Hybrid-cyanogels induced sandwich-like N,P-carbon/SnNi₁₀P₃ for excellent lithium storage
We have developed a novel sandwich-like nanostructure where SnNi₁₀P₃ particles are intimately confined within flexible N,P-codoped bilayer carbon membranes (SnNi₁₀P₃@N,P-C) via using SnNi-based hybrid-cyanogels as the precursor, followed by freeze-drying and pyrolysis. The cyano-bridges can effectiv...
| Main Authors: | , , , , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2021
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| Online Access: | https://hdl.handle.net/10356/151607 |
| _version_ | 1826121225956491264 |
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| author | Li, Tongfei Zhang, Hao Tang, Yidan Li, Xin Liu, Kunhao Zhang, Yiwei Fu, Gengtao Wu, Ping Tang, Yawen |
| author2 | School of Chemical and Biomedical Engineering |
| author_facet | School of Chemical and Biomedical Engineering Li, Tongfei Zhang, Hao Tang, Yidan Li, Xin Liu, Kunhao Zhang, Yiwei Fu, Gengtao Wu, Ping Tang, Yawen |
| author_sort | Li, Tongfei |
| collection | NTU |
| description | We have developed a novel sandwich-like nanostructure where SnNi₁₀P₃ particles are intimately confined within flexible N,P-codoped bilayer carbon membranes (SnNi₁₀P₃@N,P-C) via using SnNi-based hybrid-cyanogels as the precursor, followed by freeze-drying and pyrolysis. The cyano-bridges can effectively capture metal cations within the composite cyanogels, which facilitates the formation of a carbon-encapsulated sandwich-like architecture. The sandwiched SnNi₁₀P₃@N,P-C is demonstrated to be an outstanding lithium-ion (Li-ion) batteries anode material with superior reversible capacity and long cycle stability. The flexible N,P-codoped bilayer carbon membranes not only afford fast charge transfer pathway but also inhibit the aggregation of SnNi₁₀P₃ active component and buffer the mechanical strain during lithiation/delithiation. |
| first_indexed | 2024-10-01T05:29:13Z |
| format | Journal Article |
| id | ntu-10356/151607 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T05:29:13Z |
| publishDate | 2021 |
| record_format | dspace |
| spelling | ntu-10356/1516072021-07-01T06:04:44Z Hybrid-cyanogels induced sandwich-like N,P-carbon/SnNi₁₀P₃ for excellent lithium storage Li, Tongfei Zhang, Hao Tang, Yidan Li, Xin Liu, Kunhao Zhang, Yiwei Fu, Gengtao Wu, Ping Tang, Yawen School of Chemical and Biomedical Engineering Engineering::Chemical engineering Composite Cyanogels SnNi₁₀P₃ Particles We have developed a novel sandwich-like nanostructure where SnNi₁₀P₃ particles are intimately confined within flexible N,P-codoped bilayer carbon membranes (SnNi₁₀P₃@N,P-C) via using SnNi-based hybrid-cyanogels as the precursor, followed by freeze-drying and pyrolysis. The cyano-bridges can effectively capture metal cations within the composite cyanogels, which facilitates the formation of a carbon-encapsulated sandwich-like architecture. The sandwiched SnNi₁₀P₃@N,P-C is demonstrated to be an outstanding lithium-ion (Li-ion) batteries anode material with superior reversible capacity and long cycle stability. The flexible N,P-codoped bilayer carbon membranes not only afford fast charge transfer pathway but also inhibit the aggregation of SnNi₁₀P₃ active component and buffer the mechanical strain during lithiation/delithiation. This work was financially supported by the National Natural Science Foundation of China (21875112, 21878047, 21676056, and 51673040), the Six Talents Pinnacle Program of Jiangsu Province of China (JNHB-006), the Qing Lan Project of Jiangsu Province (1107040167), and by a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) (1107047002), National and Local Joint Engineering Research Center of Biomedical Functional Materials, and Priority Academic Program Development of Jiangsu Higher Education Institutions. 2021-07-01T06:04:44Z 2021-07-01T06:04:44Z 2019 Journal Article Li, T., Zhang, H., Tang, Y., Li, X., Liu, K., Zhang, Y., Fu, G., Wu, P. & Tang, Y. (2019). Hybrid-cyanogels induced sandwich-like N,P-carbon/SnNi₁₀P₃ for excellent lithium storage. ACS Applied Energy Materials, 2(5), 3683-3691. https://dx.doi.org/10.1021/acsaem.9b00397 2574-0962 0000-0002-9374-1750 0000-0003-0411-645X 0000-0003-1819-2613 https://hdl.handle.net/10356/151607 10.1021/acsaem.9b00397 2-s2.0-85065536729 5 2 3683 3691 en ACS Applied Energy Materials © 2019 American Chemical Society. All rights reserved. |
| spellingShingle | Engineering::Chemical engineering Composite Cyanogels SnNi₁₀P₃ Particles Li, Tongfei Zhang, Hao Tang, Yidan Li, Xin Liu, Kunhao Zhang, Yiwei Fu, Gengtao Wu, Ping Tang, Yawen Hybrid-cyanogels induced sandwich-like N,P-carbon/SnNi₁₀P₃ for excellent lithium storage |
| title | Hybrid-cyanogels induced sandwich-like N,P-carbon/SnNi₁₀P₃ for excellent lithium storage |
| title_full | Hybrid-cyanogels induced sandwich-like N,P-carbon/SnNi₁₀P₃ for excellent lithium storage |
| title_fullStr | Hybrid-cyanogels induced sandwich-like N,P-carbon/SnNi₁₀P₃ for excellent lithium storage |
| title_full_unstemmed | Hybrid-cyanogels induced sandwich-like N,P-carbon/SnNi₁₀P₃ for excellent lithium storage |
| title_short | Hybrid-cyanogels induced sandwich-like N,P-carbon/SnNi₁₀P₃ for excellent lithium storage |
| title_sort | hybrid cyanogels induced sandwich like n p carbon snni₁₀p₃ for excellent lithium storage |
| topic | Engineering::Chemical engineering Composite Cyanogels SnNi₁₀P₃ Particles |
| url | https://hdl.handle.net/10356/151607 |
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