:43:39Z Electrical and thermal transport in thermoelectric, skutterudites, CoSb3 Na, Shi Ching Kedar Hippalgaonkar School of Materials Science and Engineering A star, Institute of Materials Research and Engineering REPAKA Durga Venkata Maheswar kedar@ntu.edu.sg Engineering::Materials Thermoelectric energy harvesting has come into the spotlight in recent years to achieve standards amongst other type of green technology in obtaining sustainable energy. In-filled and Te-doped Co4Sb12 skutterudites were produced via solid-state synthesis and their thermoelectric properties were investigated from 300K to 800K. The parent compound Co4Sb12 is p-type, whereas In-filled and Te-doped compounds, InzCo4Sb12-xTex showed n-type conduction resulted from indium and tellurium which are natural electron donors. InzCo4Sb12-xTex compounds show high electrical conductivity due to increase in the carrier concentration and low thermal conductivity due to predominantly increased phonon scattering due to filling of voids of the unit cell. The reduction in thermal conductivity and enhancement in electrical conductivity helped to establish a higher zT= S2σ/κ value for InzCo4Sb12-xTex. Bachelor of Engineering (Materials Engineering) 2021-04-29T01:05:45Z 2021-04-29T01:05:45Z 2021 Final Year Project (FYP) Na, S. C. (2021). Electrical and thermal transport in thermoelectric, skutterudites, CoSb3. Final Year Project (FYP), Nanyang Technological University, Singapore. https://hdl.handle.net/10356/147667 https://hdl.handle.net/10356/147667 en application/pdf Nanyang Technological University
spellingShingle Engineering::Materials
Na, Shi Ching
Electrical and thermal transport in thermoelectric, skutterudites, CoSb3
title Electrical and thermal transport in thermoelectric, skutterudites, CoSb3
title_full Electrical and thermal transport in thermoelectric, skutterudites, CoSb3
title_fullStr Electrical and thermal transport in thermoelectric, skutterudites, CoSb3
title_full_unstemmed Electrical and thermal transport in thermoelectric, skutterudites, CoSb3
title_short Electrical and thermal transport in thermoelectric, skutterudites, CoSb3
title_sort electrical and thermal transport in thermoelectric skutterudites cosb3
topic Engineering::Materials
url https://hdl.handle.net/10356/147667
work_keys_str_mv AT nashiching electricalandthermaltransportinthermoelectricskutteruditescosb3