Use of magnesium-silicate-hydrate (M-S-H) cement mixes in 3D printing applications

This study focused on the development of 3D printed building components incorporating MgO–SiO2 binders. The effects of parameters such as MgO/SiO2 and water/binder ratios and superplasticizer dosage were evaluated to produce 3D printable MgO–SiO2 binders. The assessment of rheological and mechanical...

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Main Authors: Panda, Biranchi, Sonat, Cem, Yang, En-Hua, Tan, Ming Jen, Unluer, Cise
Other Authors: School of Mechanical and Aerospace Engineering
Format: Journal Article
Language:English
Published: 2021
Subjects:
Online Access:https://hdl.handle.net/10356/154123
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author Panda, Biranchi
Sonat, Cem
Yang, En-Hua
Tan, Ming Jen
Unluer, Cise
author2 School of Mechanical and Aerospace Engineering
author_facet School of Mechanical and Aerospace Engineering
Panda, Biranchi
Sonat, Cem
Yang, En-Hua
Tan, Ming Jen
Unluer, Cise
author_sort Panda, Biranchi
collection NTU
description This study focused on the development of 3D printed building components incorporating MgO–SiO2 binders. The effects of parameters such as MgO/SiO2 and water/binder ratios and superplasticizer dosage were evaluated to produce 3D printable MgO–SiO2 binders. The assessment of rheological and mechanical properties, which led to an optimum mix that satisfied the printability criteria, was supported by microstructural characterization. The best-performing mix in terms of printability and mechanical performance was characterized via x-ray diffraction (XRD), thermogravimetric analysis/derivative thermogravimetry (TG/DTG) and field emission scanning electron microscopy (FESEM) with energy dispersive spectroscopy (EDS). The selected mix exhibited thixotropic behaviour with an ability to recover ~80% of its original viscosity within 60 s of extrusion and a shape retention factor of ~1. The extrudability, shape retention and buildability aspects were successfully demonstrated by printing a 5-layered 3D structure without any deformations. The final product contained brucite and M-S-H as hydration products, which were the main contributor to mechanical performance and microstructural densification.
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spelling ntu-10356/1541232021-12-18T20:12:24Z Use of magnesium-silicate-hydrate (M-S-H) cement mixes in 3D printing applications Panda, Biranchi Sonat, Cem Yang, En-Hua Tan, Ming Jen Unluer, Cise School of Mechanical and Aerospace Engineering School of Civil and Environmental Engineering Singapore Centre for 3D Printing Engineering::Mechanical engineering 3D Concrete Printing MgO This study focused on the development of 3D printed building components incorporating MgO–SiO2 binders. The effects of parameters such as MgO/SiO2 and water/binder ratios and superplasticizer dosage were evaluated to produce 3D printable MgO–SiO2 binders. The assessment of rheological and mechanical properties, which led to an optimum mix that satisfied the printability criteria, was supported by microstructural characterization. The best-performing mix in terms of printability and mechanical performance was characterized via x-ray diffraction (XRD), thermogravimetric analysis/derivative thermogravimetry (TG/DTG) and field emission scanning electron microscopy (FESEM) with energy dispersive spectroscopy (EDS). The selected mix exhibited thixotropic behaviour with an ability to recover ~80% of its original viscosity within 60 s of extrusion and a shape retention factor of ~1. The extrudability, shape retention and buildability aspects were successfully demonstrated by printing a 5-layered 3D structure without any deformations. The final product contained brucite and M-S-H as hydration products, which were the main contributor to mechanical performance and microstructural densification. National Research Foundation (NRF) Accepted version The authors would like to acknowledge Sembcorp Architects & Engineers Pte. Ltd. and National Research Foundation (NRF) Singapore for their funding and support in this research project. 2021-12-15T07:16:13Z 2021-12-15T07:16:13Z 2021 Journal Article Panda, B., Sonat, C., Yang, E., Tan, M. J. & Unluer, C. (2021). Use of magnesium-silicate-hydrate (M-S-H) cement mixes in 3D printing applications. Cement and Concrete Composites, 117, 103901-. https://dx.doi.org/10.1016/j.cemconcomp.2020.103901 0958-9465 https://hdl.handle.net/10356/154123 10.1016/j.cemconcomp.2020.103901 2-s2.0-85098188930 117 103901 en Cement and Concrete Composites © 2020 Elsevier Ltd. All rights reserved. This paper was published in Cement and Concrete Composites and is made available with permission of Elsevier Ltd. application/pdf
spellingShingle Engineering::Mechanical engineering
3D Concrete Printing
MgO
Panda, Biranchi
Sonat, Cem
Yang, En-Hua
Tan, Ming Jen
Unluer, Cise
Use of magnesium-silicate-hydrate (M-S-H) cement mixes in 3D printing applications
title Use of magnesium-silicate-hydrate (M-S-H) cement mixes in 3D printing applications
title_full Use of magnesium-silicate-hydrate (M-S-H) cement mixes in 3D printing applications
title_fullStr Use of magnesium-silicate-hydrate (M-S-H) cement mixes in 3D printing applications
title_full_unstemmed Use of magnesium-silicate-hydrate (M-S-H) cement mixes in 3D printing applications
title_short Use of magnesium-silicate-hydrate (M-S-H) cement mixes in 3D printing applications
title_sort use of magnesium silicate hydrate m s h cement mixes in 3d printing applications
topic Engineering::Mechanical engineering
3D Concrete Printing
MgO
url https://hdl.handle.net/10356/154123
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