Halogen-bond-driven supramolecular assemblies of quaternary-ammonium-iodide-containing polymers in three phases
Halogen bonding (XB) opens avenues to supramolecular assemblies. Here, we report XB-driven supramolecular assemblies of quaternary ammonium iodide (QAI)-containing polymers in three (solution, surface, and solid) phases. In the solution, QAI-containing block copolymers form unique self-assembly stru...
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2021
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| Online Access: | https://hdl.handle.net/10356/153605 |
| _version_ | 1826129873462099968 |
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| author | Le, Hong Tho Goto, Atsushi |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Le, Hong Tho Goto, Atsushi |
| author_sort | Le, Hong Tho |
| collection | NTU |
| description | Halogen bonding (XB) opens avenues to supramolecular assemblies. Here, we report XB-driven supramolecular assemblies of quaternary ammonium iodide (QAI)-containing polymers in three (solution, surface, and solid) phases. In the solution, QAI-containing block copolymers form unique self-assembly structures such as micrometer-sized giant vesicles (up to 5-μm diameter) and a 1-dimensional (1D) structure with multiple inter-vesicular linkages via XB. Exploiting the temperature dependence of XB strength, external molecules are successfully loaded and unloaded. On the surface, reversible XB crosslinking and decrosslinking of QAI-containing polymer brushes are achieved. The wettability of the polymer brush is finely tuned by the XB crosslinking density. In solid phase, QAI-containing monomers are co-crystalized (assembled) via XB. A polymer sheet is obtained via the solid-phase polymerization of the monomer co-crystal; the sheet enables capture and release of halogen-containing (XB-coordinating) guest molecules and thereby serves as an innovative host material. |
| first_indexed | 2024-10-01T07:47:39Z |
| format | Journal Article |
| id | ntu-10356/153605 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T07:47:39Z |
| publishDate | 2021 |
| record_format | dspace |
| spelling | ntu-10356/1536052023-02-28T19:53:30Z Halogen-bond-driven supramolecular assemblies of quaternary-ammonium-iodide-containing polymers in three phases Le, Hong Tho Goto, Atsushi School of Physical and Mathematical Sciences Division of Chemistry and Biological Chemistry Science::Chemistry::Organic chemistry::Polymers Polymer Halogen Bonding Halogen bonding (XB) opens avenues to supramolecular assemblies. Here, we report XB-driven supramolecular assemblies of quaternary ammonium iodide (QAI)-containing polymers in three (solution, surface, and solid) phases. In the solution, QAI-containing block copolymers form unique self-assembly structures such as micrometer-sized giant vesicles (up to 5-μm diameter) and a 1-dimensional (1D) structure with multiple inter-vesicular linkages via XB. Exploiting the temperature dependence of XB strength, external molecules are successfully loaded and unloaded. On the surface, reversible XB crosslinking and decrosslinking of QAI-containing polymer brushes are achieved. The wettability of the polymer brush is finely tuned by the XB crosslinking density. In solid phase, QAI-containing monomers are co-crystalized (assembled) via XB. A polymer sheet is obtained via the solid-phase polymerization of the monomer co-crystal; the sheet enables capture and release of halogen-containing (XB-coordinating) guest molecules and thereby serves as an innovative host material. Ministry of Education (MOE) National Research Foundation (NRF) Published version This work was supported by National Research Foundation (NRF) Investigatorship in Singapore (NRF-NRFI05-2019-0001) and Academic Research Fund (AcRF) Tier 2 from Ministry of Education in Singapore (MOE2017-T2-1-018). 2021-12-12T08:54:59Z 2021-12-12T08:54:59Z 2021 Journal Article Le, H. T. & Goto, A. (2021). Halogen-bond-driven supramolecular assemblies of quaternary-ammonium-iodide-containing polymers in three phases. Cell Reports Physical Science, 2(6), 100469-. https://dx.doi.org/10.1016/j.xcrp.2021.100469 2666-3864 https://hdl.handle.net/10356/153605 10.1016/j.xcrp.2021.100469 2-s2.0-85108421960 6 2 100469 en NRF-NRFI05-2019-0001 MOE2017-T2-1-018 Cell Reports Physical Science © 2021 The Author(s). This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). application/pdf |
| spellingShingle | Science::Chemistry::Organic chemistry::Polymers Polymer Halogen Bonding Le, Hong Tho Goto, Atsushi Halogen-bond-driven supramolecular assemblies of quaternary-ammonium-iodide-containing polymers in three phases |
| title | Halogen-bond-driven supramolecular assemblies of quaternary-ammonium-iodide-containing polymers in three phases |
| title_full | Halogen-bond-driven supramolecular assemblies of quaternary-ammonium-iodide-containing polymers in three phases |
| title_fullStr | Halogen-bond-driven supramolecular assemblies of quaternary-ammonium-iodide-containing polymers in three phases |
| title_full_unstemmed | Halogen-bond-driven supramolecular assemblies of quaternary-ammonium-iodide-containing polymers in three phases |
| title_short | Halogen-bond-driven supramolecular assemblies of quaternary-ammonium-iodide-containing polymers in three phases |
| title_sort | halogen bond driven supramolecular assemblies of quaternary ammonium iodide containing polymers in three phases |
| topic | Science::Chemistry::Organic chemistry::Polymers Polymer Halogen Bonding |
| url | https://hdl.handle.net/10356/153605 |
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