Synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative
The synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative is described. The reaction of amidinato phosphinoamidosilylene [L{(Ar)(Ph₂P)N}Si:] (1, L = PhC(NtBu)₂, Ar = 2,6-iPr₂C₆H₃) with GeCl₂·dioxane afforded a phosphine-stabilized phosphidogermanium(i) dimer...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2021
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| Online Access: | https://hdl.handle.net/10356/151739 |
| _version_ | 1811680600131633152 |
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| author | Muhammad Luthfi Ismail So, Cheuk-Wai |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Muhammad Luthfi Ismail So, Cheuk-Wai |
| author_sort | Muhammad Luthfi Ismail |
| collection | NTU |
| description | The synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative is described. The reaction of amidinato phosphinoamidosilylene [L{(Ar)(Ph₂P)N}Si:] (1, L = PhC(NtBu)₂, Ar = 2,6-iPr₂C₆H₃) with GeCl₂·dioxane afforded a phosphine-stabilized phosphidogermanium(i) dimer moiety in a mixed-valent germanium(I,II) compound [:Ge(Cl){N(Ar)PPh₂}(Ph₂P)Ge:]₂ (3). The mechanism for the formation of 3 is also studied and reported. |
| first_indexed | 2024-10-01T03:27:37Z |
| format | Journal Article |
| id | ntu-10356/151739 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:27:37Z |
| publishDate | 2021 |
| record_format | dspace |
| spelling | ntu-10356/1517392021-07-21T09:24:31Z Synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative Muhammad Luthfi Ismail So, Cheuk-Wai School of Physical and Mathematical Sciences Science::Chemistry Amidogermanium Derivative Germanium Derivative The synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative is described. The reaction of amidinato phosphinoamidosilylene [L{(Ar)(Ph₂P)N}Si:] (1, L = PhC(NtBu)₂, Ar = 2,6-iPr₂C₆H₃) with GeCl₂·dioxane afforded a phosphine-stabilized phosphidogermanium(i) dimer moiety in a mixed-valent germanium(I,II) compound [:Ge(Cl){N(Ar)PPh₂}(Ph₂P)Ge:]₂ (3). The mechanism for the formation of 3 is also studied and reported. Ministry of Education (MOE) This work is supported by AcRF Tier 1 grant (RG 15/15). 2021-07-21T09:24:31Z 2021-07-21T09:24:31Z 2019 Journal Article Muhammad Luthfi Ismail & So, C. (2019). Synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative. Chemical Communications, 55(14), 2074-2077. https://dx.doi.org/10.1039/c8cc09454c 1359-7345 https://hdl.handle.net/10356/151739 10.1039/c8cc09454c 30693929 2-s2.0-85061392355 14 55 2074 2077 en RG 15/15 Chemical Communications © 2019 The Royal Society of Chemistry. All rights reserved. |
| spellingShingle | Science::Chemistry Amidogermanium Derivative Germanium Derivative Muhammad Luthfi Ismail So, Cheuk-Wai Synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative |
| title | Synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative |
| title_full | Synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative |
| title_fullStr | Synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative |
| title_full_unstemmed | Synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative |
| title_short | Synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative |
| title_sort | synthesis of a dimeric phosphine stabilized phosphidogermanium i amidogermanium ii derivative |
| topic | Science::Chemistry Amidogermanium Derivative Germanium Derivative |
| url | https://hdl.handle.net/10356/151739 |
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